胶晶结构生色体系的构筑及应用研究进展

doi:10.16085/j.issn.1000-6613.2020-0817

摘要/Abstract

摘要：

胶晶是由单分散胶体微球自组装形成的有序阵列结构。胶体微球自组装制备结构生色体系，具有方法简单、成本低及不需要复杂且昂贵的设备等优点，是人工构建结构生色体系的重要途径。由胶晶产生的结构色具有亮度高、色彩饱和度高和光稳定性好等优点，在纺织品着色、传感、防伪以及信息加密等领域展现出广阔的应用前景。本文详细介绍了胶体微球的结构设计与合成、胶晶的可控构筑及其应用研究三个方面的内容。文中综述了无机纳米微球、有机聚合物纳米微球和核壳结构纳米微球的优点和不足；较全面地总结了胶体微球的组装方法，包括重力沉降法、加热辅助组装法、垂直沉积法、浸渍提拉法、喷涂法、喷墨打印技术、旋涂法、磁场诱导自组装法、电场驱动组装法和界面转印法等；讨论了胶晶结构的应用现状，并对胶晶结构生色体系未来的研究重点进行了展望。

关键词: 胶晶, 乳液, 纳米材料, 结构色, 界面

Abstract:

Colloidal crystals are ordered arrays formed by self-assembly of monodisperse colloidal microspheres. The self-assembly of colloidal microspheres is an important way to build the structural color, which is simple, low cost, and no need for complicated and expensive equipment, etc. The structural color produced from colloidal crystals has great potential in the fields of textiles coloring, sensing, anti-counterfeiting, and information encryption, owing to the advantages of high luminance, high saturation, and good light stability, etc. This article introduces the following three aspects in details: the design of the structure and the synthesis of colloidal microspheres, the controllable construction, and the application of colloidal crystals. The advantages and disadvantages of inorganic nanospheres, organic polymer nanospheres, and core-shell nanospheres are reviewed. The assembly methods of colloidal microspheres are summarized, including gravity deposition, heat-assisted assembly, vertical deposition, dip-coating, spraying, inkjet printing, spin coating, magnetic field induced self-assembly, electric field-driven assembly, and interface transfer printing, etc. The application status of the colloidal crystals structure are described and the perspective of future research emphasis on the colloidal structure color system are also presented.

Key words: colloidal crystals, emulsions, nanomaterials, structural color, interface

中图分类号:

O734⁺.2

孔淼, 刘芳芳, 唐炳涛. 胶晶结构生色体系的构筑及应用研究进展[J]. 化工进展, 2021, 40(3): 1469-1482.

KONG Miao, LIU Fangfang, TANG Bingtao. Research progress on the construction and application of colloidal crystal structure in coloration system[J]. Chemical Industry and Engineering Progress, 2021, 40(3): 1469-1482.

