MoS2-based electrocatalysts for hydrogen evolution and the prospect of hydrogen energy technology

doi:10.16085/j.issn.1000-6613.2018-1107

Abstract

Abstract:

Hydrogen is regarded as an ideal energy carrier for its light quality, high energy density and eco-friendly combustion emission. Hydrogen can be used as fuel for PEM fuel cells and energy storage media to regulate the energy output from wind turbine and solar power, therefore it is expected to play a crucial role in future energy system. In order to develop the technology and devices for water electrolysis, high efficient electrocatalysts are the key. We systematically introduce the recent progress in MoS₂-based electrocatalysts for hydrogen evolution reaction (HER), categorize the electrocatalysts into powder-type and binder-free electrocatalysts, and discuss two methods of regulation of active sites and the improvement of electric conductivity. Different types of MoS₂ and MoS₂-based electrodes for HER were compared and evaluated using the overpotential and Tafel slopes, and the results demonstrate promising potential of MoS₂ as HER electrocatalysts. For developing MoS₂ HER electrocatalysts, it should further increase the stability of MoS₂ crystal, regulate the electronic properties and optimize the electrode structure.

Key words: hydrogen, electrocatalyst, molybdenum disulfide, water-splitting, hydrogen production

摘要：

氢气具有质量轻、热值高、燃烧产物清洁等优点，被认为是理想的能源载体。氢气既能作为燃料电池的燃料，又能作为储能介质调节风能、太阳能发电系统的随机性、间歇性，正在成为未来能源的重要组成部分。为了促进电解水制氢技术与装备发展，研究高效电催化剂十分重要。本文围绕“粉末型”与“自支撑型”电催化剂结构特征，讨论基于二硫化钼（MoS₂）的析氢电催化剂的研究现状，阐述了催化活性位点调控策略与提高导电性两条技术途径，并以析氢过电位和塔菲尔曲线斜率为依据，比较不同方法制备的二硫化钼电催化剂的催化活性。表明提高二硫化钼晶相稳定性、调节其电子结构和优化催化电极结构等方法，将进一步提高基于二硫化钼的析氢催化电极性能。

关键词: 氢, 电催化剂, 二硫化钼, 电解水, 制氢

CLC Number:

TQ151

Peican WANG, Qing LEI, Shuai LIU, Baoguo WANG. MoS₂-based electrocatalysts for hydrogen evolution and the prospect of hydrogen energy technology[J]. Chemical Industry and Engineering Progress, 2019, 38(01): 278-291.

王培灿, 雷青, 刘帅, 王保国. 电解水制氢MoS₂催化剂研究与氢能技术展望[J]. 化工进展, 2019, 38(01): 278-291.

