Fe@HKUST-1负载型材料催化苯羟基化反应

doi:10.16085/j.issn.1000-6613.2016.10.028

化工进展 ›› 2016, Vol. 35 ›› Issue (10): 3212-3218.DOI: 10.16085/j.issn.1000-6613.2016.10.028

Fe@HKUST-1负载型材料催化苯羟基化反应

刘艳凤¹, 刘勃良¹, 张浩¹, 张天永², 张柳钦¹, 郝振涛¹, 吴武斌²

1 海南大学材料与化工学院, 海南海口 570228;
2 天津大学化工学院, 天津 300072

收稿日期:2016-03-25 修回日期:2016-05-31 出版日期:2016-10-05 发布日期:2016-10-05
通讯作者: 张天永,教授,从事工业催化和精细化工的研究。E-mail:tyzhang@tju.edu.cn
作者简介:刘艳凤(1980-),女,实验师,从事工业催化的研究。E-mail:lyfvip@tju.edu.cn。
基金资助:
国家自然科学基金（21276187），教育部博士点基金（20110032120011）及海南大学科研启动基金（kyqd1612）项目。

The catalytic properties of Fe@HKUST-1 material in the direct hydroxylation of benzene

LIU Yanfeng¹, LIU Boliang¹, ZHANG Hao¹, ZHANG Tianyong², ZHANG Liuqin¹, HAO Zhentao¹, WU Wubin²

1 School of Materials and Chemical Engineering, Hainan University, Haikou 570228, Hainan, China;
2 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Received:2016-03-25 Revised:2016-05-31 Online:2016-10-05 Published:2016-10-05

摘要/Abstract

摘要： 以氯化铁与二水合氯化铜的投料摩尔比为4∶100、8∶100、12∶100的比例，将氯化铁加入HKUST-1的前体二水合氯化铜和均苯三酸的混合溶液中，在超声波作用下原位合成Fe@HKUST-1负载型材料。用XRD、BET、TGA、SEM对Fe@HKUST-1进行晶体结构、孔径结构、热稳定性、外观形貌进行分析表征，考察了铁负载量对这些性质的影响。将Fe@HKUST-1负载型材料用于苯羟基化反应，实验表明，与HKUST-1相比Fe@HKUST-1负载型材料的活性有所提高。当氯化铁与二水合氯化铜投料的摩尔比为8∶100时，Fe@HKUST-1负载型材料的活性和稳定性在苯羟基化反应中处于较优状态。

关键词: 苯, 催化剂载体, 氧化, 金属有机框架化合物, Fe@HKUST

Abstract: FeCl₃ was mixed with CuCl₂·2H₂O and benzenetricarboxylic acid,the precursors of HKUST-1,to in situ synthesize Fe@HKUST-1 material under ultrasonic wave. The molar ratios of FeCl₃ to CuCl₂·2H₂O were 4:100,8:100 and 12:100 respectively. The material was then characterized by XRD,BET,TGA and SEM to obtain the data of crystal structure,pore structure,thermal stability and morphology,as well as the influences of loaded iron on the properties of Fe@HKUST-1. Fe@HKUST-1 was applied for the hydroxylation of benzene as catalyst. The results indicated Fe@HKUST-1 had higher catalytic activity than HKUST-1. When the molar ratio of FeCl₃ to CuCl₂·2H₂O was 8:100,the obtained Fe@HKUST-1 showed the best activity and stability in the hydroxylation of benzene.

Key words: benzene, catalyst support, oxidation, metal-organic framework, Fe@HKUST

中图分类号:

O625.1

刘艳凤, 刘勃良, 张浩, 张天永, 张柳钦, 郝振涛, 吴武斌. Fe@HKUST-1负载型材料催化苯羟基化反应[J]. 化工进展, 2016, 35(10): 3212-3218.

LIU Yanfeng, LIU Boliang, ZHANG Hao, ZHANG Tianyong, ZHANG Liuqin, HAO Zhentao, WU Wubin. The catalytic properties of Fe@HKUST-1 material in the direct hydroxylation of benzene[J]. Chemical Industry and Engineering Progree, 2016, 35(10): 3212-3218.

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Fe@HKUST-1负载型材料催化苯羟基化反应

The catalytic properties of Fe@HKUST-1 material in the direct hydroxylation of benzene

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