化工进展 ›› 2019, Vol. 38 ›› Issue (12): 5217-5224.DOI: 10.16085/j.issn.1000-6613.2019-1088

• 特约评述 • 上一篇    下一篇

化石原料制氢技术发展现状与经济性分析

黄格省(),李锦山,魏寿祥,杨延翔,周笑洋   

  1. 中国石油天然气股份有限公司石油化工研究院,北京 102206
  • 收稿日期:2019-07-09 出版日期:2019-12-05 发布日期:2019-12-05
  • 通讯作者: 黄格省
  • 作者简介:黄格省(1965—),高级工程师,从事炼油化工、煤化工及新能源领域战略与决策支持研究。E-mail:huanggesheng@petrochina.com.cn
  • 基金资助:
    (1)甲醇裂解制氢 甲醇裂解是在300℃左右、催化剂存在下甲醇气相催化裂解,通常用于合成气制备,或通过进一步分离获得高纯CO和氢气,氢气纯度可达99.999%。该技术成熟,适用于科研实验小规模制氢场合使用

Status and economic analysis of hydrogen production technology from fossil raw materials

Gesheng HUANG(),Jinshan LI,Shouxiang WEI,Yanxiang YANG,Xiaoyang ZHOU   

  1. Petrochemical Research Institute of PetroChina, Beijing 102206, China
  • Received:2019-07-09 Online:2019-12-05 Published:2019-12-05
  • Contact: Gesheng HUANG

摘要:

对煤制氢、天然气制氢、甲醇制氢以及工业副产回收氢气等化石原料制氢技术发展现状进行了详细分析,研究对比了几种化石原料制氢技术的生产成本与经济性,并对化石原料制氢产业发展前景进行了深入思考,总体认为:煤制氢具有资源成本优势,是实现大规模制氢的首选技术;天然气制氢发展潜力大,但目前存在资源约束和成本较高的问题;工业副产回收氢气是未来颇具发展潜力的制氢方式;甲醇制氢规模灵活,但存在设备成本高、稳定性较差等不足。在当前太阳能等新能源制氢技术尚未成熟的现实条件下,化石原料制氢必将担当主要角色,未来氢能产业必将是化石原料制氢与电解水制氢、新能源制氢多种方式共存、多元化发展的供给格局。

关键词: 煤制氢, 天然气制氢, 甲醇制氢, 工业副产回收氢, 成本分析, 产业前景

Abstract:

The development status of hydrogen production technology from coal, natural gas, methanol and hydrogen recovery from industrial byproducts was analyzed in detail. The production cost and economy of several hydrogen production technologies from fossil raw materials were studied and compared, and the development prospect of hydrogen production technology from fossil raw materials was deeply considered. The conclusion was that coal hydrogen production technology had excellent resources. Coal-based hydrogen production was the preferred technology for large-scale hydrogen production because of its potential and cost advantages. Natural gas-based hydrogen production had great development potential, but there were problems of resource constraints and high cost. By-product hydrogen recovery was a potential hydrogen production mode in the future. Methanol-based hydrogen production was flexible in scale, but it had shortcomings of high equipment cost and poor stability. Under the current situation that new energy hydrogen production technologies such as solar energy were not yet mature, hydrogen production from fossil raw materials will play a major role. In the future, hydrogen industry will be the supply pattern of coexistence and diversified development of various ways of hydrogen production from fossil raw materials, electrolytic water and new energy.

Key words: coal to hydrogen, natural gas to hydrogen, methanol to hydrogen, by-product to hydrogen, cost analysis, industrial prospects

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