Research progress of sodium manganate oxide Na0.44MnO2 as cathode for sodium-ion batteries

doi:10.16085/j.issn.1000-6613.2017-0015

Abstract

Abstract: Sodium-ion secondary batteries have attracted global attentions nowadays,and the tunnel-structure-crystalized Na_0.44MnO₂,as one of the main cathode materials,not only well provides the non-aqueous batteries with high energy density and outstanding cyclic stability,but also applies promisingly in the safe and high rate aqueous batteries. To summarize the relevant progress,the crystal structure,principles of charging and discharging of Na_0.44MnO₂ are discussed with the focus on the synthesis methods and their effects on the structure and electrochemical properties of Na_0.44MnO₂. In addition,the applications of Na_0.44MnO₂ material in the full-cells and the aqueous batteries and the recent research progress on the doping and coating modification of this material are also briefly introduced. It is concluded that Na_0.44MnO₂ material has great scientific value and application prospects as sodium-ion battery cathode material in the future.

Key words: sodium ion battery, cathode material, Na_0.44MnO₂, electrochemistry, synthesis, nanomaterials

摘要： 钠离子电池的研究开发在国内外处于迅速发展的浪潮中，而具有隧道结构的Na_0.44MnO₂作为正极材料具有既可以支持高能量密度和长循环寿命的非水电解质电池，也可以支持安全和高倍率的水溶液电解质电池的优点，成为一个重要的研究热点。本文比较系统地综述了Na_0.44MnO₂作为钠离子电池正极材料的研究现状，从晶体结构和充放电机理等方面进行了讨论，重点阐述了Na_0.44MnO₂材料的合成方法以及不同的合成方法对其结构形貌和电化学性能的影响，同时，也介绍了Na_0.44MnO₂材料在全电池和水系电池中的应用现状和前景以及对Na_0.44MnO₂正极材料掺杂和表面包覆等改性方面的研究进展，并且总结分析了改性工艺对其结构与电化学性能的影响，认为Na_0.44MnO₂材料对于钠离子电池仍具有极大的科研价值和应用前景。

关键词: 钠离子电池, 正极材料, 锰酸钠, 电化学, 合成, 纳米材料

CLC Number:

TM912.9

SHI Wenjing, YAN Yongwang, XU Shoudong, CHEN Liang, LIU Shibin, ZHANG Ding. Research progress of sodium manganate oxide Na_0.44MnO₂ as cathode for sodium-ion batteries[J]. Chemical Industry and Engineering Progress, 2017, 36(09): 3343-3352.

史文静, 燕永旺, 徐守冬, 陈良, 刘世斌, 张鼎. 钠离子电池正极材料Na_0.44MnO₂的研究进展[J]. 化工进展, 2017, 36(09): 3343-3352.

