化工进展 ›› 2019, Vol. 38 ›› Issue (06): 2953-2960.DOI: 10.16085/j.issn.1000-6613.2018-2039

• 精细化工 • 上一篇    下一篇

一种新型缓凝剂的制备及其在水泥基复合材料中的应用

李均星1(),郭锦棠1(),张弛2,李鹏鹏1   

  1. 1. 天津大学化工学院,天津 300350
    2. 中国石油集团钻井工程技术研究院,北京 100089
  • 收稿日期:2018-10-15 出版日期:2019-06-05 发布日期:2019-06-05
  • 通讯作者: 郭锦棠
  • 作者简介:李均星(1993—),男,硕士研究生,研究方向为油井水泥外加剂。E-mail:<email>13752328251@163.com</email>。
  • 基金资助:
    国家重大科技专项(2016ZX05020-004)

Synthesis of a novel retarder and its application in cement matrix composites

Junxing LI1(),Jintang GUO1(),Chi ZHANG2,Pengpeng LI1   

  1. 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
    2. Drilling Research Institute of CNPC, Beijing 100089, China
  • Received:2018-10-15 Online:2019-06-05 Published:2019-06-05
  • Contact: Jintang GUO

摘要:

针对目前固井使用的缓凝剂存在的热稳定性能不好、异常胶凝现象(结块)、水泥石抗压强度减弱、水泥浆综合性能欠佳等问题,通过水溶液自由基聚合,研制了一种新型高温缓凝剂GWR-1,并对其热稳定性能进行了评价,同时,对加入4种缓凝剂GWR-1、GWH-1、HX-400、DRH-200L的水泥浆异常胶凝现象和综合性能做了比较。微观结构分析表明:各单体参与了反应,分子量分布较为均一,分子结构高温下稳定,GWR-1的热稳定性可达350℃。GWR-1在硅酸盐水泥基复合材料中应用性能测试结果表明:加入GWR-1水泥浆的稠化温度可达160℃,高温时加量不敏感,高温抗盐性能较好,加入GWR-1的水泥浆在150℃不会发生异常胶凝现象,且其硅酸盐水泥石的强度发展良好,低密度和高密度的水泥浆的综合性能优于加入其他3种缓凝剂的水泥浆。

关键词: 缓凝剂, 硅酸盐水泥, 热稳定性, 异常胶凝, 综合性能

Abstract:

For conventional cementing, the retarders used currently have some shortcomings, such as poor thermostability, abnormal gelation (clots), compressive strength reduction and low quantities of cement. In this paper, a new retarder, GWR-1, was prepared by aqueous free-radical polymerization and its thermostability was tested. Also, the abnormal gelation and other related properties of cement slurry added with GWR-1 were compared to those added with other three retarders GWH-1, HX-400 and DRH-200L. The structural analysis shows that almost all monomers are involved in the polymer, and the distribution of molecular weight is relatively uniform. The GWR-1 retarder is stable at 350℃. The performance test of silicate cement composite containing GWR-1 shows that the thickening temperature of cement slurry increasesd to 160℃ after adding GWR-1. The addition amount of GWR-1 is not sensitive at high temperature and the salt resistance at high temperature is good. The cement slurry with GWR-1 will not have abnormal cementing phenomenon at 150℃, and the strength of final cement stone develops well. The comprehensive performance of low density and high density cement slurry added to GWR-1 is better than that with three other retarders.

Key words: retarder, portland cement, thermostability, abnormal gelation, comprehensive properties

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