Figures/Tables 16

References 70

1	DINCER I , ACAR C . Review and evaluation of hydrogen production methods for better sustainability[J]. International Journal of Hydrogen Energy, 2015, 40(34): 11094-11111.
2	WANG L , LI Y , YIN X , et al . Comparison of three nickel-based carbon composite catalysts for hydrogen evolution reaction in alkaline solution[J]. International Journal of Hydrogen Energy, 2017, 42(36): 22655-22662.
3	COOK T R , DOGUTAN D K , REECE S Y , et al . Solar energy supply and storage for the legacy and nonlegacy worlds[J]. Chemical reviews, 2010, 110(11): 6474-6502.
4	ZENG K , ZHANG D K . Recent progress in alkaline water electrolysis for hydrogen production and applications[J]. Progress in Energy & Combustion Science, 2010, 36(3): 307-326.
5	PAUL B , ANDREWS J . PEM unitised reversible/regenerative hydrogen fuel cell systems: state of the art and technical challenges[J]. Renewable & Sustainable Energy Reviews, 2017, 79: 585-599.
6	王保国, 王培灿, 雷青, 等 . 一种电解水制氢气的方法及装置:CN105483747A[P]. 2016-04-13.
	WANG B G , WANG P C , LEI Q , et al .Hydrogen production method and device through electrolysis of water: CN105483747A[P]. 2016-04-13.
7	MA L, XU L , XU X , et al . Cobalt-doped edge-rich MoS₂/nitrogenated graphene composite as an electrocatalyst for hydrogen evolution reaction[J]. Materials Science & Engineering B, 2016, 212: 30-38.
8	TAN Y , YU K , YANG T , et al . The combinations of hollow MoS₂ micro@nano-spheres: one-step synthesis, excellent photocatalytic and humidity sensing properties[J]. Journal of Materials Chemistry C, 2014, 2(27): 5422-5430.
9	TIAN J , LIU Q , ASIRI A M , et al . Self-supported nanoporous cobalt phosphide nanowire arrays: an efficient 3D hydrogen-evolving cathode over the wide range of pH 0-14[J]. Journal of the American Chemical Society, 2014, 136(21): 7587-7590.
10	TANG C , GAN L , ZHANG R , et al . Ternary Fe _x Co_1– _x P nanowire array as a robust hydrogen evolution reaction electrocatalyst with Pt-like activity: experimental and theoretical insight[J]. Nano letters, 2016, 16(10): 6617-6621.
11	WANG H , KONG D , JOHANES P , et al . MoSe₂ and WSe₂ nanofilms with vertically aligned molecular layers on curved and rough surfaces[J]. Nano Letters, 2013, 13(7): 3426-3433.
12	DUAN J , CHEN S , JARONIEC M , et al . Porous C₃N₄ nanolayers@N-graphene films as catalyst electrodes for highly efficient hydrogen evolution[J]. ACS Nano, 2015, 9(1): 931-940.
13	CONWAY B E , TILAK B V . Interfacial processes involving electrocatalytic evolution and oxidation of H₂, and the role of chemisorbed H[J]. Electrochimica Acta, 2002, 47(22): 3571-3594.
14	MCCRORY C C , JUNG S , FERRER I M , et al . Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices[J].J.Am.Chem.Soc., 2015, 137(13): 4347-4357.
15	KIBSGAARD J , JARAMILLO T F , BESENBACHER F . Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo₃S₁₃]^2- clusters[J]. Nature Chemistry, 2014, 6(3): 248-253.
16	HU J , HUANG B , ZHANG C , et al . Engineering stepped edge surface structures of MoS₂ sheet stacks to accelerate the hydrogen evolution reaction[J]. Energy & Environmental Science, 2017, 10(2): 593-603.
17	KONG D , WANG H , CHA J J , et al . Synthesis of MoS₂ and MoSe₂ films with vertically aligned layers[J]. Nano Lett., 2013, 13(3): 1341-1347.
18	HINNEMANN B , MOSES P G , BONDE J , et al . Biomimetic hydrogen evolution: MoS₂ nanoparticles as catalyst for hydrogen evolution[J].AmJ. Chem. Soc., 2005, 36(25): 5308-5309.
19	JARAMILLO T F , JΦGENSEN K P , BONDE J , et al . Identification of active edge sites for electrochemical H₂ evolution from MoS₂ nanocatalysts[J]. Science, 2007, 317(5834): 100-102.
20	KARUNADASA H I , MONTALVO E , SUN Y , et al . A molecular MoS₂ edge site mimic for catalytic hydrogen generation[J]. Science, 2012, 335(6069): 698-702.
21	SUN Y , ALIMOHAMMADI F , ZHANG D , et al . Enabling colloidal synthesis of edge-oriented MoS₂ with expanded interlayer spacing for enhanced HER catalysis[J]. Nano Letters, 2017, 17(3): 1963-1969.
22	KUMAR S , SAHOO P K , SATPATI A K . Electrochemical and SECM investigation of MoS₂/GO and MoS₂/rGO nanocomposite materials for HER electrocatalysis[J]. ACS Omega, 2017, 2(11): 7532-7545.
23	JIANG W J , LIN G , LI L , et al . Understanding the high activity of Fe-N-C electrocatalysts in oxygen reduction: Fe/Fe₃C nanoparticles boost the activity of Fe-N _x [J].J.Am.Chem.Soc., 2016, 138(10): 3570-3578.
24	LI Y G , WANG H L , XIE L M , et al . MoS₂ nanoparticles grown on graphene: an advanced catalyst for the hydrogen evolution reaction[J].AmJ. Chem. Soc., 2011, 133(19): 7296-7299.
25	ZHENG X , XU J , YAN K , et al . Space-confined growth of MoS₂ nanosheets within graphite: the layered hybrid of MoS₂ and graphene as an active catalyst for hydrogen evolution reaction[J]. Chemistry of Materials, 2014, 26(7): 2344-2353.
26	YAN Y , GE X , LIU Z , et al . Facile synthesis of low crystalline MoS₂ nanosheet-coated CNTs for enhanced hydrogen evolution reaction[J]. Nanoscale, 2013, 5(17): 7768-7771.
27	LIAO L , ZHU J , BIAN X , et al . MoS₂ formed on mesoporous graphene as a highly active catalyst for hydrogen evolution[J]. Advanced Functional Materials, 2013, 23(42): 5326-5333.
28	RHEEM Y , HAN Y , LEE K H , et al . Synthesis of hierarchical MoO₂/MoS₂ nanofibers for electrocatalytic hydrogen evolution[J]. Nanotechnology, 2017, 28(10): 105605.
29	GUO Y , GAN L , SHANG C , et al . A cake-style CoS₂@MoS₂/RGO hybrid catalyst for efficient hydrogen evolution[J]. Advanced Functional Materials, 2017, 27(5): 1602699.
30	LI D J , MAITI U N , LIM J , et al . Molybdenum sulfide/N-doped CNT forest hybrid catalysts for high-performance hydrogen evolution reaction[J]. Nano Lett., 2014, 14(3): 1228-1233.
31	TANG Y J , WANG Y , WANG X L , et al . Molybdenum disulfide/nitrogen-doped reduced graphene oxide nanocomposite with enlarged interlayer spacing for electrocatalytic hydrogen evolution[J]. Advanced Energy Materials, 2016, 6(12): 1600116.
32	DAI X , DU K , LI Z , et al . Co-doped MoS₂ nanosheets with the dominant CoMoS phase coated on carbon as an excellent electrocatalyst for hydrogen evolution[J]. ACS Appl. Mater. Interfaces, 2015, 7(49): 27242-27253.
33	WU Z , FANG B , WANG Z , et al . MoS₂ nanosheets: a designed structure with high active site density for the hydrogen evolution reaction[J]. ACS Catalysis, 2013, 3(9): 2101-2107.
34	XU S , LI D , WU P . One-pot, facile, and versatile synthesis of monolayer MoS₂/WS₂ quantum dots as bioimaging probes and efficient electrocatalysts for hydrogen evolution reaction[J]. Advanced Functional Materials, 2015, 25(7): 1127-1136.
35	HUANG L B , ZHAO L , ZHANG Y , et al . Self-limited on-site conversion of MoO₃ nanodots into vertically aligned ultrasmall monolayer MoS₂ for efficient hydrogen evolution[J]. Advanced Energy Materials, 2018, 8(21): 1800734.
36	KIBSGAARD J , CHEN Z , REINECKE B N , et al . Engineering the surface structure of MoS₂ to preferentially expose active edge sites for electrocatalysis[J]. Nat. Mater., 2012, 11(11): 963-969.