References

[1] MIN J W,YIM C J,IM W B.Facile synthesis of electrospun Li_1.2Ni_0.17Co_0.17Mn_0.5O₂ nanofiber and its enhanced high-rate performance for lithium-ion battery applications[J].ACS Applied Materials & Interfaces,2013,5(16):7765-7769.
[2] PAN H L,HU Y S,CHEN L Q.Room-temperature stationary sodium-ion batteries for large-scale electric energy storage[J].Energy & Environmental Science,2013,6(8):2338-2360.
[3] MINAKSHI M,MEYRICK D.Electrochemical energy storage device for securing future renewable energy[J].Electrochimica Acta,2013,101:66-70.
[4] LIU X,ZHANG N,NI J F,et al.Improved electrochemical performance of sol-gel method prepared Na₄Mn₉O₁₈ in aqueous hybrid Na-ion supercapacitor[J]. Journal of Solid State Electrochemistry,2013,17(7):1939-1944.
[5] PALOMARES V,SERRAS P,VILLALUENGA I,et al.Na-ion batteries,recent advances and present challenges to become low cost energy storage systems[J].Energy & Environmental Science,2012,5(3):5884-5901.
[6] MASQUELIER C,CROGUENNEC L.Polyanionic(phosphates,silicates,sulfates) frameworks as electrode materials for rechargeable Li (or Na) batteries[J].Chemical Reviews,2013,113(8):6552-6591.
[7] ISLAM M S,FISHER C A J.Lithium and sodium battery cathode materials:computational insights into voltage,diffusion and nanostructural properties[J].Chemical Society Reviews,2014,43:185-204.
[8] YABUUCHI N,KUBOTA K,DAHBI M,et al.Research development on sodium-ion batteries[J].Chemical Reviews,2014,114(23):11636-11682.
[9] KUNDU D,TALAIE E,DUFFORT V,et al.The emerging chemistry of sodium ion batteries for electrochemical energy storage[J].Angew.Chem.Int.Ed.,2015,54(11):3431-3448.
[10] 张传香,何建平,赵桂网,等.掺碳的钠离子电池正极材料NaVPO₄F的电化学性能[J].无机化学学报,2007,23(4):649-654. ZHANG C X,HE J P,ZHAO G W,et al.Electrochemical characteristics of C-doped NaVPO₄F cathode material for sodium-ion battery[J].Chinese Journal of Inorganic Chemistry,2007,23(4):649-654.
[11] 叶飞鹏,王莉,连芳,等.钠离子电池研究进展[J].化工进展,2013,32(8):1789-1795. YE F P,WANG L,LIAN F,et al.Advance in Na-ion batteries[J].Chemical Industry and Engineering Progress,2013,32(8):1789-1795.
[12] YUAN D D,HE W,PEI F,et al.Synthesis and electrochemical behaviors of layered Na_0.67[Mn_0.65Co_0.2Ni_0.15] O₂ microflakes as a stable cathode material for sodium-ion batteries[J].Journal of Materials Chemistry A,2013,1(12):3895-3899.
[13] XU J,LEE D H,CLEMENT R J,et al.Identifying the critical role of Li substitution in P2-Na_x[Li_yNi_zMn_1-y-z]O₂(0[14] YOSHIDA H,YABUUCHI N,KUBOTA K,et al.P2-type Na_2/3Ni_1/3Mn_2/3-xTi_xO₂ as a new positive electrode for higher energy Na-ion batteries[J].Chem.Commun.,2014,50(28):3677-3680.
[15] ZHU H L,LEE K T,HITZ G T,et al.Free-standing Na_2/3Fe_1/2Mn_1/2O₂@graphene film for a sodium-ion battery cathode[J].ACS Applied Materials & Interfaces,2014,6(6):4242-4247.
[16] WHITACRE J F,TEVAR A,SHARMA S.Na₄Mn₉O₁₈ as a positive electrode material for an aqueous electrolyte sodium-ion energy storage device[J].Electrochemistry Communications,2010,12(3):463-466.
[17] DOEFF M M,RICHARDSON T J,KEPLEY L.Orthorhombic NaxMnO₂ as a cathode material for secondary sodium[J]. J. Electrochem.Soc.,1996,143(8):2507-2516.
