化工进展 ›› 2024, Vol. 43 ›› Issue (6): 3128-3144.DOI: 10.16085/j.issn.1000-6613.2023-0815
• 材料科学与技术 • 上一篇
谢蒙蒙1,2(), 刘健1(
), 党蕊2(
), 李美馨1,2, 林晓婷1, 苏舟1, 王洁1
收稿日期:
2023-05-15
修回日期:
2023-08-18
出版日期:
2024-06-15
发布日期:
2024-07-02
通讯作者:
刘健,党蕊
作者简介:
谢蒙蒙(1997—),女,硕士研究生,研究方向为导电水凝胶及柔性可穿戴电子。E-mail:xiemeng1216@163.com。
基金资助:
XIE Mengmeng1,2(), LIU Jian1(
), DANG Rui2(
), LI Meixin1,2, LIN Xiaoting1, SU Zhou1, WANG Jie1
Received:
2023-05-15
Revised:
2023-08-18
Online:
2024-06-15
Published:
2024-07-02
Contact:
LIU Jian, DANG Rui
摘要:
离子导电水凝胶是一种具有高含水量、可拉伸性和良好生物相容性的高分子聚合物材料,聚合物网络间存在的自由离子使其表现出与人类皮肤非常相似的离子导电方式,在可穿戴传感设备、能量存储器件和生物医疗等应用领域展现出巨大潜力。本文简要介绍了离子导电水凝胶的研究背景与进展,讨论了离子导电水凝胶的制备方式,介绍了离子导电水凝胶在导电性、柔韧性、抗冻保水性、自愈合性、黏附性及生物相容性等功能特性方面的研究进展,分析和阐述了离子导电水凝胶材料相关的应用研究进展。最后,总结了离子导电水凝胶材料在稳定性、环境适应性、多功能协同匹配性等方面存在的问题与挑战,展望了离子导电水凝胶材料的发展趋势及前景,指出开发具有高导电性、极端环境稳定性、自愈合性能及生物可降解性的功能可调控离子导电水凝胶将成为下一步的研究重点,同时结合无线传感网络技术、自供电设备开发无线传感及自供电功能的可穿戴传感系统也将成为重要的研究方向之一。
中图分类号:
谢蒙蒙, 刘健, 党蕊, 李美馨, 林晓婷, 苏舟, 王洁. 离子导电水凝胶的制备及在柔性电子领域的应用[J]. 化工进展, 2024, 43(6): 3128-3144.
XIE Mengmeng, LIU Jian, DANG Rui, LI Meixin, LIN Xiaoting, SU Zhou, WANG Jie. Preparation of ionic conductive hydrogels and its applications in flexible electronic[J]. Chemical Industry and Engineering Progress, 2024, 43(6): 3128-3144.
水凝胶 | 导电介质 | 电导率/S·m-1 | 灵敏度(GF) | 断裂伸长率/% | 拉伸应力/kPa | 应用 | 参考文献 |
---|---|---|---|---|---|---|---|
P(AA-AM)-Fe3+/CS-SO42- | Fe3+; SO42- | 3.04 | 6 | 1225 | 5100 | 传感器 | [ |
PAM/卡拉胶/KCl | KCl | — | 0.63 | 2000 | 550 | 传感器 | [ |
DA-Fe-PAA | Fe3+ | 30 | — | >2000 | 13 | 传感器 | [ |
P(SBMA-HEMA)/XLG | XLG;SBMA | 0.24 | 1.8 | 2000 | 270 | 传感器 | [ |
PVA/PVP/CNCs-Fe3+ | Fe3+ | — | 0.478 | 830 | 2100 | 传感器 | [ |
GMA-SA-PAM | NaCl | 5.26 | — | 407 | 21.63 | 传感器 | [ |
PAM-CMC/Ca2+ | Ca2+ | 1.4 | 1.42 | 1480 | 276 | 传感器 | [ |
PAM/SC/CMS-Na | Na+ | 6.12 | — | 3300 | 320 | 传感器 | [ |
PAM-SA/CaCl2 | CaCl2 | 8 | — | 400 | — | 超级电容器 | [ |
PAM/干酪素/LiCl | LiCl | 7.53 | — | 1465 | 168 | 传感器 | [ |
PVA-NaCl-甘油 | NaCl | 9.25 | — | 575±29 | 570±20 | 超级电容器 | [ |
