Research status and research ideas of chrome tanning waste disposal

doi:10.16085/j.issn.1000-6613.2017-0860

Abstract

Abstract: The disposal of chromium containing tannery waste can recover the energy, chromium and collagen, but the unreasonable disposal has caused environment pollution and waste of resources. In this paper, the source and the current situation of disposal of chromium containing leather wastes were described. Based on the latest domestic and foreign chromium tanning waste processing literatures, the related researches of chrome tanning waste treatment and disposal were summarized. The disposal methods can be divided into two categories:direct treatment and indirect treatment. Three direct treatments including adsorbent, pyrolysis, incineration and four indirect treatments including oxidation, acid hydrolysis, alkaline hydrolysis, enzymatic hydrolysis were described in detail. The principle, advantages and disadvantages,and application prospect of each disposal method were analyzed. The main functions of various disposal methods were briefly described. Besides, the advantages and disadvantages of each method were compared. At last, the research ideas of chromium leather waste disposal were put forward. Especially, the mechanism of combustion and pollutant emission during the process of pyrolysis and incineration of chromium containing tannery wastes will be studied.

Key words: leather, chromium-tanning, waste, waste treatment, environment, resource utilization

摘要： 含铬制革废弃物经过适当处理可以回收其中的能量、重金属铬和胶原蛋白，但目前不合理的处置造成了环境污染及资源浪费。本文简述了含铬制革废弃物的来源和处置现状，综合国内外最新的含铬制革废弃物处理的文献，系统总结了含铬制革废弃物处理方式的相关研究，将处置方式分为直接处理和间接处理两大类分别进行阐述，详细介绍了吸附剂、热解、焚烧这3种直接处理方式及氧化法、酸水解法、碱水解法、酶水解法这4种间接处理方式，分析了每种处置方式的原理、存在的优缺点和应用前景，简述了各种处置方式的主要作用以及优缺点对比。最后提出了含铬制革废弃物处置的研究思路，特别是开展含铬制革废弃物热解和焚烧过程中燃烧和污染物排放机理研究。

关键词: 皮革, 含铬铬鞣, 废弃物, 废物处理, 环境, 资源化利用

CLC Number:

X705

JIANG Xuguang, FANG Chunqi, JIN Yuqi, LÜ Guojun, YUAN Weizhong, CHEN Xijiong, LUO Weizhong. Research status and research ideas of chrome tanning waste disposal[J]. Chemical Industry and Engineering Progress, 2018, 37(02): 752-760.

蒋旭光, 方纯琪, 金余其, 吕国钧, 袁伟中, 陈锡炯, 罗伟忠. 含铬制革废弃物处理的研究现状和研究思路[J]. 化工进展, 2018, 37(02): 752-760.

