蒽醌法制过氧化氢工艺中工作液的应用性能研究进展

doi:10.16085/j.issn.1000-6613.2024-1645

摘要/Abstract

摘要：

从溶解度、沸点、密度、黏度等物理性质方面出发，本文汇总对比了蒽醌法制过氧化氢装置常用工作液成分的特点。不同工作液成分在气液传质、与水互溶度、液液分离、降解特征等应用性质方面存在差异，同一种工作液成分的同分异构体、杂质含量的不同，均会影响工作液的性质，进而影响过氧化氢生产装置氢化、氧化、萃取、后处理各工序的运行状况。工作液在过氧化氢生产装置中循环，不断发生氢化、氧化反应，并且会接触酸性、碱性环境，化学稳定性不足的工作液成分会发生过度降解，过多的降解物会影响过氧化氢生产装置的稳定运行，降低过氧化氢产品品质。工作液成分或其降解物残留于过氧化氢水溶液中还可能对高纯过氧化氢制备、化工合成等下游领域的应用产生不利影响。

关键词: 蒽醌法, 工作液, 工作液成分, 过氧化氢, 化工合成

Abstract:

From the aspects of physical properties such as solubility, boiling point, density, and viscosity, the characteristics of the commonly-used working solution components in hydrogen peroxide production devices through the anthraquinone process were summarized and compared. The disparities in application properties, including gas-liquid mass transfer, water miscibility, liquid-liquid separation, and degradation characteristics between different working solution components, as well as the variations in isomers and impurity contents of the same working solution component, all had an impact on the properties of the working solution, thereby influencing the operational status of hydrogenation process, oxidation process, extraction process, and post-treatment process in hydrogen peroxide production devices. The working solution circulated in the hydrogen peroxide production device, undergoing hydrogenation and oxidation reactions constantly, and it was exposed to acidic and alkaline environments. Working solution components with insufficient chemical stability would undergo excessive degradation, affecting the stable operation of the hydrogen peroxide production device and reducing the quality of the hydrogen peroxide product. The residue of the working solution component or its degradation products in the hydrogen peroxide aqueous solution might also exert an influence on the application effects in downstream fields such as application of high-purity hydrogen peroxide and chemical synthesis.

Key words: anthraquinone process, working solution, working solution component, hydrogen peroxide, chemical synthesis

中图分类号:

TQ123.6

庞飞, 马准准, 申敬敬, 许颖睿, 柴春玲, 白立光, 赵晓东. 蒽醌法制过氧化氢工艺中工作液的应用性能研究进展[J]. 化工进展, 2025, 44(11): 6581-6588.

PANG Fei, MA Zhunzhun, SHEN Jingjing, XU Yingrui, CHAI Chunling, BAI Liguang, ZHAO Xiaodong. Research progress on the application performance of working solution in production of hydrogen peroxide by anthraquinone process[J]. Chemical Industry and Engineering Progress, 2025, 44(11): 6581-6588.