37	ZHANG L , WU H B , YAN Y , et al . Hierarchical MoS₂ microboxes constructed by nanosheets with enhanced electrochemical properties for lithium storage and water splitting[J]. Energy Environ. Sci., 2014, 7(10): 3302-3306.
38	SHANG X , HU W H , LI X , et al . Oriented stacking along vertical (002) planes of MoS₂: a novel assembling style to enhance activity for hydrogen evolution[J]. Electrochimica Acta, 2017, 224∶ 25-31.
39	XIE J , ZHANG H , LI S , et al . Defect-rich MoS₂ ultrathin nanosheets with additional active edge sites for enhanced electrocatalytic hydrogen evolution[J]. Adv. Mater., 2013, 25(40): 5807-5813.
40	LI H , TSAI C , KOH A L , et al . Activating and optimizing MoS₂ basal planes for hydrogen evolution through the formation of strained sulphur vacancies[J]. Nature Materials, 2016, 15(1): 48-53.
41	BONDE J , MOSES P G , JARAMILLO T F , et al . Hydrogen evolution on nano-particulate transition metal sulfides[J]. Faraday Discussions, 2008, 140(1): 219-231.
42	XIE J , ZHANG J , LI S , et al . Controllable disorder engineering in oxygen-incorporated MoS₂ ultrathin nanosheets for efficient hydrogen evolution[J].AmJ. Chem. Soc., 2013, 135(47): 17881-17888.
43	YU X Y , FENG Y , JEON Y , et al . Formation of Ni-Co-MoS₂ nanoboxes with enhanced electrocatalytic activity for hydrogen evolution[J]. Adv. Mater., 2016, 28(40): 9006-9011.
44	XIAO W , LIU P , ZHANG J , et al . Dual-functional N dopants in edges and basal plane of MoS₂ nanosheets toward efficient and durable hydrogen evolution[J]. Advanced Energy Materials, 2017, 7(7): 1602086.
45	HUANG X , LENG M , XIAO W , et al . Activating basal planes and S-terminated edges of MoS₂ toward more efficient hydrogen evolution[J]. Advanced Functional Materials, 2016, 27(6): 1604943.
46	XIONG Q , WANG Y , LIU P F , et al . Cobalt covalent doping in MoS₂ to induce bifunctionality of overall water splitting[J]. Adv. Mater., 2018, 30(29): 1801450.
47	LUKOWSKI M A , DANIEL A S , MENG F , et al . Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS₂ nanosheets[J]. Journal of the American Chemical Society, 2013, 135(28): 10274-10277.
48	WANG H , LU Z , XU S , et al . Electrochemical tuning of vertically aligned MoS₂ nanofilms and its application in improving hydrogen evolution reaction[J]. Proc. Natl. Acad. Sci. USA, 2013, 110(49): 19701-19706.
49	VOIRY D , SALEHI M , SILVA R , et al . Conducting MoS₂ nanosheets as catalysts for hydrogen evolution reaction[J]. Nano Letters, 2013, 13(12): 6222-6227.
50	ZHANG J , WU J , GUO H , et al . Unveiling active sites for the hydrogen evolution reaction on monolayer MoS₂ [J]. Advanced Materials, 2017, 29(42): 1701955.
51	WANG S , ZHANG D , LI B , et al . Ultrastable in-plane 1T-2H MoS₂ heterostructures for enhanced hydrogen evolution reaction[J]. Advanced Energy Materials, 2018, 8(25): 1801345.
52	LI H , CHEN S , JIA X , et al . Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting[J]. Nat. Commun., 2017, 8: 15377.
53	YU Y , HUANG S Y , LI Y , et al . Layer-dependent electrocatalysis of MoS₂ for hydrogen evolution[J]. Nano Lett., 2014, 14(2): 553-558.
54	YAN Y , XIA B , LI N , et al . Vertically oriented MoS₂ and WS₂ nanosheets directly grown on carbon cloth as efficient and stable 3-dimensional hydrogen-evolving cathodes[J]. Journal of Materials Chemistry A, 2015, 3(1): 131-135.
55	YU H , YU X , CHEN Y , et al . A strategy to synergistically increase the number of active edge sites and the conductivity of MoS₂ nanosheets for hydrogen evolution[J]. Nanoscale, 2015, 7(19): 8731-8738.
56	ZHANG Z , LI W , YUEN M F , et al . Hierarchical composite structure of few-layers MoS₂ nanosheets supported by vertical graphene on carbon cloth for high-performance hydrogen evolution reaction[J]. Nano Energy, 2015, 18: 196-204.
57	ZHANG Z , LI W , YUEN M F , et al . Hierarchical composite structure of few-layers MoS₂ nanosheets supported by vertical graphene on carbon cloth for high-performance hydrogen evolution reaction[J]. Nano Energy, 2015, 18: 196-204.
58	NIKAM R D , LU A Y , SONAWANE P A , et al . Three-dimensional heterostructures of MoS₂ nanosheets on conducting MoO₂ as an efficient electrocatalyst to enhance hydrogen evolution reaction[J]. ACS Appl. Mater. Interfaces, 2015, 7(41): 23328-23335.
59	SU C , XIANG J , WEN F , et al . Microwave synthesized three-dimensional hierarchical nanostructure CoS₂/MoS₂ growth on carbon fiber cloth: a bifunctional electrode for hydrogen evolution reaction and supercapacitor[J]. Electrochimica Acta, 2016, 212:941-949.
60	MIAO J , XIAO F X , YANG H B , et al . Hierarchical Ni-Mo-S nanosheets on carbon fiber cloth: a flexible electrode for efficient hydrogen generation in neutral electrolyte[J]. Science Advances, 2015, 1(7): e1500259.
61	ZHU H , LYU F , DU M , et al . Design of two-dimensional, ultrathin MoS₂ nanoplates fabricated within one-dimensional carbon nanofibers with thermosensitive morphology: high-performance electrocatalysts for the hydrogen evolution reaction[J]. ACS Appl. Mater. Interfaces, 2014, 6(24): 22126-22137.
62	OUYANG C , FENG S , HUO J , et al . Three-dimensional hierarchical MoS₂ /CoS₂ heterostructure arrays for highly efficient electrocatalytic hydrogen evolution[J]. Green Energy & Environment, 2017, 2(2): 134-141.
63	ZHOU W , ZHOU K , HOU D , et al . Three-dimensional hierarchical frameworks based on MoS₂ nanosheets self-assembled on graphene oxide for efficient electrocatalytic hydrogen evolution[J]. ACS Appl. Mater. Interfaces, 2014, 6(23): 21534-21540.
64	YANG Y , FEI H , RUAN G , et al . Edge-oriented MoS₂ nanoporous films as flexible electrodes for hydrogen evolution reactions and supercapacitor devices[J]. Adv. Mater., 2014, 26(48): 8163-8168.
65	HAN G-Q , LI X , XUE J , et al . Electrodeposited hybrid Ni-P/MoS _x film as efficient electrocatalyst for hydrogen evolution in alkaline media[J]. International Journal of Hydrogen Energy, 2017, 42(5): 2952-2960.
66	CHEN S , DUAN J , TANG Y , et al . Molybdenum sulfide clusters-nitrogen-doped graphene hybrid hydrogel film as an efficient three-dimensional hydrogen evolution electrocatalyst[J]. Nano Energy, 2015, 11: 11-18.
67	HU W H , SHANG X , HAN G Q , et al . MoS _x supported graphene oxides with different degree of oxidation as efficient electrocatalysts for hydrogen evolution[J]. Carbon, 2016, 100: 236-242.
68	ZHANG N , GAN S , WU T , et al . Growth control of MoS₂ nanosheets on carbon cloth for maximum active edges exposed: an excellent hydrogen evolution 3D cathode[J]. ACS Appl. Mater. Interfaces, 2015, 7(22): 12193-12202.
69	MA C B, QI X , CHEN B , et al . MoS₂ nanoflower-decorated reduced graphene oxide paper for high-performance hydrogen evolution reaction[J]. Nanoscale, 2014, 6(11): 5624-5629.
70	BEHRANGINIA A , ASADI M , LIU C , et al . Highly efficient hydrogen evolution reaction using crystalline layered three-dimensional molybdenum disulfides grown on graphene film[J]. Chemistry of Materials, 2016, 28(2): 549-555.

