化工进展 ›› 2025, Vol. 44 ›› Issue (S1): 277-287.DOI: 10.16085/j.issn.1000-6613.2025-0854

• 材料科学与技术 • 上一篇    

石蜡基复合相变材料及其在储能系统中的应用

甘玉凤(), 陈静然, 周志华, 潘春荣, 张大千, 钟骏薇()   

  1. 江西理工大学机电工程学院,江西 赣州 341000
  • 收稿日期:2025-06-16 修回日期:2025-08-28 出版日期:2025-10-25 发布日期:2025-11-24
  • 通讯作者: 钟骏薇
  • 作者简介:甘玉凤(1987—),女,博士,讲师,研究方向为多相流、相变冷却。E-mail:9120200023@jxust.edu.cn
  • 基金资助:
    江西省自然科学基金(20242BAB20217);江西省重大科技研发专项(2023ACG01004)

Research on paraffin-based composite phase change materials and applications in energy storage systems

GAN Yufeng(), CHEN Jingran, ZHOU Zhihua, PAN Chunrong, ZHANG Daqian, ZHONG Junwei()   

  1. School of Mechanical and Electrical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China
  • Received:2025-06-16 Revised:2025-08-28 Online:2025-10-25 Published:2025-11-24
  • Contact: ZHONG Junwei

摘要:

石蜡(PW)作为典型相变材料(PCM)具有潜热值高、稳定性能好、成本低廉等突出优点,能够在相变过程中吸收/放出热量保持储能系统的温度,提升系统能源效率,可应用于诸多场景。然而热导率低、相变过程易泄漏等固有缺陷严重制约了石蜡在工业规模化应用中的可靠性,限制了其在实际应用中的推广。与功能材料复合是优化石蜡性能的有效途径,本文介绍了4类目前常见的石蜡基复合相变材料:石蜡多孔复合相变材料、石蜡纳米颗粒复合相变材料、石蜡微胶囊复合相变材料以及石蜡多元复合相变材料。本文系统性梳理了各类功能材料改性原理及改性后复合材料的性能参数,并阐述了石蜡基复合相变材料在各类储能领域的研究和应用以及人工智能在相变材料研究中发挥的作用,分析表明不同功能材料在抑制泄漏、提升导热性、强化循环稳定性方面各具优势,但仍难以兼顾成本、潜热问题。未来急需研发低泄漏、高导热性、环境友好、经济适配、环境适宜的石蜡基复合相变材料,以契合多元市场需求。

关键词: 石蜡, 复合材料, 热性能, 储能系统, 多孔介质, 纳米粒子

Abstract:

Paraffin wax, as a typical phase change material, has outstanding advantages such as high latent heat value, good stability and low cost. It can absorb or release heat during the phase change process to maintain the temperature of the energy storage system and improve the energy efficiency of the system, and can be applied in many scenarios. However, its inherent defects such as low thermal conductivity and easy leakage during the phase change process seriously restrict the reliability of paraffin wax in large-scale industrial applications and limit its promotion in practical applications. Compositing with functional materials is an effective way to optimize the performance of paraffin wax. This paper introduced four common types of paraffin-based composite phase change materials: Porous paraffin composite phase change materials, paraffin nanoparticle composite phase change materials, paraffin phase change microcapsule composite phase change materials and paraffin multi-component composite phase change materials. It systematically reviewed the modification principles of various functional materials and the performance parameters of the modified composite materials, and elaborated on the research and application of paraffin-based composite phase change materials in various energy storage fields as well as the role of artificial intelligence in the research of phase change materials. The analysis showed that different functional materials had their own advantages in inhibiting leakage, enhancing thermal conductivity and strengthening cycle stability, but it was still difficult to balance cost and latent heat issues. In the future, it was urgent to develop paraffin-based composite phase change materials with low leakage, high thermal conductivity, environmental friendliness, economic adaptability and environmental suitability to meet the diverse market demands.

Key words: paraffin, composite, thermal properties, energy storage system, porous media, nanoparticles

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