图/表 3

参考文献 71

[1]	陈冠荣. 化工百科全书: 第6卷[M]. 北京; 化学工业出版社. 1994: 646.
	CHEN Guanrong. encyclopedia of chemical engineering: Volume 6[M]. Beijing: Chemical industry Press, 1994: 646.
[2]	姚冬龄, 张小平. 中国蒽醌法生产过氧化氢的发展过程及技术进步[J]. 无机盐工业, 2020, 52(6): 1-7, 19.
	YAO Dongling, ZHANG Xiaoping. Development progress and technical process of hydrogen peroxide production by anthraquinone process in China[J]. Inorganic Chemicals Industry, 2020, 52(6): 1-7, 19.
[3]	NYSTROM Mats, JARNVIK Christina. Chemical process and composition: US20020110515[P]. 2002-08-15.
[4]	ERIK Bengtsson. Aromatic solvent for hydrogen peroxide production: EP3342750A1[P]. 2018-07-04.
[5]	国家质量监督检验检疫总局, 中国国家标准化管理委员会. 高沸点芳烃溶剂: [S]. 北京: 中国标准出版社, 2017.
	General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of the People’s Republic of China. High-flash aromatic hydrocarbon solvents: [S]. Beijing: Standards Press of China, 2017.
[6]	赵晓东, 沈冲, 冯彬, 等. 含AR+TOP+TBU三元溶剂工作液在过氧化氢生产中的应用[J]. 化学推进剂与高分子材料, 2017, 15(1): 85-89.
	ZHAO Xiaodong, SHEN Chong, FENG Bin, et al. Application of working solution containing AR+TOP+TBU ternary solvents in hydrogen peroxide production[J]. Chemical Propellants & Polymeric Materials, 2017, 15(1): 85-89.
[7]	郑小华, 徐振祥. 基于含2-甲基环己基醋酸酯工作液体系的过氧化氢生产装置改造[J]. 化学推进剂与高分子材料, 2020, 18(1): 68-72.
	ZHENG Xiaohua, XU Zhenxiang. Transform of hydrogen peroxide production plant based on working solution system containing 2-methylcyclohexyl acetate[J]. Chemical Propellants & Polymeric Materials, 2020, 18(1): 68-72.
[8]	RANBOM Wayne. Hydrogen peroxide process: US04394369A[P]. 1983-07-19.
[9]	潘智勇, 郑博, 张晓昕, 等. 一种蒽醌法生产过氧化氢的工作液和一种过氧化氢的生产方法: CN116002627A[P]. 2023-04-25.
	PAN Zhiyong, ZHENG Bo, ZHANG Xiaoxin, et al. Working solution for producing hydrogen peroxide by anthraquinone method and production method of hydrogen peroxide: CN116002627A[P]. 2023-04-25.
[10]	HALASA Matej, GANHY Jean-Pierre, LIEBENS Armin T. Method for the production of hydrogen peroxide: US20120027667[P]. 2012-02-02.
[11]	Abdelatif BABA-AHMED, ANDRE David, BOSSOUTROT Jean-Michel, et al. Process for the production of hydrogen peroxide: US20240253988[P]. 2024-08-01.
[12]	李中, 赵晓东, 张惠平, 等. 含四丁基脲工作液新工艺在工业过氧化氢生产中的应用[J]. 化学推进剂与高分子材料, 2015, 13(5): 1-6.
	LI Zhong, ZHAO Xiaodong, ZHANG Huiping, et al. Application of new technology using tetrabutylurea-containing working solution in production of hydrogen peroxide[J]. Chemical Propellants & Polymeric Materials, 2015, 13(5): 1-6.
[13]	张蓉蓉, 窦茂斌, 袁恩先, 等. 均三甲苯/二异丁基甲醇混合溶剂黏度测定及关联[J]. 化工学报, 2015, 66(9): 3377-3382.
	ZHANG Rongrong, DOU Maobin, YUAN Enxian, et al. Measurement and correlation of viscosities of mixed solvents 1,3,5-trimethylbenzene and diisobutylcarbinol[J]. CIESC Journal, 2015, 66(9): 3377-3382.
[14]	刘航, 方向晨, 贾立明, 等. 蒽醌法生产H₂O₂工作液的改进[J]. 石油学报(石油加工), 2015, 31(1): 72-77.
	LIU Hang, FANG Xiangchen, JIA Liming, et al. Improvement of working solution for H₂O₂ production by anthraquinone method[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2015, 31(1): 72-77.