[18] KIM H,KIM D J,SEO D H,et al.Ab initio study of the sodium intercalation and intermediate phases in Na_0.44MnO₂ for sodium-ion battery[J].Chemistry of Materials,2012,24(6):1205-1211.
[19] ZHAN P,WANG S,YUAN Y,et al.Facile synthesis of nanorod-like single crystalline Na_0.44MnO₂ for high performance sodium-ion batteries[J].Journal of the Electrochemical Society,2015,162(6):A1028-A1032.
[20] WANG Y S,LIU J,LEE B,et al.Ti-substituted tunnel-type Na_0.44MnO₂ oxide as a negative electrode for aqueous sodium-ion batteries[J].Nature Communications,2015,6:6401-6410.
[21] SAUVAGE F,LAFFONT L,TARASCON J M,et al.Study of the insertion/deinsertion mechanism of sodium into Na_0.44MnO₂[J]. Inorganic Chemistry,2007,46(8):3289-3294.
[22] DAI K H,MAO J,SONG X Y,et al.Na_0.44MnO₂ with very fast sodium diffusion and stable cycling synthesized via polyvinylpyrrolidone-combustion method[J]. Journal of Power Sources,2015,285:161-168.
[23] PARANT J P,OLAZCUAGA R,DEVALETTE M,et al.Sur quelques nouvelles phases de formule NaxMnO₂(x ≤ 1)[J]. Journal of Solid State Chemistry,1971,3:1-11.
[24] ZHAO L W,NI J F,WANG H B,et al.Flux synthesis of Na_0.44MnO₂ nanorbbons and their electrochemical properties for Na-ion batteries[J].Functional Materials Letters,2013,6(2):1350012.
[25] DEMIREL S,OZ E,ALTIN E,et al.Growth mechanism and magnetic and electrochemical properties of Na_0.44MnO₂ nanorods as cathode material for Na-ion batteries[J].Materials Characterization,2015,105:104-112.
[26] MA G Y,ZHAO Y,HUANG K S,et al.Effects of the starting materials of Na_0.44MnO₂ cathode materials on their electrochemical properties for Na-ion batteries[J].Electrochimica Acta,2016,222:36-43.
[27] HOSONO E,MATSUDA H,HONMA I,et al.Synthesis of single crystalline electro-conductive Na_0.44MnO₂ nanowires with high aspect ratio for the fast charge-discharge Li ion battery[J].Journal of Power Sources,2008,182(1):349-352.
[28] QIAO R M,DAI K H,MAO J,et al.Revealing and suppressing surface Mn(Ⅱ) formation of Na_0.44MnO₂ electrodes for Na-ion batteries[J].Nano Energy,2015,16:186-195.
[29] ZHAO L W,NI J F,WANG H B,et al.Na_0.44MnO₂-CNT electrodes for non-aqueous sodium batteries[J].RSC Advances,2013,3(18):6650-6655.
[30] HOSONO E,SAITO T,HOSHINO J,et al.High power Na-ion rechargeable battery with single-crystalline Na_0.44MnO₂ nanowire electrode[J].Journal of Power Sources,2012,217:43-46.
[31] LI Y G,WU Y Y.Formation of Na_0.44MnO₂ nanowires via stress-induced splitting of birnessite nanosheets[J].Nano Research,2009,2(1):54-60.
[32] XU M W,NIU Y B,CHEN C J,et al.Synthesis and application of ultra-long Na_0.44MnO₂ submicron slabs as a cathode material for Na-ion batteries[J].RSC Advance,2014,4:38140-38143.
[33] CAO Y L,XIAO L F,WANG W,et al.Reversible sodium ion insertion in single crystalline manganese oxide nanowires with long cycle life[J].Adv.Mater.,2011,23(28):3155-3160.
[34] YU L H,YANG H X,AI X P,et al.Structural and electrochemical characterization of nanocrystalline Li[Li_0.12Ni_0.32Mn_0.56] O₂ synthesized by a polymer-pyrolysis route[J]. J.Phys.Chem.,2005,109:1148-1154.
[35] 程永亮,宋武林,谢长生.燃烧法制备氧化物纳米材料的研究进展[J].材料导报,2013,17(7):70-72. CHENG Y L,SONG W L,XIE C S.Advances in preparation of oxide nanoparticles by combustion method[J].Materials Herald,2013,17(7):70-72.
