微生物合成金属纳米颗粒及在稠油催化降黏中的应用研究进展

doi:10.16085/j.issn.1000-6613.2020-1611

摘要/Abstract

摘要：

纳米材料的传统制备包括化学、物理和机械方法，近年来，生物技术制备金属纳米颗粒因其经济和环保的优势引起了广泛的关注。本文首先阐述了微生物合成金属纳米颗粒的原理，总结了影响纳米颗粒生物合成的条件以及生物合成纳米颗粒及其在生物质中稳定分散的优势；然后讨论了使用污染物作为生物合成纳米颗粒前体，即当金属前体来自污染物和受污染的废水时，微生物合成纳米颗粒既降低了生产成本又处理了废液；并且探讨了纳米颗粒的应用对环境和人类健康的影响，强调在应用中应提前实地评估其环保可行性。最后，重点阐述了金属纳米颗粒在稠油催化降黏中的催化作用、纳米催化稠油降黏中的加氢反应和氧化反应；介绍了金属纳米颗粒辅助稠油原位开采的热采方法；展望了合成仿生复合纳米催化材料的应用前景。

关键词: 金属纳米颗粒, 生物合成机制, 纳米催化剂, 稠油降黏, 可持续性发展

Abstract:

Several chemical, physical and mechanical methods could be used in the traditional preparation of nanomaterials. In recent years, the preparation of metal nanoparticles by biotechnology has attracted widespread attention due to its economic and environmental advantages. This review describes the principles of microbial synthesis of metal nanoparticles, the conditions that affect nanoparticle biosynthesis, the biosynthetic nanoparticles and their advantages of stable dispersion in biomass. Then the use of pollutants as biosynthetic nanoparticles is discussed. When metal precursors come from pollutants and contaminated wastewater, microbial synthesis of nanoparticles reduces production costs and treats waste liquids. The impact of the application of nanoparticles on the environment and human health is analyzed, and it is emphasized that the environmental feasibility should be assessed principally before the application. In addition, the discussion focuses on the catalytic effect of metal nanoparticles on the catalytic viscosity reduction of heavy oil, the hydrogenation and oxidation reactions of nano-catalyzed heavy oil viscosity reduction. The thermal recovery method of metal nanoparticles-assisted in-situ heavy oil recovery is also introduced. Finally, the application of synthetic biomimetic composite nano-catalytic materials are prospected.

Key words: metal nanoparticle, biosynthesis mechanism, nanocatalyst, heavy oil viscosity reduction, sustainable development

中图分类号:

TE39

冯阳阳, 赵众从, 杨文博, 胡琳琪, 张文达, 佘跃惠. 微生物合成金属纳米颗粒及在稠油催化降黏中的应用研究进展[J]. 化工进展, 2021, 40(4): 2215-2226.

FENG Yangyang, ZHAO Zhongcong, YANG Wenbo, HU Linqi, ZHANG Wenda, SHE Yuehui. Microbial natural synthetic metal nanoparticles and the application in heavy oil catalytic viscosity reduction[J]. Chemical Industry and Engineering Progress, 2021, 40(4): 2215-2226.

图/表 9

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细菌种类	细菌来源	合成金属	尺寸/nm	形状	应用	参考文献
蜡状芽孢杆菌	藤黄叶黄花菜	银	20~40	球形	抗菌	[21]
嗜单胞菌GSG2	从孟加拉湾收集的珊瑚样本	银，金	金 10~50，银 40~60	圆形，三角形，六边形	抗菌	[22]
马氏链霉菌	印度科钦水样沉积物样本	银	70	球形	抗菌	[23]
粪产碱菌	马纳尔湾曼达帕姆附近帕克湾的珊瑚	银	30~50	球形	抗菌和抗生物膜的活性	[24]
芽孢杆菌 CS11	印度科钦的土壤样品	银	42~92	球形	抗菌	[25]
Kocuria flava	印度的甘尼亚古马里海岸	铜	5~30	球形	抗菌	[26]
放射球菌	美国马纳萨斯文化收藏馆	银	4~50	球形	抗菌、抗生物污垢剂和抗癌	[27]
根瘤菌	海水	银	10	球形	抗菌	[28]
铜绿假单胞菌	曼多维河口红树林水样	银	35~60	球形，三角形	抗菌	[29]
希瓦氏菌PV-4	德国	钯，铂	2~7	球形	甲基橙染料的降解	[30]
莫氏菌	—	银	2~5	球形	抗菌	[31]
苍白杆菌属 MPV1	意大利托斯卡纳的砂	碲	—	大致球形，棒状	减少有毒化合物	[32]
枯草芽孢杆菌	印度胡蒂金矿	金	20~25	球形	亚甲基蓝的降解	[33]
短芽孢杆菌NCIM2533	印度浦那国家工业微生物保藏中心（NCL）	银	41~68	球形	抗菌	[34]

