化工进展 ›› 2022, Vol. 41 ›› Issue (6): 3051-3062.DOI: 10.16085/j.issn.1000-6613.2021-1591
田追(), 张震, 卢嫚, 杨斌, 杨金辉(), 周书葵, 魏柏, 李聪
收稿日期:
2021-07-27
修回日期:
2021-11-17
出版日期:
2022-06-10
发布日期:
2022-06-21
通讯作者:
杨金辉
作者简介:
田追(1997—),男,硕士研究生,研究方向为水处理理论与技术。E-mail:基金资助:
TIAN Zhui(), ZHANG Zhen, LU Man, YANG Bin, YANG Jinhui(), ZHOU Shukui, WEI Bai, LI Cong
Received:
2021-07-27
Revised:
2021-11-17
Online:
2022-06-10
Published:
2022-06-21
Contact:
YANG Jinhui
摘要:
半导体、稀土开采等行业所排放的氟废水所引发氟中毒现象备受关注。吸附法是去除废水中氟离子的有效方法之一,但传统吸附剂存在吸附容量低、选择性差等缺点,亟需研发具有高吸附容量、可再生且无二次污染的吸附材料。本文归纳了一些新型吸附材料,如高分子材料吸附剂、生物炭、层状双氢氧化物、工业废弃物、纳米材料及其改性材料在含氟废水中的研究应用;总结了这些改性材料的制备过程,介绍了这些材料吸附除氟的能力,分析了新型吸附材料吸附除氟的机理以及共存离子干扰、pH适用范围等影响因素,并指出了材料制备存在的问题,提出了制备对氟离子具有高选择性能的改性吸附材料的发展方向和材料循环利用所需解决的重要问题。
中图分类号:
田追, 张震, 卢嫚, 杨斌, 杨金辉, 周书葵, 魏柏, 李聪. 新型除氟吸附材料的研究进展[J]. 化工进展, 2022, 41(6): 3051-3062.
TIAN Zhui, ZHANG Zhen, LU Man, YANG Bin, YANG Jinhui, ZHOU Shukui, WEI Bai, LI Cong. New adsorption materials for removing fluoride from wastewater: a review[J]. Chemical Industry and Engineering Progress, 2022, 41(6): 3051-3062.
吸附剂 | pH适用范围 | 吸附容量/mg·g-1 | 吸附机理 | 热力学/动力学 | 参考文献 |
---|---|---|---|---|---|
锆改性茶籽壳生物炭 | 3~9 | 11.04 | 静电吸附 | Langmuir/二级 | [ |
锆浸渍核桃壳生物炭 | 3~12 | 6.38 | 静电吸附 | Freundlich/二级 | [ |
炭化椰子树根 | — | 2.04 | 化学吸附 | Langmuir/二级 | [ |
硝酸活化植物树皮生物炭 | 2~11 | 1.65 | — | Langmuir/二级 | [ |
超声空化诱导合成锆浸渍生物炭 | 2~12 | 5.40 | 离子交换 | Langmuir/二级 | [ |
钙修饰花生壳生物炭 | 5~7 | 1.32 | 表面吸附 | Langmuir/二级 | [ |
氧化铁复合木片生物炭 | 5 | 0.42 | 静电吸附 | — | [ |
表1 一些生物质炭改性材料吸附除氟性能比较
吸附剂 | pH适用范围 | 吸附容量/mg·g-1 | 吸附机理 | 热力学/动力学 | 参考文献 |
---|---|---|---|---|---|
锆改性茶籽壳生物炭 | 3~9 | 11.04 | 静电吸附 | Langmuir/二级 | [ |
锆浸渍核桃壳生物炭 | 3~12 | 6.38 | 静电吸附 | Freundlich/二级 | [ |
炭化椰子树根 | — | 2.04 | 化学吸附 | Langmuir/二级 | [ |
硝酸活化植物树皮生物炭 | 2~11 | 1.65 | — | Langmuir/二级 | [ |
超声空化诱导合成锆浸渍生物炭 | 2~12 | 5.40 | 离子交换 | Langmuir/二级 | [ |
钙修饰花生壳生物炭 | 5~7 | 1.32 | 表面吸附 | Langmuir/二级 | [ |
氧化铁复合木片生物炭 | 5 | 0.42 | 静电吸附 | — | [ |
水滑石类别 | pH适用范围 | 吸附容量/mg·g–1 | 吸附机理 | 热力学/动力学 | 参考文献 |
---|---|---|---|---|---|
Li-Al型类水滑石 | 6.5~8.0 | 123.46 | 离子交换 | Freundlich/二级 | [ |
Mg-Al-NO3型类水滑石 | 10.49 | 57.14 | 氟离子插层和氟代诺三水铝石沉淀 | Langmuir/二级 | [ |
Mg-Al-Fe类水滑石 | 3~8 | 33.67 | — | Langmuir/二级 | [ |
Ni-Al型类水滑石 | 6.6~7.5 | 0.45 | 离子交换 | Langmuir/二级 | [ |
Co-Al型类水滑石 | 6.9~7.3 | 0.31 | 离子交换 | Langmuir/二级 | [ |
Mg-Al型类水滑石 | 7.1~8.2 | 0.37 | 离子交换 | Langmuir/二级 | [ |
表2 其他水滑石材料除氟
水滑石类别 | pH适用范围 | 吸附容量/mg·g–1 | 吸附机理 | 热力学/动力学 | 参考文献 |
---|---|---|---|---|---|
Li-Al型类水滑石 | 6.5~8.0 | 123.46 | 离子交换 | Freundlich/二级 | [ |
Mg-Al-NO3型类水滑石 | 10.49 | 57.14 | 氟离子插层和氟代诺三水铝石沉淀 | Langmuir/二级 | [ |
Mg-Al-Fe类水滑石 | 3~8 | 33.67 | — | Langmuir/二级 | [ |
Ni-Al型类水滑石 | 6.6~7.5 | 0.45 | 离子交换 | Langmuir/二级 | [ |
Co-Al型类水滑石 | 6.9~7.3 | 0.31 | 离子交换 | Langmuir/二级 | [ |
Mg-Al型类水滑石 | 7.1~8.2 | 0.37 | 离子交换 | Langmuir/二级 | [ |
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