[15]	寇志豪, 朱爱萍, 苏广文, 等. 四丁基脲在蒽醌法制备过氧化氢工艺中的应用研究[J]. 化学推进剂与高分子材料, 2005, 3(5): 21-25.
	KOU Zhihao, ZHU Aiping, SU Guangwen, et al. Application research of tetrabutyl urea in hydrogen peroxide preparation by anthraquinone process[J]. Chemical Propellants & Polymeric Materials, 2005, 3(5): 21-25.
[16]	REN Xiangwei, PAN Zhiyong, ZHAO Wentao, et al. Measurement and correlation of solubility of 2-alkylanthraquinone (ethyl, tert-butyl and tert-amyl) in mixed solvents of 1,3,5-trimethylbenzene and tetrabutylurea[J]. The Journal of Chemical Thermodynamics, 2023, 184: 107085.
[17]	庞玉娜, 冯庆霞, 董宝田, 等. 高效液相色谱法测定过氧化氢工作液中2-乙基蒽醌、2-戊基蒽醌及其氢化物[J]. 化学分析计量, 2021, 30(5): 28-31.
	PANG Yuna, FENG Qingxia, DONG Baotian, et al. Determination of 2-ethylanthraquinone, 2-pentylanthraquinone and their hydrides in hydrogen peroxide working-solution by high performance liquid chromatography[J]. Chemical Analysis and Meterage, 2021, 30(5): 28-31.
[18]	中石化巴陵石油化工有限公司己内酰胺产业链搬迁与升级转型发展项目环境影响报告书（公示稿）[EB/OL].(2021-03-17)[2024-10-13]. .
	Sinopec Baling Petrochemical Co., Ltd.. Environmental impact assessment report for the relocation and upgrading of caprolactam industry chain development project (public draft)[EB/OL]. (2021-03-17)[2024-10-13]. .
[19]	泰兴菱苏机能新材料有限公司. 年产7万吨双氧水（折百）及相关衍生物项目[EB/OL]. (2021-06-25)[2024-10-13]. .
	Taixing Lingsu Functional New Materials Co., Ltd.. Environmental impact assessment report for the annual production of 70000 tons of high purity hydrogen peroxide (converted to 100%) and related derivatives project[EB/OL]. (2021-06-25)[2024-10-13]. .
[20]	贾雪婷. 二元溶剂中烷基蒽醌衍生物溶解度的测定与关联[D]. 天津: 天津大学, 2014.
	JIA Xueting. Measurement and correlation of solubilities of alkylanthraquinone derivatives in binary solvents[D]. Tianjin: Tianjin University, 2014.
[21]	赵晓东, 张哲, 沈冲, 等. 烷基蒽醌加氢用钯催化剂使用性能影响因素分析: “中国无机盐工业协会过氧化物分会2020行业年会”论文集[C]. 北京: 中国无机盐工业协会, 2020.
	ZHAO Xiaodong, ZHANG Zhe, SHEN Chong, et al. Analysis of factors affecting the performance of palladium catalysts for alkyl anthraquinone hydrogenation: “Peroxide branch of China inorganic salts industry associaion 2020” annual symposium[C]. Beijing: China Inorganic Salts Industry Association, 2020.
[22]	LEI Zhigang, GUO Yaru, GUO Yanyan, et al. H₂ solubility and mass transfer in anthraquinone working solution: Experimental and modeling study[J]. Chinese Journal of Chemical Engineering, 2017, 25(2): 143-148.
[23]	白红鑫, 方向晨, 刘全杰, 等. 2-烷基蒽醌加氢合成过氧化氢的动力学研究[J]. 化学反应工程与工艺, 2022, 38(5): 453-460.
	BAI Hongxin, FANG Xiangchen, LIU Quanjie, et al. Kinetics study for hydrogenation of 2-alkylanthraquinone to hydrogen peroxide[J]. Chemical Reaction Engineering and Technology, 2022, 38(5): 453-460.
[24]	白红鑫, 方向晨, 刘全杰, 等. 蒽醌法生产双氧水工作液溶剂体系: CN115947310A[P]. 2023-04-11.
	BAI Hongxin, FANG Xiangchen, LIU Quanjie, et al. Solvent system for producing hydrogen peroxide working solution by anthraquinone method: CN115947310A[P]. 2023-04-11.
[25]	BAI Hongxin, FANG Xiangchen, PENG Chong. Novel working solvent for the production of hydrogen peroxide[J]. Industrial & Engineering Chemistry Research, 2019, 58(16): 6948-6956.