图/表 14

图1 重力沉降法组装胶体微球制备胶晶结构过程

图2 加热辅助组装法组装胶体微球制备胶晶结构

图3 垂直沉积法组装胶体微球制备胶晶结构

图4 浸渍提拉法原理示意

图5 喷涂法组装胶体微球制备胶晶结构

图6 喷墨打印技术组装胶体微球制备胶晶结构

图7 旋涂法组装胶体微球制备胶晶结构

图8 磁场诱导自组装胶体微球制备胶晶结构

图9 低压直流电场组装胶晶过程示意图及结构色照片（标尺为2mm）

图10 界面转印组装胶体微球制备胶晶结构

图11 胶晶结构生色体系在纺织品领域中的应用

图12 胶晶结构色体系在传感领域中的应用

图13 胶晶结构色体系在防伪领域中的应用

图14 胶晶结构色体系在信息安全领域中的应用

参考文献 74

1	KIM Hyoki, GE Jianping, KIM Junhoi, et al. Structural color printing using a magnetically tunable and lithographically fixable photonic crystal[J]. Nature Photonics, 2009, 3(9): 534-540.
2	MENG Zhipeng, WU Suli, TANG Bingtao, et al. Structurally colored polymer films with narrow stop band, high angle-dependence and good mechanical robustness for trademark anti-counterfeiting[J]. Nanoscale, 2018, 10(30): 14755-14762.
3	HOU Jue, ZHANG Huacheng, SU Bin, et al. Four-dimensional screening anti-counterfeiting pattern by inkjet printed photonic crystals[J]. Chemistry: An Asian Journal, 2016, 11(19): 2680-2685.
4	Cherylsuwen LAW, MARSAL Lluisf, SANTOS Abel. Handbook of nanomaterials in analytical chemistry[M]. Newark: Elsevier, 2020: 201-226.
5	VOGEL Nicolas, RETSCH Markus, FUSTIN Charles-andre, et al. Advances in colloidal assembly: the design of structure and hierarchy in two and three dimensions[J]. Chemical Reviews, 2015, 115(13): 6265-6311.
6	Yongjoon HEO, KANG Hyelim, Joonseok LEE, et al. Lithographically encrypted inverse opals for anti-counterfeiting applications[J]. Small, 2016, 12(28): 3819-3826.
7	LIAO Junlong, ZHU Cun, GAO Bingbing, et al. Multiresponsive elastic colloidal crystals for reversible structural color patterns[J]. Advanced Functional Materials, 2019, 29(39): 1902954.
8	LIU Guojin, ZHOU Lan, WANG Cuicui, et al. Study on the high hydrophobicity and its possible mechanism of textile fabric with structural colors of three-dimensional poly(styrene-methacrylic acid) photonic crystals[J]. RSC Advances, 2015, 5(77): 62855-62863.
9	CHAI Liqin, ZHOU Lan, LIU Guojin, et al. Study on the stability of the photonic crystals under different application environments and the possible mechanisms[J]. The Journal of the Textile Institute, 2019, 110(2): 234-242.
10	ZHOU Changtong, QI Yong, ZHANG Shufen, et al. Rapid fabrication of vivid noniridescent structural colors on fabrics with robust structural stability by screen printing[J]. Dyes and Pigments, 2020, 176: 108226.
11	张骜, 袁伟, 周宁, 等. 结构生色及其染整应用前景(一)[J]. 印染, 2012, 38(13): 44-47.
	ZHANG Ao, YUAN Wei, ZHOU Ning, et al. Structural color and its application prospect in dyeing and finishing industry(Ⅰ)[J]. Dyeing Finishing, 2012, 38(13): 44-47.
12	YABLONOVITCH Eli. Inhibited spontaneous emission in solid-state physics and electronics[J]. Physical Review Letters, 1987, 58(12): 2059-2062.
13	JOHN Sajeev. Strong localization of photons in certain disordered dielectric superlattices[J]. Physical Review Letters, 1987, 58(23): 2486-2489.
14	SIEVENPIPER D F, SICKMILLER M E, YABLONOVITCH E. 3D wire mesh photonic crystals[J]. Physical Review Letters, 1996, 76(14): 2480-2483.
15	STARCZEWSKA Anna, KEPINSKA Mirosława, SZPERLICH Piotr, et al. Influence of temperature on optical spectra of SbSI photonic crystals[J]. Optical Materials, 2020, 100: 109606.
16	LI Jianfeng, WANG Jian, WANG Xiaotian, et al. Bandgap engineering of TiO₂ nanotube photonic crystals for enhancement of photocatalytic capability[J]. CrystEngComm, 2020, 22(11): 1929-1938.
17	XIE Juan, DUAN Ming, BAI Penghui, et al. Gas adsorption behavior of silica photonic crystals with different size of initial particles[J]. Journal of the Ceramic Society of Japan, 2020, 128(1): 19-23.
18	左丽娜, 彭瑜, 郭贺虎, 等. 基于多维光子晶体及非晶光子晶体的结构色构筑研究进展[J]. 现代纺织技术, 2019, 27(6): 1-15.
	ZUO Lina, PENG Yu, GUO Hehu, et al. Research progress of structural color construction based on multi-dimensional photonic crystals and amorphous photonic crystals[J]. Advanced Textile Technology, 2019, 27(6): 1-15.
19	孟尧. 结构稳定型结构色材料的制备与应用研究[D]. 大连: 大连理工大学, 2019.
