化工进展 ›› 2023, Vol. 42 ›› Issue (8): 4447-4457.DOI: 10.16085/j.issn.1000-6613.2022-1845
收稿日期:
2022-10-08
修回日期:
2022-11-23
出版日期:
2023-08-15
发布日期:
2023-09-19
通讯作者:
张丽宏
作者简介:
张丽宏(1984—),女,博士,副教授,硕士生导师,研究方向为固废资源化利用。E-mail:zhanglh@sxu.edu.cn。
基金资助:
ZHANG Lihong(), JIN Yaoru, CHENG Fangqin
Received:
2022-10-08
Revised:
2022-11-23
Online:
2023-08-15
Published:
2023-09-19
Contact:
ZHANG Lihong
摘要:
煤气化技术作为清洁利用技术得到迅速发展,但同时产生大量的煤气化渣。本文从煤气化渣的来源及危害、煤气化渣的基本性质、煤气化渣制备材料(介孔材料、活性炭、复合材料)和煤气化渣的应用(废气废水处理、建工建材、农业)4个方面进行概述总结,对存在的问题、应用前景分别进行了分析和展望。文中指出:煤气化渣含碳量高、铝硅资源丰富、比表面积较大、孔隙结构比较发达,可用于制备高值化产品,但制备过程中所产生的废液需要进行处理与处置,剩余的含铝、硅和碳残渣也需要进行回收利用。煤气化渣的研究虽然取得了良好的效果,但大都处于实验室研究阶段或试验推广阶段,无法实现规模化利用。建议开发工艺简单、可行性强且具有经济效益的煤气化渣资源化利用技术,在分级利用的基础上实现铝、硅、碳资源的协同利用;在全利用的基础上实现其规模化利用。
中图分类号:
张丽宏, 金要茹, 程芳琴. 煤气化渣资源化利用[J]. 化工进展, 2023, 42(8): 4447-4457.
ZHANG Lihong, JIN Yaoru, CHENG Fangqin. Resource utilization of coal gasification slag[J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4447-4457.
产煤地区 | 炉型 | 渣样 | SiO2/% | Al2O3/% | Fe2O3/% | CaO/% |
---|---|---|---|---|---|---|
鄂尔多斯煤[ | 多喷嘴 气化炉 | 粗渣 | 55.3 | 19.14 | 9.79 | 8.65 |
细渣 | 54.4 | 21.93 | 8.36 | 6.7 | ||
陕西煤[ | 多喷嘴 | 粗渣 | 41.44 | 13.91 | 17.37 | 17.27 |
气化炉 | 细渣 | 35.93 | 15.48 | 18.13 | 17.19 | |
陕西煤[ | Texaco气化炉 | 粗渣 | 41.12 | 12.72 | — | 12.88 |
细渣 | 32.20 | 8.87 | — | 4.33 | ||
宁东煤[ | — | 粗渣 | 50.09 | 19.26 | 10.35 | 11.30 |
细渣 | 53.80 | 16.59 | 7.79 | 9.95 | ||
宁东煤[ | Texaco气化炉 | 细渣 | 44.86 | 19.63 | 9.03 | 9.82 |
表1 不同种类煤气化渣的基本化学组成(质量分数)
产煤地区 | 炉型 | 渣样 | SiO2/% | Al2O3/% | Fe2O3/% | CaO/% |
---|---|---|---|---|---|---|
鄂尔多斯煤[ | 多喷嘴 气化炉 | 粗渣 | 55.3 | 19.14 | 9.79 | 8.65 |
细渣 | 54.4 | 21.93 | 8.36 | 6.7 | ||
陕西煤[ | 多喷嘴 | 粗渣 | 41.44 | 13.91 | 17.37 | 17.27 |
气化炉 | 细渣 | 35.93 | 15.48 | 18.13 | 17.19 | |
陕西煤[ | Texaco气化炉 | 粗渣 | 41.12 | 12.72 | — | 12.88 |
细渣 | 32.20 | 8.87 | — | 4.33 | ||
宁东煤[ | — | 粗渣 | 50.09 | 19.26 | 10.35 | 11.30 |
细渣 | 53.80 | 16.59 | 7.79 | 9.95 | ||
宁东煤[ | Texaco气化炉 | 细渣 | 44.86 | 19.63 | 9.03 | 9.82 |
用途 | 利用方法 | 优点 | 缺点 |
---|---|---|---|
水泥和混凝土 | 掺杂制备 | 有利于水泥发生水化反应、缩短凝结时间,提高 抗压、抗裂强度 | 对气化渣的烧失量要求 比较严格、反应条件苛刻 |
墙体材料 | 煤气化渣磨细后,通过高温、挤压成型法制备而成 | 保温、隔热、节能利废,增加密实度和耐久性 | 工艺复杂、投资大、成本 高、且处于实验研究阶段 |
道路材料 | 煤气化渣筛分、破碎后,与骨料、砂浆等材料合制 备而成 | 改善路面抗裂性,提高混合材料的强度和抗冻性 |
表2 煤气化渣作为建筑材料的分析
用途 | 利用方法 | 优点 | 缺点 |
---|---|---|---|
水泥和混凝土 | 掺杂制备 | 有利于水泥发生水化反应、缩短凝结时间,提高 抗压、抗裂强度 | 对气化渣的烧失量要求 比较严格、反应条件苛刻 |
墙体材料 | 煤气化渣磨细后,通过高温、挤压成型法制备而成 | 保温、隔热、节能利废,增加密实度和耐久性 | 工艺复杂、投资大、成本 高、且处于实验研究阶段 |
道路材料 | 煤气化渣筛分、破碎后,与骨料、砂浆等材料合制 备而成 | 改善路面抗裂性,提高混合材料的强度和抗冻性 |
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