[26]	DESMEDT Frédérique Jacqueline, HODGE Philip, JANSSENS Francine. Process for the manufacture of hydrogen peroxide: WO2012041918A2[P]. 2012-06-21.
[27]	KOGYO Kabushiki. Process for the cyclic production of hydrogen peroxide: GB875189[P]. 1961-08-16.
[28]	Jüergen GLENNEBERG, GOOR Gustaf, STAAB Eugen, et al. Method of producing hydrogen peroxide and reaction promoters therefor: US6153169[P]. 2002-03-12.
[29]	邱彬, 柴春玲, 明扬帆, 等. 蒽醌降解物再生剂的研究进展[J]. 化学推进剂与高分子材料, 2024, 22(4): 1-6.
	QIU Bin, CHAI Chunling, MING Yangfan, et al. Progress in study of regenerating agents for degradation products of anthraquinone[J]. Chemical Propellants & Polymeric Materials, 2024, 22(4): 1-6.
[30]	SAKAITANI Hisashi, IURA Katsuhiro, HAGIWARA Isao, et al. Method for producing hydrogen peroxide: US20080213164[P]. 2008-09-04.
[31]	冯坤. 2-叔戊基蒽的制备过程研究[D]. 杭州: 浙江大学, 2021.
	FENG Kun. Study on the preparation process of 2-tert-pentylanthracene[D]. Hangzhou: Zhejiang University, 2021.
[32]	郑博, 潘智勇, 朱振兴, 等. 一种由蒽制备蒽醌衍生物并用于生产过氧化氢的方法: CN114906819A[P]. 2022-08-16.
	ZHENG Bo, PAN Zhiyong, ZHU Zhenxing, et al. Method for preparing anthraquinone derivative from anthracene and producing hydrogen peroxide: CN114906819A[P]. 2022-08-16.
[33]	潘智勇, 郑博, 张晓昕, 等. 一种多烷基蒽醌工作液及其应用: CN116062702A[P]. 2023-05-05.
	PAN Zhiyong, ZHENG Bo, ZHANG Xiaoxin, et al. Polyalkyl anthraquinone working solution and application thereof: CN116062702A[P]. 2023-05-05.
[34]	白立光, 马会强, 柴春玲, 等. 一种蒽醌法生产过氧化氢用工作液载体的制备方法和应用: CN117682483A[P]. 2024-03-12.
	BAI Liguang, MA Huiqiang, CHAI Chunling, et al. Preparation method and application of working solution carrier for producing hydrogen peroxide by anthraquinone method: CN117682483A[P]. 2024-03-12.
[35]	姚冬龄. 中国过氧化氢生产现状及展望[J]. 无机盐工业, 2013, 45(9): 1-4, 23.
	YAO Dongling. Current situation and outlook of hydrogen peroxide production in China[J]. Inorganic Chemicals Industry, 2013, 45(9): 1-4, 23.
[36]	HASEGAWA Hiroshi, KOZAWA Yukako, TAKEUCHI Motoharu. Method for regenerating working solution used for production of hydrogen peroxide and method for producing hydrogen peroxide using regenerated working solution: US20160200574[P]. 2016-07-14.
[37]	郑博, 宗保宁, 朱振兴, 等. 烷基蒽醌工作液及其配制方法以及过氧化氢的生产方法: CN114906820A[P]. 2022-08-16.
	ZHENG Bo, ZONG Baoning, ZHU Zhenxing, et al. Alkyl anthraquinone working solution, preparation method thereof and production method of hydrogen peroxide: CN114906820A[P]. 2022-08-16.
[38]	KABISCH Gerhard, TRUBE Rudolf. Process for the production of hydrogen peroxide: US3761581[P]. 1973-09-25.
[39]	GOOR Gustaaf, KUNKEL Wolfgang. Process for the production of hydrogen peroxide: US4349526[P]. 1982-09-14.
[40]	PRALUS Christian. Process for the cyclic production of hydrogen peroxide: US4803063[P]. 1989-02-07.
[41]	白红鑫, 方向晨, 刘全杰, 等. 蒽醌法合成双氧水的工作液: CN118324097A[P]. 2024-07-12.
	BAI Hongxin, FANG Xiangchen, LIU Quanjie, et al. Working solution for synthesizing hydrogen peroxide by anthraquinone method: CN118324097A[P]. 2024-07-12.