	MENG Yao. Fabrication of structural color materials with high structural stability and their applications[D]. Dalian: Dalian University of Technology, 2019.
20	TANG Bingtao, ZHENG Xixi, LIN Tao, et al. Hydrophobic structural color films with bright color and tunable stop-bands[J]. Dyes and Pigments, 2014, 104: 146-150.
21	SU Xin, XIA Hongbo, ZHANG Shufen, et al. Vivid structural colors from long-range ordered photonic crystal films with low angle-dependence[J]. Nanoscale, 2017, 9(9): 3002-3009.
22	CONG Hailin, YU Bing, TANG Jianguo, et al. Current status and future developments in preparation and application of colloidal crystals[J]. Chemical Society Reviews, 2013, 42(19): 7774-7800.
23	FREYMANN Georgvon, KITAEV Vladimir, LOTSCH Bettinav, et al. Bottom-up assembly of photonic crystals[J]. Chemical Society Reviews, 2013, 42(7): 2528-2554.
24	ZHANG Jing, ZHU Zhijie, YU Ziyi, et al. Large-scale colloidal films with robust structural colors[J]. Materials Horizons, 2019, 6(1): 90-96.
25	PAN Lei, XU Hongbo, SUN Yunyong, et al. Preparation of three-dimensional photonic crystals of zirconia by electrodeposition in a colloidal crystals template[J]. Crystals, 2016, 6(7): 76-84.
26	PARCHINE Mikhail, MCGRATH Joe, BARDOSOVA Maria, et al. Large area 2D and 3D colloidal photonic crystals fabricated by a roll-to-roll Langmuir-Blodgett method[J]. Langmuir, 2016, 32(23): 5862-5869.
27	GAO Weihong, RIGOUT Muriel, OWENS Huw. Self-assembly of silica colloidal crystal thin films with tuneable structural colours over a wide visible spectrum[J]. Applied Surface Science, 2016, 380: 12-15.
28	WANG Wentao, TANG Bingtao, MA Wei, et al. Easy approach to assembling a biomimetic color film with tunable structural colors[J]. Journal Optical Society of America A, 2015, 32(6): 1109-1117.
29	WANG Wentao, FAN Xiaoqiao, LI Feihu, et al. Magnetochromic photonic hydrogel for an alternating magnetic field-responsive color display[J]. Advanced Optical Materials, 2018, 6(4): 1701093.
30	WANG Wentao, TANG Bingtao, JU Benzhi, et al. Size-controlled synthesis of water-dispersible superparamagnetic Fe₃O₄ nanoclusters and their magnetic responsiveness[J]. RSC Advances, 2015, 5(92): 75292-75299.
31	SU Xin, CHANG Jie, WU Suli, et al. Synthesis of highly uniform Cu₂O spheres by a two-step approach and their assembly to form photonic crystals with a brilliant color[J]. Nanoscale, 2016, 8(11): 6155-6161.
32	BI Jiajie, WU Yue, LI Lu, et al. Asymmetric structural colors based on monodisperse single crystal Cu₂O spheres[J]. Nanoscale, 2020, 12(5): 3220-3226.
33	WANG Fen, ZHANG Xin, LIN Ying, et al. Fabrication and characterization of structurally colored pigments based on carbon-modified ZnS nanospheres[J]. Journal of Materials Chemistry C, 2016, 4(15): 3321-3327.
34	LADMIRAL Vincent, MORINAGA Takashi, OHNO Kohji, et al. Synthesis of monodisperse zinc sulfide particles grafted with concentrated polystyrene brush by surface-initiated nitroxide-mediated polymerization[J]. European Polymer Journal, 2009, 45(10): 2788-2796.
35	JOSEPHSON David, POPCZUN Eric, STEIN Andreas. Effects of integrated carbon as a light absorber on the coloration of photonic crystal-based pigments[J]. The Journal of Physical Chemistry C, 2013, 117(26): 13585-13592.
36	WU Suli, LIU Baoqi, SU Xin, et al. Structural color patterns on paper fabricated by inkjet printer and their application in anticounterfeiting[J]. The Journal of Physical Chemistry Letters, 2017, 8(13): 2835-2841.
37	JIANG Xuchuan, HERRICKS Thurston, XIA Younan. Monodispersed spherical colloids of titania: synthesis, characterization, and crystallization[J]. Advanced Materials, 2003, 15(14): 1205-1209.
38	ZENG Fang, SUN Zaiwu, WU Shuizhu, et al. Preparation of highly charged, monodisperse nanospheres[J]. Macromolecular Chemistry and Physics, 2002, 203(4): 673-677.
