刺激响应性聚合物的设计、合成及其应用研究新进展

doi:10.16085/j.issn.1000-6613.2015.08.027

化工进展 ›› 2015, Vol. 34 ›› Issue (08): 3075-3084,3098.DOI: 10.16085/j.issn.1000-6613.2015.08.027

刺激响应性聚合物的设计、合成及其应用研究新进展

杨倩丽^1,2, 康晓明¹, 孙静¹, 魏柳荷¹, 马志²

1 郑州市弹性密封材料重点实验室, 郑州大学化学与分子工程学院, 河南郑州 450052;
2 中国科学院有机功能分子合成与组装化学重点实验室, 中国科学院上海有机化学研究所, 上海 200032

收稿日期:2014-11-19 修回日期:2015-03-23 出版日期:2015-08-05 发布日期:2015-08-05
通讯作者: 马志,博士,研究员,主要研究方向涉及功能化聚烯烃材料、有机软物质材料的设计、合成、结构与性能研究。E-mail mazhi728@sioc.ac.cn。
作者简介:杨倩丽(1989—),女,硕士研究生,研究方向为功能聚合物的设计合成及其应用。
基金资助:
国家自然科学基金项目(21074146, 21374130)。

New progress in the design, synthesis and application of stimuli responsive polymers

YANG Qianli^1,2, KANG Xiaoming¹, SUN Jing¹, WEI Liuhe¹, MA Zhi²

1 Zhengzhou Key Laboratory of Elastic Sealing Materials, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, Henan, China;
2 Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Received:2014-11-19 Revised:2015-03-23 Online:2015-08-05 Published:2015-08-05

摘要/Abstract

摘要： 介绍了研究刺激响应性聚合物的意义,针对水体系中的刺激响应性聚合物,介绍了近年来刺激响应性聚合物的设计与合成中的应用研究新进展,主要从3个方面进行阐述:①单一刺激响应性聚合物,包括温度、pH值、光、其他刺激响应性聚合物;②双重刺激响应性聚合物,包括温度-pH值、温度-光、温度-氧化还原刺激响应聚合物、pH值-氧化还原刺激响应聚合物;③多重刺激响应性聚合物,包括温度-光-pH值、温度-光-氧化还原、温度-pH值-CO₂刺激响应聚合物。着重评述了水体系中双重和多重刺激响应性聚合物的合成研究及应用。最后总结了多重刺激响应性聚合物应用研究的现状及问题,指出开发刺激响应性高度可控、灵敏度高、可逆性好的新型多重刺激响应性聚合物是未来的研究方向。

关键词: 刺激响应性, 设计与合成, 聚合物, 聚合, 水溶液

Abstract: This review first describes the general significance of the study on stimuli-responsive polymers. Then the latest research progress in the design, synthesis and application of stimuli-responsive polymers in aqueous solution is reviewed. Three kinds of stimuli-responsive polymers are introduced:① single stimuli-responsive polymers:temperature, pH, light and other single stimuli-responsive polymers. ②dual stimuli-responsive polymers:temperature/pH, temperature/light and temperature/redox stimuli-responsive polymers. ③ multiple stimuli-responsive polymers:temperature/light/pH, temperature/light/redox and temperature/pH/CO₂ stimuli-responsive polymers. In addition, the dual and multiple stimuli-responsive polymers are intensively reviewed. At last, the current situation and problems of multiple stimuli-responsive polymers are summarized, and the development of multiple stimulus responsive polymers with high sensitivity, high sensitivity and good reversikility will be the future development directions.

Key words: stimuli-responsive, design and synthesis, polymers, polymerization, solution

中图分类号:

杨倩丽, 康晓明, 孙静, 魏柳荷, 马志. 刺激响应性聚合物的设计、合成及其应用研究新进展[J]. 化工进展, 2015, 34(08): 3075-3084,3098.

YANG Qianli, KANG Xiaoming, SUN Jing, WEI Liuhe, MA Zhi. New progress in the design, synthesis and application of stimuli responsive polymers[J]. Chemical Industry and Engineering Progree, 2015, 34(08): 3075-3084,3098.

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刺激响应性聚合物的设计、合成及其应用研究新进展

New progress in the design, synthesis and application of stimuli responsive polymers

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