[42]	THILMANY Pierre, GILLIN Frédéric, LORENT Karol, et al. Process for manufacturing an aqueous hydrogen peroxide solution by using alkyl-cyclohexane carbonitrile solvents: WO2024125974[P]. 2024-06-20.
[43]	李娜. 双氧水装置工作液质量管控及氧化铝性能研究[J]. 氮肥与合成气, 2023, 51(1): 1-2.
	LI Na. Quality control of working solution in hydrogen peroxide plant and study on performance of aluminum oxide[J]. Nitrogenous Fertilizer & Syngas, 2023, 51(1): 1-2.
[44]	吴敏杰. 蒽醌法制过氧化氢工艺中2-乙基蒽醌和四烷基脲的合成及性能研究[D]. 北京: 北京化工大学, 2019.
	WU Minjie. Study on synthesis and properties of 2-ethylhydrazine and tetraalkylurea in hydrogen peroxide process[D]. Beijing: Beijing University of Chemical Technology, 2019.
[45]	王晓韡, 夏小明, 徐振祥, 等. 一种用于蒽醌法过氧化氢生产的工作液: CN101798065A[P]. 2010-08-11.
	WANG Xiaowei, XIA Xiaoming, XU Zhenxiang, et al. Formula of working liquid for hydrogen peroxide production based on anthraquinone process: CN101798065A[P]. 2010-08-11.
[46]	方向晨, 白红鑫, 刘全杰, 等. 一种工作液溶剂体系: CN111071993A[P]. 2020-04-28.
	FANG Xiangchen, BAI Hongxin, LIU Quanjie, et al. Working solution solvent system: CN111071993A[P]. 2020-04-28.
[47]	JIA Xuewu, SUN Feng, FEI Yi, et al. Explosion characteristics of mixtures containing hydrogen peroxide and working solution in the anthraquinone route to hydrogen peroxide[J]. Process Safety and Environmental Protection, 2018, 119: 218-222.
[48]	庞飞, 许颖睿, 柴春玲, 等. 蒽醌法过氧化氢生产工艺中废弃活性氧化铝的回收利用研究概况[J]. 无机盐工业, 2023, 55(6): 1-7, 49.
	PANG Fei, XU Yingrui, CHAI Chunling, et al. Overview on recycling of waste activated alumina in production of hydrogen peroxide by anthraquinone process[J]. Inorganic Chemicals Industry, 2023, 55(6): 1-7, 49.
[49]	熊烨, 程义, 汤亚文, 等. 氢蒽醌溶剂的水解稳定性研究[J]. 化学反应工程与工艺, 2023, 39(4): 343-349.
	XIONG Ye, CHENG Yi, TANG Yawen, et al. Study on hydrolytic stability of hydroanthraquinone solvents[J]. Chemical Reaction Engineering and Technology, 2023, 39(4): 343-349.
[50]	GIESSELMANN Gunter, SCHREYER Gerd, WEIGERT Wolfgang. Process for the production of hydrogen peroxide: US3767778[P]. 1973-10-23.
[51]	关盛文. 固体酸催化合成2-戊基蒽醌的研究[D]. 长春: 吉林大学, 2017.
	GUAN Shengwen. Study on the catalytic synthesis of 2-amylanthraquinone over solid acid[D]. Changchun: Jilin University, 2017.
[52]	钱余锋. 2-叔戊基蒽醌的合成工艺研究[D]. 天津: 天津大学, 2015.
	QIAN Yufeng. Study on the procedure of 2-tert-amyl anthraquinone[D]. Tianjin: Tianjin University, 2015.
[53]	EGGERSDORFER Manfred, HENKELMANN Jochen, GROSCH Walter. 2-neopentylanthraquinone, processes for its preparation and methods for its use: US5107004[P]. 1992-04-21.
[54]	GODFRINE Pierre, LUIS Denaeyer Jose. Procédé cyclique de fabrication de peroxyde d'hydrogène: CH507871[P]. 1971-05-31.
[55]	TAYLOR John Martin. Improvements in or relating to the cyclic process for the production of hydrogen peroxide: GB943683A[P]. 1963-12-04.
[56]	HINEGARDNER Wilbie S, SPRAUER Jerome W. Purification of 2-t-butylanthraquinone: US2842563[P]. 1958-07-08.
[57]	LEE Nathan D, SETHI Dalbir S. Purification of alkylated anthraquinones: US4544543[P]. 1985-10-01.
[58]	昌德新材料科技股份有限公司. 工业用二异丁基甲醇: Q/ [S]. 岳阳: 2022.
