Optimized preparation of foaming MF resin by multi-objective orthogonal experiment

doi:10.16085/j.issn.1000-6613.2015.02.026

Chemical Industry and Engineering Progree ›› 2015, Vol. 34 ›› Issue (02): 474-478.DOI: 10.16085/j.issn.1000-6613.2015.02.026

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Optimized preparation of foaming MF resin by multi-objective orthogonal experiment

LIU Junxia^1,2, YAO Qingxin¹, YANG Jin², ZHOU Lei², XIE Jianjun¹

1. School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410000, Hunan, China;
2. Zhuzhou Times New Material Technology Co., Ltd., Zhuzhou 412000, Hunan, China

Received:2014-07-01 Revised:2014-10-08 Online:2015-02-05 Published:2015-02-05

多指标正交实验优化可发性三聚氰胺甲醛树脂的制备

刘军霞^1,2, 姚庆鑫¹, 杨金², 周磊², 谢建军¹

1. 中南林业科技大学材料科学与工程学院, 湖南长沙 410000;
2. 株洲时代新材料科技股份有限公司, 湖南株洲 412000

通讯作者: 谢建军,教授,博士生导师,主要从事功能高分子材料、胶黏剂和聚合反应工程研究。E-mail:xiejianjun12@sina.com
作者简介:刘军霞(1989-),女,硕士研究生,主要从事功能高分子材料的研究
基金资助:
国家自然科学基金(31270603)、湖南省研究生科研创新项目(CX2013B347)及中南林业科技大学研究生创新基金(CX2013B10)项目

Abstract

Abstract: The effects of mole ratio of formaldehyde and melamine (F/M),solution pH,reaction temperature (T) and time (t) on the properties of foaming melamine-formaldehyde (MF) resin with caprolactam as modifier were investigated by orthogonal experiment where solid content,viscosity and storage time of the MF resin,density and size uniformity of the MF foam were used as performance evaluation parameters. The results of the experiments were analyzed by using the comprehensive scoring method and the integrated balance method. The optimum formula of preparation was obtained as follows:F/M=2.5,pH=8.0,T=90℃,t=60min. The MF resin prepared under the optimal conditions could be foamed well and the properties of the foam were good.

Key words: melamine-formaldehyde resin, foam, optimization, preparation, orthogonal experiment

摘要： 用己内酰胺作改性剂,通过正交实验设计考察了甲醛和三聚氰胺摩尔比(F/M)、溶液pH值、反应温度(T)和反应时间(t)对可发性三聚氰胺甲醛(MF)树脂的储存期、固含量、黏度、MF泡沫密度及泡孔尺寸均匀性的影响,运用综合评分法和综合平衡法对正交实验结果进行了分析,得出最优水平组合:F/M=2.5,pH=8.0,T=90℃,t=60min。最优条件下合成的MF树脂可发泡性良好,制得的泡沫性能优良。

关键词: 三聚氰胺甲醛树脂, 泡沫, 优化, 制备, 正交实验

CLC Number:

TQ322.4

LIU Junxia, YAO Qingxin, YANG Jin, ZHOU Lei, XIE Jianjun. Optimized preparation of foaming MF resin by multi-objective orthogonal experiment[J]. Chemical Industry and Engineering Progree, 2015, 34(02): 474-478.

刘军霞, 姚庆鑫, 杨金, 周磊, 谢建军. 多指标正交实验优化可发性三聚氰胺甲醛树脂的制备[J]. 化工进展, 2015, 34(02): 474-478.

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Optimized preparation of foaming MF resin by multi-objective orthogonal experiment

多指标正交实验优化可发性三聚氰胺甲醛树脂的制备

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