PVA-SA-TA-Bx | Bx; Na+ | 2.69 | 15.98 | 600 | 23 | 传感器 | [ |
PAM-CS/NaCl | NaCl | 17 | 2 | 1350 | 200 | 传感器伤口敷料 | [ |
PAA-TA@CNC-Al3+ | AlCl3 | — | 7.8 | 2800 | 300 | 传感器 | [ |
AC/NaOH-尿素 | NaOH | 0.016 | 0.3 | 126 | 50 | 传感器 | [ |
PAM-CMC/LiCl | LiCl | — | 3.15 | 1363 | 22.8 | 传感器 | [ |
PAM-铁蛋白 | 铁蛋白 | 0.067 | 2.06 | 1400 | 99 | 传感器 | [ |
PAA-AAPBA/TA | CaCl2 | — | 0.79 | 7300 | 54 | 传感器 | [ |
PNA/PVP/TA/Fe3+ | Fe3+ | 0.79 | 3.61 | 720 | — | 传感器 | [ |
P(AA-AM)/SA/ZnSO4 | ZnSO4 | — | 2.9 | 4200 | 210 | 传感器 | [ |
SA/ZnSO4/P(AM-AA) | ZnSO4 | 0.34 | — | >10000 | 150 | 摩擦纳米发电机 | [ |
表1 离子导电水凝胶的性能与应用
水凝胶 | 导电介质 | 电导率/S·m-1 | 灵敏度(GF) | 断裂伸长率/% | 拉伸应力/kPa | 应用 | 参考文献 |
---|---|---|---|---|---|---|---|
P(AA-AM)-Fe3+/CS-SO42- | Fe3+; SO42- | 3.04 | 6 | 1225 | 5100 | 传感器 | [ |
PAM/卡拉胶/KCl | KCl | — | 0.63 | 2000 | 550 | 传感器 | [ |
DA-Fe-PAA | Fe3+ | 30 | — | >2000 | 13 | 传感器 | [ |
P(SBMA-HEMA)/XLG | XLG;SBMA | 0.24 | 1.8 | 2000 | 270 | 传感器 | [ |
PVA/PVP/CNCs-Fe3+ | Fe3+ | — | 0.478 | 830 | 2100 | 传感器 | [ |
GMA-SA-PAM | NaCl | 5.26 | — | 407 | 21.63 | 传感器 | [ |
PAM-CMC/Ca2+ | Ca2+ | 1.4 | 1.42 | 1480 | 276 | 传感器 | [ |
PAM/SC/CMS-Na | Na+ | 6.12 | — | 3300 | 320 | 传感器 | [ |
PAM-SA/CaCl2 | CaCl2 | 8 | — | 400 | — | 超级电容器 | [ |
PAM/干酪素/LiCl | LiCl | 7.53 | — | 1465 | 168 | 传感器 | [ |
PVA-NaCl-甘油 | NaCl | 9.25 | — | 575±29 | 570±20 | 超级电容器 | [ |
PVA-SA-TA-Bx | Bx; Na+ | 2.69 | 15.98 | 600 | 23 | 传感器 | [ |
PAM-CS/NaCl | NaCl | 17 | 2 | 1350 | 200 | 传感器伤口敷料 | [ |
PAA-TA@CNC-Al3+ | AlCl3 | — | 7.8 | 2800 | 300 | 传感器 | [ |
AC/NaOH-尿素 | NaOH | 0.016 | 0.3 | 126 | 50 | 传感器 | [ |
PAM-CMC/LiCl | LiCl | — | 3.15 | 1363 | 22.8 | 传感器 | [ |
PAM-铁蛋白 | 铁蛋白 | 0.067 | 2.06 | 1400 | 99 | 传感器 | [ |
PAA-AAPBA/TA | CaCl2 | — | 0.79 | 7300 | 54 | 传感器 | [ |
PNA/PVP/TA/Fe3+ | Fe3+ | 0.79 | 3.61 | 720 | — | 传感器 | [ |
P(AA-AM)/SA/ZnSO4 | ZnSO4 | — | 2.9 | 4200 | 210 | 传感器 | [ |
SA/ZnSO4/P(AM-AA) | ZnSO4 | 0.34 | — | >10000 | 150 | 摩擦纳米发电机 | [ |
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