	Changde New Material Science and Technology Co., Ltd.. Diisobutyl carbinol for industrial use: Q/ [S]. Yueyang: 2022-02-16.
[59]	櫛田泰宏. 過酸化水素製造用作動溶液および該作動溶液を用いた過酸化水素の製造方法: JP2018203554[P]. 2018-12-27.
	KUSHIDA Yasuhiro. Working solution for producing hydrogen peroxide and method for producing hydrogen peroxide using the same: JP2018203554[P]. 2018-12-27.
[60]	张晶晶. 过氧化氢分配系数的测定与关联及新型溶剂的筛选[D]. 天津: 天津大学, 2022.
	ZHANG Jingjing. Measurment and correlation of hydrogen peroxide distribution coefficient and exploration of new solvents[D]. Tianjin: Tianjin University, 2022.
[61]	沈冲, 庞飞, 柴春玲, 等. 磷酸三辛酯的合成工艺概况[J]. 化学推进剂与高分子材料, 2021, 19(6): 1-7.
	SHEN Chong, PANG Fei, CHAI Chunling, et al. Overview of synthesis process of trioctyl phosphate[J]. Chemical Propellants & Polymeric Materials, 2021, 19(6): 1-7.
[62]	杭州潜阳科技有限公司. 磷酸三辛酯: [S]. 杭州: 2017.
	Hangzhou Qianyang Technology Co., Ltd.. Trioctyl phosphate: [S]. Hangzhou: 2017.
[63]	孙启文. 煤炭间接液化[M]. 北京: 化学工业出版社, 2012.
	SUN Qiwen. Indirect coal liquefaction[M]. Beijing: Chemical Industry Press, 2012.
[64]	郑博, 潘智勇, 唐晓津, 等. 2-烷基蒽醌工作液的预处理方法以及过氧化氢的生产方法: CN110885061A[P]. 2020-03-17.
	ZHENG Bo, PAN Zhiyong, TANG Xiaojin, et al. Pretreatment method of 2-alkylanthraquinone working solution and production method of hydrogen peroxide: CN110885061A[P]. 2020-03-17.
[65]	胡渤, 武本成, 朱建华, 等. 原油中有机氯化物分布转化情况及危害性研究进展[J]. 世界石油工业, 2024, 31(3): 90-99.
	HU Bo, WU Bencheng, ZHU Jianhua, et al. Research progress on the distribution, transformation and hazards of organochloride compounds in crude oil[J]. World Petroleum Industry, 2024, 31(3): 90-99.
[66]	松浦慎一郎, 長谷川浩, 竹内基晴. 過酸化水素製造に使用される作動溶液、および該作動溶液の処理方法、並びに該作動溶液を用いた過酸化水素の製造方法: JP2014224009[P]. 2014-12-04.
	MATSUURA Shinichiro, HASEGAWA Hiroshi, TAKEUCHI Motoharu. Actuating solution used for hydrogen peroxide production, processing method of the same, and method of hydrogen peroxide production using the same: JP2014224009[P]. 2014-12-04.
[67]	刘泉军, 唐建业, 周怀国. 一种 2-(4-甲基-3-戊烯基)蒽醌的合成方法: CN116003235A[P]. 2023-04-25.
	LIU Quanjun, TANG Jianye, ZHOU Huaiguo. Synthesis method of 2-(4-methyl-3-pentenyl) anthraquinone: CN116003235A[P]. 2023-04-25.
[68]	刘柯, 黎斯明, 吕小敏, 等. 双氧水中总碳含量的影响因素及优化措施探讨[J]. 合成纤维工业, 2022, 45(1): 90-92, 96.
	LIU Ke, LI Siming, Xiaomin LYU, et al. Influential factors on total carbon content in hydrogen peroxide and optimization measures[J]. China Synthetic Fiber Industry, 2022, 45(1): 90-92, 96.
[69]	豆振江, 杜玮辰, 韩林, 等. 双氧水吸附净化工艺中失活树脂的失活机制及再生方法研究[J]. 南京工业大学学报(自然科学版), 2024, 46(1): 20-27.
	DOU Zhenjiang, DU Weichen, HAN Lin, et al. Study on deactivation mechanism and regeneration method of deactivated resin in hydrogen peroxide adsorption purification process[J]. Journal of Nanjing Tech University (Natural Science Edition), 2024, 46(1): 20-27.
[70]	BRASSE Claudia, Jürgen GLENNEBERG, HAAS Thomas, et al. Novel aqueous hydrogen peroxide solutions: WO2004028962[P]. 2004-04-08.
[71]	RIEDEL Dominic, TELES Joaquim Henrique, MORMUL Jaroslaw Michael, et al. HO2 without DIBC for PO production: US20230145404[P]. 2023-05-11.