种类	催化剂	起始过电位/mV	10mA·cm^-2相应过电位/mV	塔菲尔斜率/mV·dec^-1	参考文献
纯二硫化钼型	二硫化钼纳米带	170	约180	70	[64]
	富缺陷二硫化钼	120	约180	50	[39]
	1T相二硫化钼	100	约200	40	[49]
	氧掺杂二硫化钼	120	约180	55	[42]
	双螺旋二硫化钼	—	206	50	[36]
	镍-磷/多硫化钼	—	140	64	[65]
	量子点二硫化钼	约120	约250	69	[34]
基底型	石墨烯基二硫化钼	约100	150	41	[24]
	氮杂石墨烯二硫化钼	100	146	105	[66]
	二硫化钼/还原性石墨烯	约140	—	46	[25]
	介孔石墨烯基二硫化钼	100	—	42	[27]
	二硫化钼/氮杂还原性石墨烯	5	56	41.3	[31]
	低结晶度二硫化钼	90	约170	40	[26]
	多硫化钼/氧化石墨烯	—	约180	47.7	[67]
自支撑型	二硫化钼/碳布	100	150	50	[54]
	二硫化钼/碳布	100	—	39	[68]
	二氧化钼/还原性氧化石墨烯	190	—	95	[69]
	二硫化钼/氧化石墨烯膜	70	100	41	[70]
	二硫化钼/玻碳	约200	约400	约105	[17]
	二硫化钼/二氧化钼/碳布	142	约200	35.6	[57]
	二硫化钼/二硫化钴/碳布	—	87	73.4	[58]
	镍杂硫化钼/碳布	130	约200	85.4	[60]
	二硫化钼/石墨烯骨架	107	—	86.3	[63]

