化工进展 ›› 2020, Vol. 39 ›› Issue (11): 4550-4556.DOI: 10.16085/j.issn.1000-6613.2020-0081

• 材料科学与技术 • 上一篇    下一篇

离子液体接枝型PI/GO膜的制备及CO2/N2分离的应用

贝鹏志(), 刘红晶(), 张莹, 高缨佳, 胡爱军, 宾华   

  1. 沈阳工业大学石油化工学院,辽宁 辽阳 111003
  • 出版日期:2020-11-05 发布日期:2020-11-06
  • 通讯作者: 刘红晶
  • 作者简介:贝鹏志(1993—),男,硕士研究生,研究方向为气体分离膜。E-mail:beipengzhi@163.com
  • 基金资助:
    辽宁省教育厅重点攻关项目(LZGD2019004);辽宁百千万人才项目;辽宁省自然科学基金(20170540685)

Preparation of ionic liquid grafted-PI/GO membranes and its application in CO2/N2 separation

Pengzhi BEI(), Hongjing LIU(), Ying ZHANG, Yingjia GAO, Aijun HU, Hua BIN   

  1. School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, Liaoning, China
  • Online:2020-11-05 Published:2020-11-06
  • Contact: Hongjing LIU

摘要:

为了显著提高聚酰亚胺气体分离膜的气体选择性,本文首先通过含有C?????N的席夫碱特征结构将胺基化功能性离子液体([NH2ebim][PF6])以侧基的形式接枝于聚酰亚胺主链,形成了离子液体接枝型聚酰亚胺 (IL-GPI),然后再通过共混的方法向其中引入氧化石墨烯(GO),制备出IL-GPI/GO混合基质膜,并应用于CO2/N2的分离体系。分别利用傅里叶红外光谱仪(FTIR)、旋转黏度计、扫描电子显微镜(SEM)和动态热机械分析仪(DMA)对IL-GPI/GO混合基质膜进行了表征,并探讨了不同GO含量的IL-GPI/GO混合基质膜对CO2/N2气体分离性能的影响。结果表明,GO在IL-GPI/GO混合基质膜中具有较好的分散性,且混合基质膜的刚性有所增强。对不同GO含量的混合基质膜进行分离性能的比较,发现当GO质量分数为0.8%时,CO2的渗透系数可以提高到16.5Barrer,CO2/N2的选择性可提高到176,突破2008年的Robeson上限。

关键词: 膜, 离子液体, 聚酰亚胺, 氧化石墨烯, 选择性

Abstract:

The study aimed to increase the CO2/N2 selectivity of gas separation membranes. Aminated task specific ionic liquid, 1-aminoethyl-3-buthylimidazolium hexafluorophosphate ([NH2ebim][PF6]), was grafted to polyimide chains as side groups by the structure of Schiff base of C?????N to form ionic liquid grafted polyimide (IL-GPI), and then graphene oxide (GO) was added into IL-GPI by blending and IL-GPI/GO mixed matrix membranes were fabricated. IL-GPI/GO mixed matrix membranes were characterized by Fourier transform infrared spectroscopy (FTIR), rotatory viscometer, scanning electronic microscopy (SEM) and dynamic thermomechanical analysis (DMA), respectively. The effect of GO concentrations of IL-GPI/GO mixed matrix membranes on gas permeability was studied. The results showed that GO had good dispersion in MMMs and the rigidity of MMMs was enhanced. After a comparison among these mixed matrix membranes with different GO concentrations, CO2 permeability and CO2/N2 selectivity were improved to 16.5Barrer and 176 when GO mass fraction was 0.8%, respectively, which had exceeded 2008 Robeson’s upper bound.

Key words: membrane, ionic liquid, polyimide, graphene oxide, selectivity

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