[36] 陶菲,沈俊,张昭.溶胶-凝胶-酯化法制备锂离子电池正极材料尖晶石LiMn₂O₄[J].四川有色金属,2003(3):18-21. TAO F,SHEN J,ZHANG Z.Synthesis of spinel LiMn₂O₄ for lithium-ion batteries as electrode material by sol-gel-ester method[J].Sichuan Nonferrous Metals,2003(3):18-21.
[37] KIM D J,PONRAJ R,KANNAN A G,et al.Diffusion behavior of sodium ions in Na_0.44MnO₂ in aqueous and non-aqueous electrolytes[J].Journal of Power Sources,2013,244:758-763.
[38] RUFFO R,FATHI R,KIM D J,et al.Impedance analysis of Na_0.44MnO₂ positive electrode for reversible sodium batteries in organic electrolyte[J]. Electrochimica Acta,2013,108:575-582.
[39] AKIMOTO J,HAYAKAWA H,KIJIMA N,et al.Single-crystal synthesis and structure refinement of Na_0.44MnO₂[J].Solid State Phenomena,2011,170:198-202.
[40] CHU Q X,WANG X F,LI B X,et al.Flux synthesis and growth mechanism of Na_0.5MnO₂ whiskers[J].Journal of Crystal Growth,2011,322(1):103-108.
[41] YU J Y,HONG M,WANG L,et al.Synthesis and gas-sensing properties of P-type Na_0.44MnO₂ nanoribbons[J].Materials Letters,2016,164:440-443.
[42] LI X L,YAN P F,ENGELHARD M H,et al.The importance of solid electrolyte interphase for mation for long cycle stability full-cell Na-ion batteries[J].Nano Energy,2016,27:664-672.
[43] TEVAR A D,WHITACRE J F.Relating synthesis conditions and electrochemical performance for the sodium intercalation compound Na₄Mn₉O₁₈ in aqueous electrolyte[J].Journal of the Electrochemical Society,2010,157(7):A870-A875.
[44] THACKERAY M M.Manganese oxides for lithium batteries[J]. Program Solid State Chemistry,1997,25:l-71.
[45] 周公度.结构化学基础[M].3版.北京:北京大学出版社,1989:28. ZHOU G D.The foundation of structural chemistry[M].3rd ed.Beijing:Peking University Press,1989:28.
[46] 赵铭姝,张国范,翟玉春,等.锂离子蓄电池正极材料尖晶石型锰酸锂的制备[J].电源技术,2011,25(3):246-250. ZHAO M S,ZHANG G F,ZHAI Y C,et al.Preparation of spinel-structure lithium manganese oxides,the positive materials for lithium-ion battery[J].Chinese Journal of Power Sources,2011,25(3):246-250.
[47] GUO S H,YU H J,LIU D Q,et al.A novel tunnel Na_0.61Ti_0.48Mn_0.52O₂ cathode material for sodium-ion batteries[J]. Chem.Commun.,2014,50(59):7998-8001.
[48] JAYAKUMAR M,HEMALATHA K,RAMESHA K,et al.Framework structured Na₄Mn₄Ti₅O₁₈ as an electrode for Na-ion storage hybrid devices[J].Phys.Chem.Chem.Phys.,2015,17(32):20733-20740.
[49] ZHAN P,JIAO K L,WANG J X,et al.Titanium-substituted Na_0.44MnO₂ nanorods as cathode materials for high performance sodium-ion batteries[J].Journal of the Electrochemical Society,2015,162(12):A2296-A2301.
[50] XU S Y,WANG Y S,BEN L B,et al.Fe-based tunnel-type Na_0.61[Mn_0.27Fe_0.34Ti_0.39] O₂ designed by a new strategy as a cathode material for sodium-ion batteries[J].Advanced Energy Materials,2015,5(22):1501156.
[51] WU Z G,ZHONG Y J,LI J T,et al.Synthesis of a novel tunnel Na_0.5K_0.1MnO₂ composite as a cathode for sodium ion batteries[J].RSC Adv.,2016,6(59):54404-54409.
[52] PARK J H,PARK K,KIM R H,et al.Improving the kinetics and surface stability of sodium manganese oxide cathode materials for sodium rechargeable batteries with Al₂O₃/MWCNT hybrid networks[J].J.Mater.Chem.A,2015,3(20):10730-10737.

