化工进展 ›› 2019, Vol. 38 ›› Issue (08): 3889-3895.DOI: 10.16085/j.issn.1000-6613.2018-2194

• 资源与环境化工 • 上一篇    下一篇

罗丹明荧光自组装膜制备及其对苯酚测定

胡文英1,2(),陈彰旭1,2,王天东1   

  1. 1. 莆田学院环境与生物工程学院,福建 莆田 351100
    2. 福建省新型污染物生态毒理效应与控制重点实验室,福建 莆田 351100
  • 收稿日期:2018-11-08 出版日期:2019-08-05 发布日期:2019-08-05
  • 通讯作者: 胡文英
  • 作者简介:胡文英(1974—),女,副教授,主要从事环境分析的研究。E-mail:1055490435@qq.com
  • 基金资助:
    福建省自然科学基金(2017J01421)

Preparation of Rhodamine fluorescence self-assembly membrane and its determination of phenol

Wenying HU1,2(),Zhangxu CHEN1,2,Tiandong WANG1   

  1. 1. College of Environmental and Biological Engineering, Putian University, Putian 351100, FuJian, China
    2. FuJian Key Laboratory of Ecology-Toxicological Effects & Control for Emerging Contaminants, Putian 351100, FuJian, China
  • Received:2018-11-08 Online:2019-08-05 Published:2019-08-05
  • Contact: Wenying HU

摘要:

以石英片作为基底,利用吸附作用力将壳聚糖组装到硅烷化的石英表面,罗丹明B通过与壳聚糖的酯化反应间接组装到石英表面,构建壳聚糖-罗丹明B自组装膜。对该膜进行扫描电镜(SEM)表征、荧光显微镜表征,考察膜的组装条件、膜的性质、膜与苯酚的相互作用机理及抗干扰实验。结果表明苯酚与该膜在一定的范围内呈良好的线性关系,线性范围为0.00~20.00×10-10g/L,检出限(DL)为0.13×10-10g/L,该膜具有良好的稳定性和可再生性。并且将壳聚糖-罗丹明B自组装膜应用于芳名湖水和绶溪河水中的苯酚污染物含量的测定,发现二者水中的苯酚含量均达到了国家Ⅰ类水标准,样品加标回收率在91%~97%,该自组装膜适合于痕量样品的分析检测。

关键词: 罗丹明B, 膜, 制备, 荧光, 吸附, 苯酚

Abstract:

By using Quartz as the substrate, chitosan was assembled on the silanization layer of the quartz surface by the adsorption force. Then RhB was indirectly assembled onto the surface of quartz substrate through its esterification of chitosan, and hence the chitosan-RhB self-assembled monolayer was constructed. The chitosan-RhB self-assembled membrane was characterized by SEM and fluorescence microscope, so that the assembly conditions of the self-assembled film, the properties of the self-assembled membrane, the interaction with the phenol and the anti-interference test were investigated. Linear relationship between the phenol concentration and the RhB self-assembled membrane was found in the range of 0—20×10-10g/L, and the detection limit (DL) was 0.13×10-10g/L, and the membrane showed good stability and reproducibility. Furthermore, the chitosan-RhB self-assembled membrane was applied to detect phenol in the water of lake and stream. It was found that the phenol content in both water samples reached the national water standard of Class Ⅰ, and the sample recovery rate was between 91% and 97%, which suggests that the self-assembled membrane is suitable for the analysis and detection of trace samples.

Key words: Rhodamine B, membrane, preparation, fluorescence, adsorption, phenol

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