细菌种类	细菌来源	合成金属	尺寸/nm	形状	应用	参考文献
蜡状芽孢杆菌	藤黄叶黄花菜	银	20~40	球形	抗菌	[21]
嗜单胞菌GSG2	从孟加拉湾收集的珊瑚样本	银，金	金 10~50，银 40~60	圆形，三角形，六边形	抗菌	[22]
马氏链霉菌	印度科钦水样沉积物样本	银	70	球形	抗菌	[23]
粪产碱菌	马纳尔湾曼达帕姆附近帕克湾的珊瑚	银	30~50	球形	抗菌和抗生物膜的活性	[24]
芽孢杆菌 CS11	印度科钦的土壤样品	银	42~92	球形	抗菌	[25]
Kocuria flava	印度的甘尼亚古马里海岸	铜	5~30	球形	抗菌	[26]
放射球菌	美国马纳萨斯文化收藏馆	银	4~50	球形	抗菌、抗生物污垢剂和抗癌	[27]
根瘤菌	海水	银	10	球形	抗菌	[28]
铜绿假单胞菌	曼多维河口红树林水样	银	35~60	球形，三角形	抗菌	[29]
希瓦氏菌PV-4	德国	钯，铂	2~7	球形	甲基橙染料的降解	[30]
莫氏菌	—	银	2~5	球形	抗菌	[31]
苍白杆菌属 MPV1	意大利托斯卡纳的砂	碲	—	大致球形，棒状	减少有毒化合物	[32]
枯草芽孢杆菌	印度胡蒂金矿	金	20~25	球形	亚甲基蓝的降解	[33]
短芽孢杆菌NCIM2533	印度浦那国家工业微生物保藏中心（NCL）	银	41~68	球形	抗菌	[34]

真菌种类	真菌来源	合成金属	尺寸 /nm	形状	应用	参考文献
绿青霉	印度昌迪加尔微生物类型文化收	银	10~50	大致球形	抗菌	[39]
佛曲霉	印度西孟加拉邦耶尼废水中心	银	20~40	大致球形	抗真菌	[40]
尖孢镰刀菌JT1	枯萎的香蕉	金	22	—	抗菌	[41]
灰葡萄孢	智利四区收集的腐烂葡萄	金	1~100	三角形，球形，六角形，金字塔形，十面体	抗菌活性	[42]
放射裂褶菌	印度安得拉邦森林	银	10~40	不规则形状	抗菌活性	[43]
里氏木霉	印度昌迪加尔微生物类型文化收藏	金	61	三角形，杆形，球形，六边形	生物催化和抗菌	[19]
弯孢菌	长春花的叶子	银	10~50	球形	协同抗菌	[44]
尖孢梭菌AJP03	印度果阿Sonshi矿区的土壤	金	约72	球形	罗丹明B的降解	[45]
尖孢镰刀菌405	美国华盛顿的研究服务局	银	10~50	球形	胶体稳定性	[46]
米根霉	印度浦那国家工业微生物收集中心（NCIM）	金	16~43	球形,花状	血液相容性	[47]
哈茨木霉	—	银	20~30	球形	抗真菌	[48]
尖孢镰刀菌	伊朗德黑兰国家基因工程与生物技术研究所（NIGEB）	银	34~44	球形	抗菌	[49]
平菇	埃及开罗大学生物技术中心	金	10~30	球形,棱柱形	抗癌和协同抗菌	[50]

真菌种类	真菌来源	合成金属	尺寸 /nm	形状	应用	参考文献
绿青霉	印度昌迪加尔微生物类型文化收	银	10~50	大致球形	抗菌	[39]
佛曲霉	印度西孟加拉邦耶尼废水中心	银	20~40	大致球形	抗真菌	[40]
尖孢镰刀菌JT1	枯萎的香蕉	金	22	—	抗菌	[41]
灰葡萄孢	智利四区收集的腐烂葡萄	金	1~100	三角形，球形，六角形，金字塔形，十面体	抗菌活性	[42]
放射裂褶菌	印度安得拉邦森林	银	10~40	不规则形状	抗菌活性	[43]
里氏木霉	印度昌迪加尔微生物类型文化收藏	金	61	三角形，杆形，球形，六边形	生物催化和抗菌	[19]
弯孢菌	长春花的叶子	银	10~50	球形	协同抗菌	[44]
尖孢梭菌AJP03	印度果阿Sonshi矿区的土壤	金	约72	球形	罗丹明B的降解	[45]
尖孢镰刀菌405	美国华盛顿的研究服务局	银	10~50	球形	胶体稳定性	[46]
米根霉	印度浦那国家工业微生物收集中心（NCIM）	金	16~43	球形,花状	血液相容性	[47]
哈茨木霉	—	银	20~30	球形	抗真菌	[48]
尖孢镰刀菌	伊朗德黑兰国家基因工程与生物技术研究所（NIGEB）	银	34~44	球形	抗菌	[49]
平菇	埃及开罗大学生物技术中心	金	10~30	球形,棱柱形	抗癌和协同抗菌	[50]

藻类	藻类来源	合成金属	尺寸/nm	形状	应用	参考文献
越南紫菜	—	银	13	球形	抗菌	[53]
螺旋藻	伊朗克尔曼甜水区	银	35	球形	抗菌	[54]
小球藻	印度钦奈藻类文化收藏馆	金	2~10	球形	抗病原	[55]
小球藻	德州大学奥斯汀分校的藻类文化收藏	银	3~15	球形	抗菌	[56]
小球藻	伊朗比尔詹德大学自然资源与环境学院	钯	5~20	球形	—	[57]
海带	韩国当地的海藻产业	银	31	球形到椭圆形	植物毒性和幼苗生长测定	[58]