种类	催化剂	起始过电位/mV	10mA·cm^-2相应过电位/mV	塔菲尔斜率/mV·dec^-1	参考文献
纯二硫化钼型	二硫化钼纳米带	170	约180	70	[64]
	富缺陷二硫化钼	120	约180	50	[39]
	1T相二硫化钼	100	约200	40	[49]
	氧掺杂二硫化钼	120	约180	55	[42]
	双螺旋二硫化钼	—	206	50	[36]
	镍-磷/多硫化钼	—	140	64	[65]
	量子点二硫化钼	约120	约250	69	[34]
基底型	石墨烯基二硫化钼	约100	150	41	[24]
	氮杂石墨烯二硫化钼	100	146	105	[66]
	二硫化钼/还原性石墨烯	约140	—	46	[25]
	介孔石墨烯基二硫化钼	100	—	42	[27]
	二硫化钼/氮杂还原性石墨烯	5	56	41.3	[31]
	低结晶度二硫化钼	90	约170	40	[26]
	多硫化钼/氧化石墨烯	—	约180	47.7	[67]
自支撑型	二硫化钼/碳布	100	150	50	[54]
	二硫化钼/碳布	100	—	39	[68]
	二氧化钼/还原性氧化石墨烯	190	—	95	[69]
	二硫化钼/氧化石墨烯膜	70	100	41	[70]
	二硫化钼/玻碳	约200	约400	约105	[17]
	二硫化钼/二氧化钼/碳布	142	约200	35.6	[57]
	二硫化钼/二硫化钴/碳布	—	87	73.4	[58]
	镍杂硫化钼/碳布	130	约200	85.4	[60]
	二硫化钼/石墨烯骨架	107	—	86.3	[63]

