化工进展 ›› 2023, Vol. 42 ›› Issue (6): 2963-2974.DOI: 10.16085/j.issn.1000-6613.2022-1524

• 工业催化 • 上一篇    下一篇

过渡金属改性Cu-SSZ-13分子筛脱硝催化剂研究进展

殷成阳(), 侯铭, 杨爽, 毛迪, 刘俊言   

  1. 沈阳师范大学化学化工学院,辽宁 沈阳 110034
  • 收稿日期:2022-08-17 修回日期:2022-11-27 出版日期:2023-06-25 发布日期:2023-06-29
  • 通讯作者: 殷成阳
  • 作者简介:殷成阳(1981—),男,博士,副教授,硕士生导师,研究方向为环境催化。E-mail:ycy2006cc@126.com
  • 基金资助:
    国家自然科学基金(U1908204);辽宁省教育厅基本科研项目(LJKZ0996);大学生创新创业训练计划(X202210166140)

Research progress in transition metals modified Cu-SSZ-13 zeolite denitration catalysts

YIN Chengyang(), HOU Ming, YANG Shuang, MAO Di, LIU Junyan   

  1. College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, Liaoning, China
  • Received:2022-08-17 Revised:2022-11-27 Online:2023-06-25 Published:2023-06-29
  • Contact: YIN Chengyang

摘要:

氨选择性催化还原技术(NH3-SCR)是消除氮氧化物最有效的技术之一,高效稳定的催化剂是NH3-SCR技术的核心。其中Cu基分子筛催化剂特别是Cu-SSZ-13分子筛催化剂受到了广泛的关注与研究,但仍存在着高温活性不好、氮气选择性不够理想和抗硫性能不足等问题。为了进一步提高Cu-SSZ-13分子筛催化剂的脱硝性能,可采用添加过渡金属的方法来改性Cu-SSZ-13分子筛催化剂。本文对过渡金属改性的Cu-SSZ-13分子筛催化剂的研究进展进行了系统的梳理,重点对Fe改性Cu-SSZ-13分子筛催化剂的几种制备方法进行了归纳,分别对离子交换法、浸渍法和一步水热合成法进行了介绍,对几种常见的不同过渡金属(Fe、Mn、Nb、Co、Ni、Ti、Zn)改性的Cu-SSZ-13分子筛催化剂脱硝性能的差别和原因进行了分析和讨论。最后对过渡金属改性的Cu-SSZ-13分子筛脱硝催化剂的研究重点和发展前景进行了展望,指出过渡金属在Cu-SSZ-13分子筛中的具体存在形式、落位情况、协同作用机制等方面的研究有待进一步深入开展。

关键词: 催化剂, 沸石, 选择催化还原, 过渡金属, 改性

Abstract:

Selective catalytic reduction of ammonia (NH3-SCR) is recognized as one of the most effective technologies for NO x elimination, and efficient and stable catalysts are the core of NH3-SCR technology. Cu-based zeolite catalysts, especially Cu-SSZ-13, have attracted extensive attention and research. However, there are still some problems, such as low high temperature activity, insufficient N2 selectivity and poor sulfur resistance. In order to further improve the denitrification performance of Cu-SSZ-13 zeolite catalysts, transition metal modification can be applied. In this paper, the research progress of Cu-SSZ-13 zeolite catalyst modified by transition metals is reviewed, and the preparation methods of Fe-modified Cu-SSZ-13 zeolite are summarized. The ion exchange method, impregnation method and one-step hydrothermal synthesis method are introduced respectively. The differences and reasons of denitrification performance of Cu-SSZ-13 zeolite modified by different transition metals (Fe, Mn, Nb, Co, Ni, Ti, Zn) are discussed. Finally, the research emphasis and development prospect of Cu-SSZ-13 zeolite catalysts modified by transition metals are prospected, and it concludes that the form, location and synergistic mechanism of transition metals in Cu-SSZ-13 zeolite need to be further studied.

Key words: catalyst, zeolite, selective catalytic reduction, transition metal, modification

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