References

[1] KANAGARAJ J, SENTHILVELAN T, PANDA R C, et al. Eco-friendly waste management strategies for greener environment towards sustainable development in leather industry:a comprehensive review[J]. Journal of Cleaner Production, 2015, 89:1-17.
[2] JIANG H, LIU J, HAN W. The status and developments of leather solid waste treatment:a mini-review[J]. Waste Management & Research, 2016, 34(5):399-408.
[3] FELA K, WIECZOREKCIUROWA K, KONOPKA M, et al. Present and prospective leather industry waste disposal[J]. Polish Journal of Chemical Technology, 2011, 13(3):53-55.
[4] PATI A, CHAUDHARY R, SUBRAMANI S. A review on management of chrome-tanned leather shavings:a holistic paradigm to combat the environmental issues[J]. Environmental Science and Pollution Research, 2014, 21(19):11266-11282.
[5] 陈春燕,范浩军,冯萍. 制革固体废弃物的综合利用技术及其新进展[J]. 皮革科学与工程, 2008, 18(5):27-33. CHEN C Y, FAN H J, FENG P. Development of comprehensive utilization of leather solid waste[J]. Leather Science & Engineering, 2008, 18(5):27-33.
[6] PANDEY B D. Remediation options for the treatment of electroplating and leather tanning effluent containing chromium——a review[J]. Mineral Processing & Extractive Metallurgy Review, 2006, 27(2):99-130.
[7] TIREZ K, SILVERSMIT G, BLEUX N, et al. Determination of hexavalent chromium in ambient air:a story of method induced Cr(Ⅲ) oxidation[J]. Atmospheric Environment, 2011, 45(30):5332-5341.
[8] 周文,但卫华. 制革工业含铬革屑资源化利用途径[J]. 西部皮革, 2011(18):50-56. ZHOU W, DAN W H. Recycle route of chrome-contained shavings produced by leather manufacturing[J]. West Leather, 2011(18):50-56.
[9] ONENC S, KILINCLI O, ISMAIL C K, et al. Use of solid wastes from the leather industry as an adsorbent[J]. Journal of Residuals Science & Technology, 2011, 8(3):131-139.
[10] GAMMOUN A G, TAHIRI S T, ALBIZANE A A, et al. Decontamination of water polluted with oil through the use of tanneds solid waste[J]. Journal of Environmental Engineering & Science, 2007, 6(5):553-559.
[11] OLIVEIRA L C A, GONÇALVES M, OLIVEIRA D Q L, et al. Solid waste from leather industry as adsorbent of organic dyes in aqueous-medium[J]. Journal of Hazardous Materials, 2007, 141(1):344-347.
[12] 廖学品,张米娜,王茹,等. 制革固体废弃物的吸附特性[J]. 化工学报, 2004, 55(12):2051-2059. LIAO X P, ZHANG M N, WANG R, et al. Adsorption behavior of solid waste of leather manufacture[J]. Journal of Chemical Industry & Engineering, 2004, 55(12):2051-2059.
[13] 任涛, 廖学品, 石碧, 等. 含铬废革屑负载锆对水中氟的吸附[J]. 皮革科学与工程, 2009, 19(3):5-9. REN T, LIAO X P, SHI B, et al. Adsorption of fluoride from aqueous solution by Zr(Ⅳ) loaded chromic leather waste[J]. Leather Science & Engineering, 2009, 19(3):5-9.
[14] OLIVEIRA L C A, GUERREIRO M C, GONÇALVES M, et al. Preparation of activated carbon from leather waste:a new material containing small particle of chromium oxide[J]. Materials Letters, 2008, 62(21/22):3710-3712.
[15] KONG J, YUE Q, HUANG L, et al. Preparation, characterization and evaluation of adsorptive properties of leather waste based activated carbon via physical and chemical activation[J]. Chemical Engineering Journal, 2013, 221(2):62-71.
[16] OLIVEIRA L C. Removal of organic dyes using Cr-containing activated carbon prepared from leather waste[J]. Journal of Hazardous Materials, 2011, 192:1094-1099.
[17] KANTARLI I C, YANIK J. Activated carbon from leather shaving wastes and its application in removal of toxic materials[J]. Journal of Hazardous Materials, 2010, 179(1/2/3):348-356.
[18] OLIVEIRA D Q, GONÇALVES M, OLIVEIRA L C, et al. Removal of As(Ⅰ) and Cr(Ⅵ) from aqueous solutions using solid waste from leather industry[J]. Journal of Hazardous Materials, 2008, 151(1):280.
[19] KANTARLI I C, YUKSEL M, SAGLAM M, et al. Conversion of leather wastes to useful products[J]. Resources Conservation & Recycling, 2007, 49(4):436-448.
[20] 王全杰, 张燕. 铬革屑酶解因素研究[J]. 中国皮革, 2011, 40(11):14-17. WANG Q J, ZHANG Y. Factors influencing enzymatic hydrolysis of chrome shavings from leather processing[J]. China Leather, 2011, 40(11):14-17.
[21] 金前争,王海宁,张世红,等. 铬革屑热解NO、NH₃和HCN的释放特性[J]. 化工学报, 2016, 67(12):5291-5297. JIN Q F, WANG H N, ZHANG S H, et al. Release of NO, NH₃ and HCN during pyrolysis of chrome shaving[J]. CIESC Journal, 2016, 67(12):5291-5297.
[22] 王海宁,张世红,李攀,等. 温度对铬革屑热解产物及特性的影响[J]. 化工学报, 2014, 65(8):3152-3158. WANG H N, ZHANG S H, LI P, et al. Effects of temperature on pyrolysis products and characteristics of chrome shavings[J]. CIESC Journal, 2014, 65(8):3152-3158.
[23] MARCILLA A, GARCÍA A N, LEÓN M, et al. Study of the influence of NaOH treatment on the pyrolysis of different leather tanned using thermogravimetric analysis and Py/GC-MS system[J]. Journal of Analytical & Applied Pyrolysis, 2011, 92(1):194-201.