重芳烃牌号	沸程/℃	闭口闪点/℃	密度/g·cm^-3
SA-1000（C₉重芳烃为主）	149~180	≥38	0.861~0.878
SA-1500（C₁₀重芳烃为主）	177~215	≥61	0.877~0.907

重芳烃牌号	沸程/℃	闭口闪点/℃	密度/g·cm^-3
SA-1000（C₉重芳烃为主）	149~180	≥38	0.861~0.878
SA-1500（C₁₀重芳烃为主）	177~215	≥61	0.877~0.907

极性溶剂	20℃密度^[12]/g·cm^-3	30℃黏度^[12-13]/mPa·s	沸点/℃	闭口闪点/℃	50℃分配系数^[12]①	水中溶解度^[12]/mg·L^-1	EAQ溶解度/g·L^-1
TOP	0.923	10.8	220（667Pa）	≥170	77.1	230（20℃）	110^[14]②
TBU	0.877	10.4	310	140	86.6	133（25℃）	161^[15]③
MCA	0.950	2.5	185	65	206.5	450（25℃）	180^[14]④
DIBC	0.813	7.79	173	72	132.7	660（20℃）	190^[14]④

极性溶剂	20℃密度^[12]/g·cm^-3	30℃黏度^[12-13]/mPa·s	沸点/℃	闭口闪点/℃	50℃分配系数^[12]①	水中溶解度^[12]/mg·L^-1	EAQ溶解度/g·L^-1
TOP	0.923	10.8	220（667Pa）	≥170	77.1	230（20℃）	110^[14]②
TBU	0.877	10.4	310	140	86.6	133（25℃）	161^[15]③
MCA	0.950	2.5	185	65	206.5	450（25℃）	180^[14]④
DIBC	0.813	7.79	173	72	132.7	660（20℃）	190^[14]④

烷基蒽醌种类	分子量	熔点/℃	熔化焓/kJ·mol^-1	30℃溶解度^①/g·L^-1	30℃密度^①/g·cm^-3
EAQ	236.27	109.8	22.0	145.2	0.904
TBAQ	264.32	103.0	19.1	316.8	0.936
AAQ	278.35	65.0	13.0	378.6	0.939