[1]	SHI Yongxing, LIN Gang, SUN Xiaohang, JIANG Weigeng, QIAO Dawei, YAN Binhang. Research progress on active sites in Cu-based catalysts for CO₂ hydrogenation to methanol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 287-298.
[2]	XIE Luyao, CHEN Songzhe, WANG Laijun, ZHANG Ping. Platinum-based catalysts for SO₂ depolarized electrolysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 299-309.
[3]	YANG Jianping. PSE for feedstock consumption reduction in reaction system of HPPO plant [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 21-32.
[4]	ZHANG Qi, ZHAO Hong, RONG Junfeng. Research progress of anti-toxicity electrocatalysts for oxygen reduction reaction in PEMFC [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4677-4691.
[5]	GE Quanqian, XU Mai, LIANG Xian, WANG Fengwu. Research progress on the application of MOFs in photoelectrocatalysis [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4692-4705.
[6]	SHI Keke, LIU Muzi, ZHAO Qiang, LI Jinping, LIU Guang. Properties and research progress of magnesium based hydrogen storage materials [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4731-4745.
[7]	LIU Muzi, SHI Keke, ZHAO Qiang, LI Jinping, LIU Guang. Research progress of solid hydrogen storage materials [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4746-4769.
[8]	MAO Shanjun, WANG Zhe, WANG Yong. Group recognition hydrogenation: From concept to application [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3917-3922.
[9]	WANG Lanjiang, LIANG Yu, TANG Qiong, TANG Mingxing, LI Xuekuan, LIU Lei, DONG Jinxiang. Synthesis of highly dispersed Pt/HY catalyst by rapid pyrolysis of platinum precursors and its performance for deep naphthalene hydrogenation [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4159-4166.
[10]	GUO Jin, ZHANG Geng, CHEN Guohua, ZHU Ming, TAN Yue, LI Wei, XIA Li, HU Kun. Research progress on vehicle liquid hydrogen cylinder design [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4221-4229.
[11]	ZHANG Yajuan, XU Hui, HU Bei, SHI Xingwei. Preparation of NiCoP/rGO/NF electrocatalyst by eletroless plating for efficient hydrogen evolution reaction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4275-4282.
[12]	WANG Xiaohan, ZHOU Yasong, YU Zhiqing, WEI Qiang, SUN Jinxiao, JIANG Peng. Synthesis and hydrocracking performance of Y molecular sieves with different crystal sizes [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4283-4295.
[13]	CHU Tiantian, LIU Runzhu, DU Gaohua, MA Jiahao, ZHANG Xiao’a, WANG Chengzhong, ZHANG Junying. Preparation and chemical degradability of organoguanidine-catalyzed dehydrogenation type RTV silicone rubbers [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3664-3673.
[14]	YU Shan, DUAN Yuangang, ZHANG Yixin, TANG Chun, FU Mengyao, HUANG Jinyuan, ZHOU Ying. Research progress of catalysts for two-step hydrogen sulfide decomposition to produce hydrogen and sulfur [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3780-3790.
[15]	SUN Xudong, ZHAO Yuying, LI Shirui, WANG Qi, LI Xiaojian, ZHANG Bo. Textual quantitative analysis on China’s local hydrogen energy development policies [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3478-3488.

MoS₂-based electrocatalysts for hydrogen evolution and the prospect of hydrogen energy technology

电解水制氢MoS₂催化剂研究与氢能技术展望

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 16

References 70

Related Articles 15

Recommended Articles

Metrics

Comments