化工进展 ›› 2018, Vol. 37 ›› Issue (02): 744-751.DOI: 10.16085/j.issn.1000-6613.2017-1015
方梦祥, 姚鹏, 岑建孟, 余春江, 王勤辉, 骆仲泱
收稿日期:
2017-05-27
修回日期:
2017-07-27
出版日期:
2018-02-05
发布日期:
2018-02-05
通讯作者:
岑建孟,工学博士,研究方向为煤分级转化多联产技术的研究及开发。
作者简介:
方梦祥(1965-),男,工学博士,教授,目前主要从事煤及生物质燃烧和气化技术、CO2控制技术的研究。E-mail:mxfang@zju.edu.cn。
基金资助:
FANG Mengxiang, YAO Peng, CEN Jianmeng, YU Chunjiang, WANG Qinhui, LUO Zhongyang
Received:
2017-05-27
Revised:
2017-07-27
Online:
2018-02-05
Published:
2018-02-05
摘要: 含酚废水对环境和生物有较大危害,是一种常见的化工废水。活性炭作为良好的吸附剂被广泛用于污水处理,也常被用于吸附处理含酚废水。最新的研究集中于开发利用各种含碳原材料,并探究活性炭制备和改性方法,以改善活性炭对酚类的吸附性能。部分机理研究则关注活性炭的孔隙结构和表面官能团及其对吸附酚类性能的影响。本文从活性炭的制备和改性出发,归纳整理活性炭吸附酚类的特性和机理,分析吸附过程的主要影响因素,并对研究发展方向进行推论和展望。分析表明含碳量高的原材料适合制备活性炭,尤其是含碳废弃物。活性炭的苯酚吸附性能受比表面积和表面官能团的共同影响,这对于活性炭的制备和改性有指导意义。活性炭吸附苯酚的具体应用中,需要控制粒度、pH、温度、吸附时间和竞争吸附等影响因素。
中图分类号:
方梦祥, 姚鹏, 岑建孟, 余春江, 王勤辉, 骆仲泱. 活性炭吸附处理含酚废水的研究进展[J]. 化工进展, 2018, 37(02): 744-751.
FANG Mengxiang, YAO Peng, CEN Jianmeng, YU Chunjiang, WANG Qinhui, LUO Zhongyang. Adsorption treatment of phenolic wastewater by activated carbon: a review[J]. Chemical Industry and Engineering Progress, 2018, 37(02): 744-751.
[1] LIU Q S, ZHENG T, WANG P, et al. Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers[J]. Chemical Engineering Journal, 2010, 157(2):348-356. [2] BUSCA G, BERARDINELLI S, RESINI C, et al. Technologies for the removal of phenol from fluid streams:a short review of recent developments[J]. Journal of Hazardous Materials, 2008, 160(2):265-288. [3] AHMARUZZAMAN M. Adsorption of phenolic compounds on low-cost adsorbents:a review[J]. Advances in Colloid and Interface Science, 2008, 143(1):48-67. [4] FRASCARI D, BACCA A E M, ZAMA F, et al. Olive mill wastewater valorisation through phenolic compounds adsorption in a continuous flow column[J]. Chemical Engineering Journal, 2016, 283:293-303. [5] NAFEES M, WASEEM A. Organoclays as sorbent material for phenolic compounds:a review[J]. Clean——Soil, Air, Water, 2014, 42(11):1500-1508. [6] YOUSEF R I, EL-ESWED B, AL-MUHTASEB A A H. Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions:kinetics, mechanism, and thermodynamics studies[J]. Chemical Engineering Journal, 2011, 171(3):1143-1149. [7] CHAI X L, ZHAO Y C. Adsorption of phenolic compound by aged-refuse[J]. Journal of Hazardous Materials, 2006, 137(1):410-417. [8] 沈曾民. 活性炭材料的制备与应用[M]. 北京:化学工业出版社, 2006:10. SHEN Z M. Preparation and application of activated carbon materials[M]. Beijing:Chemical Industry Press, 2006:10. [9] HUNTER C A, SANDERS J K M. The nature of π-π interactions[J]. Journal of the American Chemical Society, 1990, 112(14):5525-5534. [10] CAM L M, VAN KHU L, HA N N. Theoretical study on the adsorption of phenol on activated carbon using density functional theory[J]. Journal of Molecular Modeling, 2013, 19(10):4395-4402. [11] MATTSON J A, MARK H B, MALBIN M D, et al. Surface chemistry of active carbon:specific adsorption of phenols[J]. Journal of Colloid and Interface Science, 1969, 31(1):116-130. [12] PAN D, JARONIEC M. Adsorption and thermogravimetric studies of unmodified and oxidized active carbons[J]. Langmuir, 1996, 12(15):3657-3665. [13] LIN S H, JUANG R S. Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents:a review[J]. Journal of Environmental Management, 2009, 90(3):1336-1349. [14] GIRALDO L, MORENO-PIRAJÁN J C. Study of adsorption of phenol on activated carbons obtained from eggshells[J]. Journal of Analytical and Applied Pyrolysis, 2014, 106:41-47. [15] RODRIGUES L A, DA SILVA M L C P, ALVAREZ-MENDES M O, et al. Phenol removal from aqueous solution by activated carbon produced from avocado kernel seeds[J]. Chemical Engineering Journal, 2011, 174(1):49-57. [16] LORENC-GRABOWSKA E, GRYGLEWICZ G, DIEZ M A. Kinetics and equilibrium study of phenol adsorption on nitrogen-enriched activated carbons[J]. Fuel, 2013, 114:235-243. [17] YU Y, ZHUANG Y Y, WANG Z H, et al. Adsorption of watersoluble dyes onto modified resin[J]. Chemosphere, 2004, 54(3):425-430. [18] LIU Y. Is the free energy change of adsorption correctly calculated?[J]. Journal of Chemical & Engineering Data, 2009, 54(7):1981-1985. [19] CHENG W P, GAO W, CUI X, et al. Phenol adsorption equilibrium and kinetics on zeolite X/activated carbon composite[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016, 62:192-198. [20] NATH K, PANCHANI S, BHAKHAR M S, et al. Preparation of activated carbon from dried pods of Prosopis cineraria with zinc chloride activation for the removal of phenol[J]. Environmental Science and Pollution Research, 2013, 20(6):4030-4045. [21] RODRIGUES L A, DE SOUSA RIBEIRO L A, THIM G P, et al. Activated carbon derived from macadamia nut shells:an effective adsorbent for phenol removal[J]. Journal of Porous Materials, 2013, 20(4):619-627. [22] 张颖. 高比表面积稻壳基活性炭制备及其在废水处理中应用研究[D]. 长沙:中南大学, 2012. ZHANG Y. Preparation of high specific surface area rice husk-based activated carbon and its application research on wastewater treatment[D]. Changsha:Central South University, 2012. [23] MIAO Q, TANG Y, XU J, et al. Activated carbon prepared from soybean straw for phenol adsorption[J]. Journal of the Taiwan Institute of Chemical Engineers, 2013, 44(3):458-465. [24] DOUARA N, BESTANI B, BENDERDOUCHE N, et al. Sawdust-based activated carbon ability in the removal of phenol-based organics from aqueous media[J]. Desalination and Water Treatment, 2016, 57(12):5529-5545. [25] RINCÓN-SILVA N G, MORENO-PIRAJÁN J C, GIRALDO L G. Thermodynamic study of adsorption of phenol, 4-chlorophenol, and 4-nitrophenol on activated carbon obtained from eucalyptus seed[J]. Journal of Chemistry, 2015.DOI:10.1155/2015/569403. [26] TEMDRARA L, ADDOUN A, KHELIFI A. Development of olivestones-activated carbons by physical, chemical and physicochemical methods for phenol removal:a comparative study[J]. Desalination and Water Treatment, 2015, 53(2):452-461. [27] KILIC M, APAYDIN-VAROL E, PÜTÜN A E. Adsorptive removal of phenol from aqueous solutions on activated carbon prepared from tobacco residues:equilibrium, kinetics and thermodynamics[J]. Journal of Hazardous Materials, 2011, 189(1):397-403. [28] 程相乐. 膨胀石墨-活性炭成型复合材料的制备及其苯酚吸附性能的研究[D]. 