39	STOBER Werner, FINK Arthur, BOHN Ernst. Controlled growth of monodisperse silica spheres in the micron size range[J]. Journal of Colloid and Interface Science, 1968, 26(1): 62-69.
40	ZHOU Lan, WU Yujiang, LIU Guojin, et al. Fabrication of high‐quality silica photonic crystals on polyester fabrics by gravitational sedimentation self-assembly[J]. Coloration Technology, 2015, 131(6): 413-423.
41	CARMONA-CARMONA A J, PALOMINO-OVANDO M A, HERNANDEZ-CRISTOBAL O, et al. Synthesis and characterization of magnetic opal/Fe₃O₄ colloidal crystal[J]. Journal of Crystal Growth, 2017, 462: 6-11.
42	TANG Bingtao, WU Cheng, LIN Tao, et al. Heat-resistant PMMA photonic crystal films with bright structural color[J]. Dyes and Pigments, 2013, 99(3): 1022-1028.
43	WU Youshen, LI Yan, QIN Lei, et al. Monodispersed or narrow-dispersed melamine-formaldehyde resin polymer colloidal spheres preparation, size-control, modification, bioconjugation and particle formation mechanism[J]. Journal of Materials Chemistry B, 2013, 1(2): 204-212.
44	QIAN Jiasheng, LIU Mingxian, GAN Lihua, et al. A seeded synthetic strategy for uniform polymer and carbon nanospheres with tunable sizes for high performance electrochemical energy storage[J]. Chemical Communications, 2013, 49(29): 3043-3045.
45	LI Feihu, TANG Bingtao, WU Suli, et al. Facile synthesis of monodispersed polysulfide spheres for building structural colors with high color visibility and broad viewing angle[J]. Small, 2017, 13(3): 1602565.
46	WANG Fen, ZHANG Xin, LIN Ying, et al. Structural coloration pigments based on carbon modified ZnS@SiO₂ nanospheres with low-angle dependence, high color saturation, and enhanced stability[J]. ACS Applied Materials & Interfaces, 2016, 8(7): 5009-5016.
47	WANG Jingxia, WEN Yongqiang, GE Hongli, et al. Simple fabrication of full color colloidal crystal films with tough mechanical strength[J]. Macromolecular Chemistry and Physics, 2006, 207(6): 596-604.
48	YI Bo, SHEN Huifang. Facile fabrication of crack-free photonic crystals with enhanced color contrast and low angle dependence[J]. Journal of Materials Chemistry C, 2017, 5(32): 8194-8200.
49	WU Jia, NIU Wenbin, ZHANG Shufen, et al. A flexible and robust dual-network supramolecular elastic film with solvent resistance and brilliant structural colors[J]. New Journal of Chemistry, 2019, 43(29): 11517-11523.
50	WANG Fen, FENG Li, QIN Yi, et al. Dual functional SiO₂@TiO₂ photonic crystals for dazzling structural colors and enhanced photocatalytic activity[J]. Journal of Materials Chemistry C, 2019, 7(38): 11972-11983.
51	LIU Guojin, ZHOU Lan, ZHANG Guoqing, et al. Fabrication of patterned photonic crystals with brilliant structural colors on fabric substrates using inkjet printing technology[J]. Materials & Design, 2017, 114: 10-17.
52	李飞虎. 缩聚型含硫聚合物微球的制备及其结构生色性能研究[D]. 大连: 大连理工大学, 2017.
	LI Feihu. Synthesis of polycondensation-type sulfur-containing polymeric microspheres and their structuralcolor properties[D]. Dalian: Dalian University of Technology, 2017.
53	周岚, 陈洋, 吴玉江, 等. SiO₂胶体微球在蚕丝织物上的重力沉降自组装条件研究[J]. 蚕业科学, 2016, 42(3): 494-499.
	ZHOU Lan, CHEN Yang, WU Yujiang, et al. An investigation on gravitational sedimentation self-assembly of SiO₂ colloidal microspheres on silk fabrics[J]. Science of Sericulture, 2016, 42(3): 494-499.
54	LIU Guojin, SHAO Jianzhong, ZHANG Yun, et al. Self-assembly behavior of polystyrene/methacrylic acid [P(St-MAA)] colloidal microspheres on polyester fabrics by gravitational sedimentation[J]. The Journal of the Textile Institute, 2015, 106(12): 1293-1305.
55	LIU Fangfang, XIU Jinghai, TANG Bingtao, et al. Dynamic monitoring of thermally assisted assembly of colloidal crystals[J]. Journal of Materials Science, 2017, 52(13): 7883-7892.
56	LIU Guojin, ZHOU Lan, WU Yujiang, et al. The fabrication of full color P(St‐MAA) photonic crystal structure on polyester fabrics by vertical deposition self-assembly[J]. Journal of Applied Polymer Science, 2015, 132(13): 41750.
57	ABRAMOVA Vera, SINITSKII Alexander. Large-scale ZnO inverse opal films fabricated by a sol-gel technique[J]. Superlattices and Microstructures, 2009, 45(6): 624-629.
58	Younggun KO, DONG Hunshin. Effects of liquid bridge between colloidal spheres and evaporation temperature on fabrication of colloidal multilayers[J]. The Journal of Physical Chemistry B, 2007, 111: 1545-1551.
59	MENG Fantao, UMAIR Malikmuhammad, ZHANG Shufen, et al. Thermal-guided interfacial confinement to fabricate flexible structural color composites for durable applications[J]. Journal of Materials Chemistry C, 2019, 7(36): 11258-11264.
60	GE Dengteng, YANG Lili, WU Gaoxiang, et al. Angle-independent colours from spray coated quasi-amorphous arrays of nanoparticles: combination of constructive interference and Rayleigh scattering[J]. Journal of Materials Chemistry C, 2014, 2(22): 4395-4400.
61	Hyunmoon NAM, SONG Kyungjun, Dogyeong HA, et al. Inkjet printing based mono-layered photonic crystal patterning for anti-counterfeiting structural colors[J]. Scientific Reports, 2016, 6(1): 30885.
62	KESKIN O Y, DALMIS R, BIRLIK I, et al. Comparison of the effect of non-metal and rare-earth element doping on structural and optical properties of CuO/TiO₂ one-dimensional photonic crystals[J]. Journal of Alloys and Compounds, 2020, 817: 153262.
63	WANG Zhanhua, ZHANG Junhu, LI Jiaxin, et al. Colorful detection of organic solvents based on responsive organic/inorganic hybrid one-dimensional photonic crystals[J]. Journal of Materials Chemistry, 2011, 21(4): 1264-1270.
64	黎哲祺, 卢裕能, 谭海湖, 等. 图案化胶体光子晶体的制备与防伪应用研究进展[J]. 包装学报, 2019, 11(5): 50-59.
	LI Zheqi, LU Yuneng, TAN Haihu, et al. Progress in fabrication of patterned colloidal photonic crystals and anti-counterfeiting application[J]. Packaging Journal, 2019, 11(5): 50-59.
65	王文涛. 超顺磁Fe₃O₄团簇的可控制备及其磁热性能应用研究[D]. 大连: 大连理工大学, 2018.
	WANG Wentao. Controllable synthesis of superparamagnetic Fe₃O₄ clusters and their application of magnetothermal properties[D]. Dalian: Dalian University of Technology, 2018.
66	ZHANG Xin, NIU Yongan, ZHAO Jiupeng, et al. Self-assembly, structural order and mechanism of γ-Fe₂O₃@SiO₂ ellipsoids induced by magnetic fields[J]. New Journal of Chemistry, 2016, 40(11): 9520-9525.
67	GE Jianping, HU Yongxing, YIN Yadong. Highly tunable superparamagnetic colloidal photonic crystals[J]. Angewandte Chemie: International Edition, 2007, 46(39): 7428-7431.
68	SHAN A A, GANESAN M, JOCZ J, et al. Direct current electric field assembly of colloidal crystals displaying reversible structural color[J]. ACS Nano, 2014, 8(8): 8095-8103.
69	MENG Yao, TANG Bingtao, JU Benzhi, et al. Multiple colors output on voile through 3D colloidal crystals with robust mechanical properties [J]. ACS Applied Materials & Interfaces, 2017, 9(3): 3024-3029.
70	ZHOU Lan, LI Yichen, LIU Guojin, et al. Study on the correlations between the structural colors of photonic crystals and the base colors of textile fabric substrates[J]. Dyes and Pigments, 2016, 133, 435-444.
71	DONG Ziye, ZHANG Nan, WANG Yinggui, et al. Photopatternable nanolayered polymeric films with fast tunable color responses triggered by humidity[J]. Advanced Functional Materials, 2019, 29(43): 1904453.
72	STUMPEL J E, BROER D J, SCHENNING A P H J. Water-responsive dual-coloured photonic polymer coatings based on cholesteric liquid crystals[J]. RSC Advances, 2015, 5(115): 94650-94653.
73	MENG Yao, LIU Fangfang, UMAIR Malikmuhammad, et al. Patterned and iridescent plastics with 3D Inverse opal structure for anticounterfeiting of the banknotes[J]. Advanced Optical Materials, 2018, 6(8):1701351.
74	MENG Yao, QIU Jinjing, WU Suli, et al. Biomimetic structural color films with bilayer inverse heterostructure for anti-counterfeiting application[J]. ACS Applied Materials & Interfaces, 2018, 10(3): 38459-38465.

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