化工进展 ›› 2023, Vol. 42 ›› Issue (3): 1411-1425.DOI: 10.16085/j.issn.1000-6613.2022-0918

• 材料科学与技术 • 上一篇    下一篇

磷酸基地质聚合物的制备及其性能研究进展

高江雨1(), 张耀君1(), 贺攀阳2, 刘礼才1, 张枫烨1   

  1. 1.西安建筑科技大学材料科学与工程学院,陕西 西安 710055
    2.西安建筑科技大学资源工程学院,陕西 西安 710055
  • 收稿日期:2022-05-17 修回日期:2022-06-27 出版日期:2023-03-15 发布日期:2023-04-10
  • 通讯作者: 张耀君
  • 作者简介:高江雨(1998—),男,硕士研究生,研究方向为固体废弃物资源化。E-mail:gaojiangyu@xauat.edu.cn
  • 基金资助:
    国家自然科学基金(21676209)

Recent progress on the fabrication and properties of phosphobase geopolymer

GAO Jiangyu1(), ZHANG Yaojun1(), HE Panyang2, LIU Licai1, ZHANG Fengye1   

  1. 1.Materials Science and Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, Shaanxi, China
    2.Resource Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, Shaanxi, China
  • Received:2022-05-17 Revised:2022-06-27 Online:2023-03-15 Published:2023-04-10
  • Contact: ZHANG Yaojun

摘要:

磷酸基地质聚合物是硅铝质前体与磷酸(盐)溶液反应生成的一类新型地质聚合物材料,原料、激发剂用量、水用量以及养护条件是影响磷酸基地质聚合物组成和结构的主要因素,也进一步决定其使用性能。本文综述了磷酸基地质聚合物形成机理及网络结构的发展;总结了不同原料、养护制度、激发剂种类与用量等因素对磷酸基地质聚合物制备的影响;详细论述了多种制备条件对磷酸基地质聚合物力学性能的影响,并简述了磷酸基地质聚合物的耐热、耐腐蚀以及介电等性能特点。此外,文中指出了磷酸基地质聚合物的形成机理研究中对网络结构认识的不足及其制备过程中存在的问题,提出应进一步明确磷酸基地质聚合物的反应机理并建立系统的性能检测标准,展望了磷酸基地质聚合物的高附加值应用及其在固体废物资源化方向的发展前景。

关键词: 磷酸基地质聚合物, 制备工艺, 形成机理, 性能

Abstract:

Phosphobase geopolymer is a new class of geopolymer material formed by the reaction between aluminosilicate precursor and phosphoric acid (salt) solution. Raw materials, amount of activator, amount of water and curing conditions are the main factors that affect the composition and structure of phosphobase geopolymer, and further determine their performance. In this paper, the formation mechanism and network structure development of phosphobase geopolymer are reviewed. The influence of different raw materials, curing systems, types and amounts of activators on phosphobase geopolymer are summarized. The effects of various preparation conditions on the mechanical properties of phosphobase geopolymer are discussed in detail, and a sketch of the heat resistance, corrosion resistance and dielectric properties of phosphobase geopolymer is introduced. In addition, the paper pointed out the insufficient understanding of network structure in the research on formation mechanism and the problems existing in the preparation process of phosphobase geopolymer. It is proposed that the reaction mechanism of phosphobase geopolymer should be further clarified and a systematic performance testing standard should be established. Finally, the high value-added application of phosphobase geopolymer and its development prospect in the direction of solid waste recycling are prospected.

Key words: phosphobase geopolymer, preparation process, formation mechanism, properties

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