镇江:江苏大学, 2015. CHENG X L. Preparation of expanded graphite-activated carbon composites and study on its phenol adsorption properties[D]. Zhenjiang:Jiangsu University, 2015. [29] LORENC-GRABOWSKA E, DIEZ M A, GRYGLEWICZ G. Influence of pore size distribution on the adsorption of phenol on PET-based activated carbons[J]. Journal of Colloid and Interface Science, 2016, 469:205-212. [30] TSYNTSARSKI B G, PETROVA B N, BUDINOVA T K, et al. Removal of phenol from contaminated water by activated carbon, produced from waste coal material[J]. Bulgarian Chemical Communications, 2014, 46(2):353-361. [31] ZHOU B, GAO Q, WANG H, et al. Preparation, characterization, and phenol adsorption of activated carbons from oxytetracycline bacterial residue[J]. Journal of the Air & Waste Management Association, 2012, 62(12):1394-1402. [32] PIRZADEH K, GHOREYSHI A A. Phenol removal from aqueous phase by adsorption on activated carbon prepared from paper mill sludge[J]. Desalination and Water Treatment, 2014, 52(34/35/36):6505-6518. [33] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会. 煤质颗粒活性炭试验方法苯酚吸附值的测定:GB/T 7702.8-2008[S]. 北京, 中国标准出版社, 2008. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China. Test method for granular activated carbon from coal——Determination of phenol adsorption:GB/T 7702.8-2008[S]. Beijing:Standards Press of China, 2008. [34] MA Y, GAO N, CHU W, et al. Removal of phenol by powdered activated carbon adsorption[J]. Frontiers of Environmental Science & Engineering, 2013, 7(2):158-165. [35] CHEN Y D, HUANG M J, HUANG B, et al. Mesoporous activated carbon from inherently potassium-rich pokeweed by in situ self-activation and its use for phenol removal[J]. Journal of Analytical and Applied Pyrolysis, 2012, 98(10):159-165. [36] HOUARI M, HAMDI B, BOURAS O, et al. Static sorption of phenol and 4-nitrophenol onto composite geomaterials based on montmorillonite, activated carbon and cement[J]. Chemical Engineering Journal, 2014, 255(6):506-512. [37] RINCÓN-SILVA N G, MORENO-PIRAJÁN J C, GIRALDO L. Equilibrium, kinetics and thermodynamics study of phenols adsorption onto activated carbon obtained from lignocellulosic material(Eucalyptus Globulus labill seed)[J]. Adsorption, 2016, 22(1):33-48. [38] SMETS K, DE JONG M, LUPUL I, et al. Rapeseed and raspberry seed cakes as inexpensive raw materials in the production of activated carbon by physical activation:effect of activation conditions on textural and phenol adsorption characteristics[J]. Materials, 2016, 9(7):565. [39] RIVERA-UTRILLA J, SÁNCHEZ-POLO M, GÓMEZ-SERRANO V, et al. Activated carbon modifications to enhance its water treatment applications:an overview[J]. Journal of Hazardous Materials, 2011, 187(1):1-23. [40] YIN C Y, AROUA M K, DAUD W M A W. Review of modifications of activated carbon for enhancing contaminant uptakes from aqueous solutions[J]. Separation and Purification Technology, 2007, 52(3):403-415. [41] PETROVA B, TSYNTSARSKI B, BUDINOVA T, et al. Activated carbon from coal tar pitch and furfural for the removal of p-nitrophenol and m-aminophenol[J]. Chemical Engineering Journal, 2011, 172(1):102-108. [42] STAVROPOULOS G G, SAMARAS P, SAKELLAROPOULOS G P. Effect of activated carbons modification on porosity, surface structure and phenol adsorption[J]. Journal of Hazardous Materials, 2008, 151(2):414-421. [43] GOKCE Y, AKTAS Z. Nitric acid modification of activated carbon produced from waste tea and adsorption of methylene blue and phenol[J]. Applied Surface Science, 2014, 313(10):352-359. [44] HAYDAR S, FERRO-GARCIA M A, RIVERA-UTRILLA J, et al. Adsorption of p-nitrophenol on an activated carbon with different