化工进展 ›› 2020, Vol. 39 ›› Issue (5): 1714-1721.DOI: 10.16085/j.issn.1000-6613.2019-1209

• 化工过程与装备 • 上一篇    下一篇

果糖在高黏度水溶液中的生长模型及机理

龚俊波1,2(), 李康1, 何兵兵3, 黄翠1, 陈明洋1   

  1. 1.天津大学化工学院,天津 300072
    2.青海民族大学,青海 西宁 810007
    3.中低品位磷矿及其共伴生资源高效 利用国家重点实验室,贵州 贵阳 550500
  • 出版日期:2020-05-05 发布日期:2020-05-25
  • 通讯作者: 龚俊波
  • 作者简介:龚俊波(1974—),男,博士,副教授。E-mail: junbo_gong@tju.edu.cn
  • 基金资助:
    青海省自然科学基金(2019-ZJ-901)

Model and mechanism of fructose crystal growth in aqueous solution with high viscosity

Junbo GONG1,2(), Kang LI1, Bingbing HE3, Cui HUANG1, Mingyang CHEN1   

  1. 1.School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
    2.Qinghai Nationalities University, Xining 810007, Qinghai, China
    3.State Key Laboratory of Efficient Utilization of Low Grade Phosphate Rock and its Associated Resource, Guiyang 550500, Guizhou, China
  • Online:2020-05-05 Published:2020-05-25
  • Contact: Junbo GONG

摘要:

果糖是一种高附加值的甜味剂,其水溶液的黏度很高,导致晶体生长速率非常缓慢。利用常规的在线和离线测量方法会因为黏度大和成核而造成测量不准确。这导致果糖晶体在纯水中的生长速率目前尚无可靠数据,难以精确实现果糖工业生产过程的设计及优化。本文通过考察黏度、密度与扩散作用研究了高黏度果糖水溶液中的晶体生长速率。首先,利用旋转黏度计测定了果糖水溶液的黏度,考察了温度、浓度对其黏度的影响,使用经验模型对黏度数据进行了关联。随后利用比重瓶法测定了果糖水溶液的密度,考察了温度、浓度对溶液密度的影响。基于黏度和密度的测定结果,利用自由体积模型预测了果糖饱和水溶液的扩散系数,探究了在高黏度果糖水溶液中影响溶质分子传递过程的关键因素。最后,使用扩散控制的生长模型预测了果糖晶体的理论生长速率。采用单晶生长实验测定了果糖晶体的实际生长速率,将理论生长速率与之进行比较,结果吻合良好。此外,基于扩散控制和实际生长形貌,判断果糖晶体的生长机理属于螺旋错位生长。

关键词: 果糖, 生长速率, 生长预测, 结晶动力学, 生长机理

Abstract:

Fructose is a high value-added sweetener. The high viscosity of its aqueous solution leads to slow crystal growth rate. High viscosity and nucleation can cause inaccurate measurements of conventional online and offline measurement methods. As a result, there is no reliable data to design and optimize the production process of the fructose industry. In this paper, the growth rate of fructose in aqueous solution with high viscosity was studied through viscosity, density and diffusion. Firstly, the viscosity of the fructose aqueous solution was measured by a rotary viscometer. The relationship among temperature, concentration and viscosity was correlated with an empirical model. Subsequently, the density of the fructose aqueous solution was determined by the pycnometer method, and the effects of temperature and concentration on the density of the solution were investigated. Based on the results of viscosity and density measurements, the free-volume model was used to predict the diffusion coefficient of fructose saturated aqueous solution and explore the key factors affecting the mass transfer of solute molecules. Finally, a diffusion-controlled growth model was adopted to predict the theoretical growth rate of fructose crystals. The results agreed with the actual growth rate determined by single crystal growth experiments. In addition, the study of diffusion control and crystal morphology indicated that the growth mechanism of fructose crystals belongs to spiral dislocation growth.

Key words: fructose, growth rate, growth prediction, crystallization kinetics, growth mechanism

中图分类号: 

京ICP备12046843号-2;京公网安备 11010102001994号
版权所有 © 《化工进展》编辑部
地址:北京市东城区青年湖南街13号 邮编:100011
电子信箱:hgjz@cip.com.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn