Research progress of catalyst for ethylene carbonate synthesis from ethylene oxide and carbon dioxide

doi:10.16085/j.issn.1000-6613.2017.2017-1633

Abstract

Abstract: The production of cyclic carbonate from CO₂ through a cycloaddition reaction represents a green and atom economic process which captures,utilize and stores CO₂ using an industrial catalytic technology.Its economic benefits and emission reduction are unmatched by traditional carbon capture and storage technologies.This work aimed to review the current development of catalyst for the esterification reaction of CO₂ and ethylene oxide(EO),categorize types of catalyst,analyzed the effect of factors such as preparation,auxiliary reagents,carriers etc on the activity of esterification catalysts as well as a discussion over the outlook of such catalysts.

Key words: industrial catalysis, ethylene oxide, carbon dioxide, catalyst

摘要： 二氧化碳（CO₂）通过环加成工艺合成环状碳酸酯的反应不仅符合“绿色化学”和“原子经济性”的理念，还能减少工业尾气中CO₂的排放所引起的温室效应影响，是一种利用工业催化技术实现碳捕集、利用和封存（CCS）的新技术，其经济效益和减排效率是传统CCS技术无法比拟的。本文综述了CO₂和环氧乙烷（EO）酯化反应催化剂的研究现状，总结了酯化催化剂的种类，分析了影响酯化催化剂性能的因素，如制备、助剂和载体等，最后对该催化剂的发展前景进行了展望。

关键词: 工业催化, 环氧乙烷, 二氧化碳, 催化剂

CLC Number:

TQ032

TAN Yanan, HE Lin, WANG Kai, CHENG Muxi, WANG Ke, FU Songbao. Research progress of catalyst for ethylene carbonate synthesis from ethylene oxide and carbon dioxide[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 241-246.

谭亚南, 何霖, 王凯, 程牧曦, 王科, 傅送保. 环氧乙烷和二氧化碳合成碳酸乙烯酯催化剂研究进展[J]. 化工进展, 2017, 36(S1): 241-246.

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