oxidations[J]. Carbon, 2003, 41(3):387-395. [45] CARVAJAL-BERNAL A M, GÓMEZ F, GIRALDO L, et al. Adsorption of phenol and 2,4-dinitrophenol on activated carbons with surface modifications[J]. Microporous and Mesoporous Materials, 2015, 209:150-156. [46] ZHANG D, HUO P, LIU W. Behavior of phenol adsorption on thermal modified activated carbon[J]. Chinese Journal of Chemical Engineering, 2016, 24(4):446-452. [47] YANG G, CHEN H, QIN H, et al. Amination of activated carbon for enhancing phenol adsorption:effect of nitrogen-containing functional groups[J]. Applied Surface Science, 2014, 293(3):299-305. [48] 丁春生,倪芳明,曾海明,等. 活性炭的改性及其对苯酚吸附行为的研究[J]. 炭素, 2010(4):8-12. DING C S, NI F M, ZENG H M, et al. Study on the modification of activated carbon and its adsorption behavior for phenol[J]. Carbon, 2010(4):8-12. [49] YAM L W, LIM L, HOSSEINI S, et al. Enhancement of phenol adsorption on mesoporous carbon monolith modified by NaOH and NH3:equilibrium and kinetic studies[J]. Desalination and Water Treatment, 2016, 57(9):4183-4193. [50] ABUSSAUD B, ASMALY H A, IHSANULLAH, et al. Sorption of phenol from waters on activated carbon impregnated with iron oxide, aluminum oxide and titanium oxide[J]. Journal of Molecular Liquids, 2016, 213:351-359. [51] 杨英,孟红旗,李素敏. 金属盐改性活性炭吸附去除水中苯酚实验研究[J]. 河南理工大学学报(自然科学版), 2012, 31(5):617-621. YANG Y, MENG H Q, LI S M. Experimental study on adsorption performance of phenol in water with activated carbon by metal salts modified[J]. Journal of Henan Polytechnic University (Nature Science), 2012, 31(5):617-621. [52] 张悦. DBD等离子体改性活性炭及对废炭中苯酚降解的研究[D]. 大连:大连理工大学, 2008. ZHANG Y. Study on DBD plasma modified activated carbon and degradation of phenol in waste[D]. Dalian:Dalian University of Technology, 2008. [53] 岳媛,胡学伟,李静园,等. 活性炭粒径对吸附不同分子质量有机污染物的影响[J]. 工业水处理, 2014, 34(1):54-57. YUE Y, HU X W, LI J Y, et al. Effect of particle size of activated carbon on the adsorption for organic pollutants with different molecular weights[J]. Industrial Water Treatment, 2014, 34(1):54-57. [54] HUA C, ZHANG R, LI L, et al. Adsorption of phenol from aqueous solutions using activated carbon prepared from crofton weed[J]. Desalination and Water Treatment, 2012, 37(1/2/3):230-237. [55] FENG J, QIAO K, PEI L, et al. Using activated carbon prepared from Typha orientalis Presl to remove phenol from aqueous solutions[J]. Ecological Engineering, 2015, 84:209-217. [56] LV G C, HAO J, LIU L, et al. The adsorption of phenol by lignite activated carbon[J]. Chinese Journal of Chemical Engineering, 2011, 19(3):380-385. [57] ABDEL-GHANI N T, EL-CHAGHABY G A, HELAL F S. Preparation, characterization and phenol adsorption capacity of activated carbons from African beech wood sawdust[J]. Global Journal of Environmental Science and Management, 2016, 2(3):209-222. [58] SURESH S, SRIVASTAVA V C, MISHRA I M. Adsorptive removal of phenol from binary aqueous solution with aniline and 4-nitrophenol by granular activated carbon[J]. Chemical Engineering Journal, 2011, 171(3):997-1003. [59] AHMARUZZAMAN M, SHARMA D K. Adsorption of phenols from wastewater[J]. Journal of Colloid and Interface Science, 2005, 287(1):14-24. [60] CARMONA M, GARCIA M T, CARNICER Á, et al. Adsorption of phenol and chlorophenols onto granular activated carbon and their desorption by supercritical CO2[J]. Journal of Chemical Technology & Biotechnology, 2014, 89(11):1660-1667. [61] SULAYMON A H, ABBOOD D W, ALI A H. A comparative adsorption/biosorption for the removal of phenol and lead onto granular activated carbon and dried anaerobic sludge[J]. Desalination and Water Treatment, 2013, 51(10/11/12):2055-2067. [62] ARCIBAR-OROZCO J A, RANGEL-MENDEZ J R, DIAZ-FLORES P E. Simultaneous adsorption of Pb(Ⅱ)-Cd(Ⅱ), Pb(Ⅱ)-phenol, and Cd(Ⅱ)-phenol by activated carbon cloth in aqueous solution[J]. Water Air & Soil Pollution, 2015, 226(1):2197. [63] HUANG R, YANG B, LIU Q, et al. Multifunctional activated carbon/chitosan composite preparation and its simultaneous adsorption of phenol and Cr(Ⅵ) from aqueous solutions[J]. Environmental Progress & Sustainable Energy, 2014, 33(3):814-823. [64] LIU Q, YANG B, ZHANG L, et al. Simultaneous adsorption of phenol and Cu2+ from aqueous solution by activated carbon/chitosan composite[J]. Korean Journal of Chemical Engineering,2014,31(9):1608-1615. [65] AGARWAL B, BALOMAJUMDER C. Removal of phenol and cyanide in multi-substrate system using copper impregnated activated carbon(Cu-GAC)[J]. Environmental Progress & Sustainable Energy, 2015, 34(6):1714-1723. [66] 陈女. 丙酮-苯酚水溶液在活性炭上的吸附平衡研究[D]. 上海:同济大学, 2007. CHEN N. Study on adsorption equilibrium of acetone-phenol aqueous solution on activated carbon[D]. Shanghai:Tongji University, 2007. [67] 林永波,肖玲玲,蔡体久. 腐殖酸、细颗粒泥沙对粉末活性炭吸附苯酚特性影响的研究[J]. 环境污染与防治, 2007, 29(7):514-516. LIN Y B, XIAO L L, CAI T J. Effect of humic acid and fine grain sediments on adsorption of phenol on activated carbon[J]. Environmental Pollution and Prevention, 2007, 29(7):514-516. [68] ANDRIANTSIFERANA C, JULCOUR-LEBIGUE C, CREANGAMANOLE C, et al. Competitive adsorption of p-hydroxybenzoic acid and phenol on activated carbon:Experimental study and modeling[J]. Journal of Environmental Engineering, 2013, 139(3):402-409. [69] TAN I A W, AHMAD A L, HAMEED B H. Fixed-bed adsorption performance of oil palm shell-based activated carbon for removal of 2,4,6-trichlorophenol[J]. Bioresource Technology, 2009, 100(3):1494-1496. [70] KULKARNI S J, TAPRE R W, PATIL S V, et al. Adsorption of phenol from wastewater in fluidized bed using coconut shell activated carbon[J]. Procedia Engineering, 2013, 51:300-307. [71] LAM S, SIN J, MOHAMED A R. Parameter effect on photocatalytic degradation of phenol using TiO2-P25/activated carbon (AC)[J]. Korean Journal of Chemical Engineering, 2010, 27(4):1109-1116. [72] PAN R R, FAN F L, LI Y, et al. Microwave regeneration of phenol-loaded activated carbons obtained from Arundo donax and waste fiberboard[J]. RSC Advances, 2016, 6(39):32960-32966. [73] TANG S, LU N, LI J, et al. Design and application of an up-scaled dielectric barrier discharge plasma reactor for regeneration of phenol-saturated granular activated carbon[J]. Separation and Purification Technology, 2012, 95(30):73-79. [74] CHARINPANITKUL T, TANTHAPANICHAKOON W. Regeneration of activated carbons saturated with pyridine or phenol using supercritical water oxidation method enhanced with hydrogen peroxide[J]. Journal of Industrial and Engineering Chemistry, 2011, 17(3):570-574. |
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