[24] SETHURAMAN M C, SRINIVAS M K, SEKARAN G. Double pyrolysis of chrome tanned leather solid waste for safe disposal and products recovery[J]. International Journal of Scientific & Engineering Research, 2014, 4(11):61-67.
[25] SETHURAMAN M C, SRINIVAS M K, SEKARAN G. Pyrolysis coupled pulse oxygen incineration for disposal of hazardous chromium impregnated fine particulate solid waste generated from leather industry[J]. Journal of Environmental Chemical Engineering, 2014, 2(1):516-524.
[26] BASEGIO T, HAAS C, POKORNY A, et al. Production of materials with alumina and ashes from incineration of chromium tanned leather shavings:environmental and technical aspects[J]. Journal of Hazardous Materials, 2006, 137(2):1156-1164.
[27] SWARNALATHA S, KUMAR A G, TANDAIAH S, et al. Efficient and safe disposal of chrome shavings discharged from leather industry using thermal combustion[J]. Journal of Chemical Technology & Biotechnology, 2009, 84(5):751-760.
[28] BAHILLO A, ARMESTO L, CABANILLAS A, et al. Thermal valorization of footwear leather wastes in bubbling fluidized bed combustion[J]. Waste Management, 2004, 24(9):935-44.
[29] ERDEM M. Chromium recovery from chrome shaving generated in tanning process[J]. Journal of Hazardous Materials, 2006, 129(1/2/3):143-146.
[30] 陈驰,但卫华,曾睿,等. 含铬革屑氧化脱铬的研究[J]. 皮革科学与工程, 2006, 16(2):22-25. CHEN C, DAN W H, ZENG R, et al. Study on oxidation dechrome for shaving containing chrome[J]. Leather Science & Engineering, 2006, 16(2):22-25.
[31] 袁文慧, 张丽平, 李宏伟, 等. 含铬革屑氧化法脱铬工艺研究[J]. 皮革与化工, 2011, 28(2):6-9. YUAN W H, ZHANG L P, LI H W, et al. Dechroming process of chrome shavings by oxidation[J]. Leather & Chemicals,2011,28(2):6-9.
[32] 孙丹红,石碧,彭必雨,等. 含铬废革屑在超声波作用下的氧化脱铬[J]. 四川大学学报(工程科学版), 2003, 35(6):71-74. SUN D H, SHI B, PENG B Y, et al. Oxidative dechroming of chrome-containing leather shavings under the effect of ultrasound[J]. Journal of Sichuan University(Engineering Science Edition), 2003, 35(6):71-74.
[33] FERREIRA M J, ALMEIDA M F, PINHO S C, et al. Finished leather waste chromium acid extraction and anaerobic biodegradation of the products[J]. Waste Management, 2010, 30(6):1091-1100.
[34] RAI A K, NIVED C, SAKHARE P Z, et al. Optimization of acid hydrolysis conditions of delimed tannery by response surface methodology[J]. Journal Ofentific & Industrial Research, 2009, 68(11):967-974.
[35] 王群,张素风,豆莞莞,等. 水解胶原蛋白在造纸工业中的应用研究[J]. 中国皮革, 2015(5):25-28. WANG Q, ZHANG S F, DOU W W, et al. Application of hydrolyzed collagen in paper industry[J]. China Leather, 2015(5):25-28.
[36] 王学川,郝晓丽,任龙芳,等. 基于废弃皮胶原改性的造纸表面施胶剂的制备及表征[J]. 功能材料, 2014, 45(9):61-64. WANG X C, HAO X L, REN L F, et al. Study on the preparation and characterization of the surface sizing agent for papers based on leather wastes[J]. Journal of Functional Materials, 2014, 45(9):61-64.
[37] TAYLOR M M, DIEFENDORF E J, THOMPSON C J, et al. Extraction and characterization of "chrome-free" protein from chromium-containing collagenous waste generated in the leather industry[J]. Anesthesia Progress, 1994, 52(4):132-135.
[38] BELTRÁN-PRIETO J C, VELOZ-RODRÍGUEZ R, PÉREZ-PÉREZ M C, et al. Chromium recovery from solid leather waste by chemical treatment and optimisation by response surface methodology[J]. Chemistry & Ecology, 2012, 28(1):89-102.
[39] 赵佳华,王琴,单志华. 废革屑脱铬及复合碱法探究[J]. 皮革科学与工程, 2016, 26(5):68-70. ZHAO J H, WANG Q, DAN Z H. Exploration of chrome shavings dechromed by composite alkali[J]. Leather Science & Engineering, 2016, 26(5):68-70.
[40] 方晓林,徐志刚,王萍,等. 废铬革屑的综合回收利用[J]. 化学研究与应用, 2008, 20(1):100-103. FANG X L, XU Z G, WANG P, et al. Integrative utilization of chromium-containing leather waste[J]. Chemical Research & Application, 2008, 20(1):100-103.
[41] 张莹,魏玉娟. 废革屑提取胶原蛋白的研究[J]. 中国皮革, 2008(5):36-40. ZHANG Y, WEI Y J. Study on collagen extraction from chrome shavings[J]. China Leather, 2008(5):36-40.
[42] 强西怀,冯洪燕,张辉,等. 碱酶结合法从废铬革屑中提取胶原蛋白的工艺方法[J]. 中国皮革, 2011, 40(1):5-8. QIANG X H, FENG H Y, ZHANG H, et al. Collagen extraction from chrome shavings using alkali and enzyme[J]. China Leather, 2011, 40(1):5-8.
[43] NICULESCU M, BAJENARU S, GAIDAU C, et al. Extraction of the protein components as amino-acids hydrolysates from chrome leather wastes through hydrolytic processes[J]. Revista de Chimie (Bucharest), 2009, 60(10):1070-1078.
[44] 王学川,商跃美,任龙芳,等. 废皮胶原蛋白基造纸表面施胶剂的制备、表征及应用性能研究[J]. 功能材料, 2016, 47(3):210-214. WANG X C, SHANG Y M, REN L F, et al. Preparation, characterization and application performance of the surface sizing agent for papers based on collagen from leather wastes[J]. Journal of Functional Materials, 2016, 47(3):210-214.