化工进展 ›› 2024, Vol. 43 ›› Issue (3): 1428-1435.DOI: 10.16085/j.issn.1000-6613.2023-0443

• 材料科学与技术 • 上一篇    

芳烃官能化有机硅膜的制备及丙烯/丙烷分离性能

钱俊明1(), 郭猛1(), 任秀秀1, 余亮2, 钟璟1, 徐荣1()   

  1. 1.常州大学石油化工学院,常州大学精细石油化工江苏省重点实验室,江苏 常州 213164
    2.北京理工大学前沿交叉科学研究院,北京 100081
  • 收稿日期:2023-03-22 修回日期:2023-06-30 出版日期:2024-03-10 发布日期:2024-04-11
  • 通讯作者: 郭猛,徐荣
  • 作者简介:钱俊明(1997—),男,硕士研究生,研究方向为功能膜材料。E-mail:2429144792@qq.com
  • 基金资助:
    江苏省自然科学基金青年基金(BK20210855);江苏省高校自然科学研究重大项目(22KJA530001);江苏省精细石油化工重点实验室开放课题(KF2105);常州市科技计划(CJ20220140)

Fabrication of aromatic functionalized organosilica membranes and gas separation performance

QIAN Junming1(), GUO Meng1(), REN Xiuxiu1, YU Liang2, ZHONG Jing1, XU Rong1()   

  1. 1.School of Petrochemical Engineering, Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
    2.Frontier Cross Science Research Institute, Beijing University of Technology, Beijing 100081, China
  • Received:2023-03-22 Revised:2023-06-30 Online:2024-03-10 Published:2024-04-11
  • Contact: GUO Meng, XU Rong

摘要:

利用具有单苯和联苯桥联结构的有机硅前体1,4-二(三乙氧基硅基)苯(BTESB)和4,4'-二(三乙氧基硅基)联苯(BTESBPh),通过溶胶-凝胶法制备成有机硅膜并应用于丙烯/丙烷分离。在25℃时,BTESB膜的C3H6渗透速率为3.4×10-9mol/(m2·s·Pa),C3H6/C3H8选择性为9.6;BTESBPh膜的C3H6渗透速率为1.7×10-8mol/(m2·s·Pa),C3H6/C3H8选择性为10.5。具有联苯桥联结构的BTESBPh膜网络结构更为疏松,可获得更高的气体渗透速率。苯环中大π键与待分离组分C3H6中的碳碳双键产生π-π相互作用,有利于C3H6组分的优先吸附和渗透。而BTESBPh中联苯结构增强了这一过程,表现为低温测试条件下,BTESBPh膜的C3H6/C3H8选择性略高于BTESB膜。本研究可为高性能丙烯/丙烷气体分离膜的开发提供参考。

关键词: 有机硅膜, 孔径, 丙烯/丙烷分离, 溶胶-凝胶法, 分子筛分

Abstract:

Two organosilica presursors, 1,4-bis (triethoxysilyl) benzene (BTESB) with benzene bridges and 4,4'-bis (triethoxysilyl) biphenyl (BTESBPh) with biphenyl bridges were utilized for the fabrication of organosilica membranes via the sol-gel strategy. The two membranes were applied to the gas separation. At 25℃, BTESB membrane displayed a C3H6 permeance of 3.4×10-9mol/(m2·s·Pa)and C3H6/C3H8 selectivity of 9.6. Nevertheless, BTESBPh membrane showed a C3H6 permeance of 1.7×10-8mol/(m2·s·Pa) and a comparable C3H6/C3H8 selectivity of 10.5. BTESBPh membrane networks with biphenyl bridged structures were much looser and could achieve higher gas permeance. The π-π interactions occurred between the big π bond in the benzene ring and the C̿    C bond in the C3H6 molecules, which was beneficial for the preferential adsorption and permeation of the C3H6 molecules. The biphenyl bridges in BTESBPh membranes enhanced the adsorption and permeation process, as evidenced by the increased C3H6/C3H8 selectivity of the BTESBPh membrane under low testing temperatures. This study could provide a reference for the development of high-performance propylene/propane separation membranes.

Key words: organosilica membranes, pore size, C3H6/C3H8 separation, sol-gel method, molecular sieving

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