Research progress of sodium manganate oxide Na_0.44MnO₂ as cathode for sodium-ion batteries

钠离子电池正极材料Na_0.44MnO₂的研究进展

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles 0

Metrics

Comments

[1]	MA Yi, CAO Shiwei, WANG Jiajun, LIN Liqun, XING Yan, CAO Tengliang, LU Feng, ZHAO Zhenlun, ZHANG Zhijun. Research progress in recovery of spent cathode materials for lithium-ion batteries using deep eutectic solvents [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 219-232.
[2]	ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286.
[3]	SHI Yongxing, LIN Gang, SUN Xiaohang, JIANG Weigeng, QIAO Dawei, YAN Binhang. Research progress on active sites in Cu-based catalysts for CO₂ hydrogenation to methanol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 287-298.
[4]	HU Xi, WANG Mingshan, LI Enzhi, HUANG Siming, CHEN Junchen, GUO Bingshu, YU Bo, MA Zhiyuan, LI Xing. Research progress on preparation and sodium storage properties of tungsten disulfide composites [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 344-355.
[5]	ZHANG Jie, BAI Zhongbo, FENG Baoxin, PENG Xiaolin, REN Weiwei, ZHANG Jingli, LIU Eryong. Effect of PEG and its compound additives on post-treatment of electrolytic copper foils [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 374-381.
[6]	ZHAO Wei, ZHAO Deyin, LI Shihan, LIU Hongda, SUN Jin, GUO Yanqiu. Synthesis and application of triazine drag reducing agent for nature gas pipeline [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 391-399.
[7]	WANG Zhengkun, LI Sifang. Green synthesis of gemini surfactant decyne diol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 400-410.
[8]	YANG Ying, HOU Haojie, HUANG Rui, CUI Yu, WANG Bing, LIU Jian, BAO Weiren, CHANG Liping, WANG Jiancheng, HAN Lina. Coal tar phenol-based carbon nanosphere prepared by Stöber method for adsorption of CO₂ [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 5011-5018.
[9]	YIN Xinyu, PI Pihui, WEN Xiufang, QIAN Yu. Application of special wettability materials for anti-hydrate-nucleation and anti-hydrate-adhesion in oil and gas pipelines [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4076-4092.
[10]	XIANG Yang, HUANG Xun, WEI Zidong. Recent progresses in the activity and selectivity improvement of electrocatalytic organic synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4005-4014.
[11]	WANG Yaogang, HAN Zishan, GAO Jiachen, WANG Xinyu, LI Siqi, YANG Quanhong, WENG Zhe. Strategies for regulating product selectivity of copper-based catalysts in electrochemical CO₂ reduction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4043-4057.
[12]	LIU Yi, FANG Qiang, ZHONG Dazhong, ZHAO Qiang, LI Jinping. Cu facets regulation of Ag/Cu coupled catalysts for electrocatalytic reduction of carbon dioxide [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4136-4142.
[13]	ZHANG Yajuan, XU Hui, HU Bei, SHI Xingwei. Preparation of NiCoP/rGO/NF electrocatalyst by eletroless plating for efficient hydrogen evolution reaction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4275-4282.
[14]	WANG Shuaiqing, YANG Siwen, LI Na, SUN Zhanying, AN Haoran. Research progress on element doped biomass carbon materials for electrochemical energy storage [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4296-4306.
[15]	LI Haidong, YANG Yuankun, GUO Shushu, WANG Benjin, YUE Tingting, FU Kaibin, WANG Zhe, HE Shouqin, YAO Jun, CHEN Shu. Effect of carbonization and calcination temperature on As(Ⅲ) removal performance of plant-based Fe-C microelectrolytic materials [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3652-3663.