壳聚糖功能微球负载贵金属的研究进展

doi:10.16085/j.issn.1000-6613.2017.02.027

摘要/Abstract

摘要： 贵金属凭借其空的d电子轨道、较小的能级间距和配位的多样性成为多领域研究热点，但目前价格昂贵、储量稀少、利用率低下，极大地限制了贵金属的广泛应用，因此近年来发展优异的功能载体成为贵金属应用领域的研究趋势，这不仅可以方便贵金属的回收循环利用，同时可避免体系内的痕量残留，减少环境污染。本文综述了一种廉价无毒、含有丰富羟基、氨基基团的壳聚糖绿色材料作为贵金属载体的研究近况，介绍了国内外在吸附、催化等领域应用壳聚糖材料的代表性学术成果，比较并分析了不同表面修饰手段对壳聚糖载体贵金属作用效果的影响，概括了目前壳聚糖功能载体在贵金属研究中存在的形貌研究相对局限、可控制备难以实现规模化等问题，同时预测了壳聚糖材料在生物医药领域良好的发展前景。

关键词: 复合材料, 离子交换, 催化剂载体, 吸附, 微通道

Abstract: Noble metal,has become a research focus in multiple fields due to its empty d electron orbit,small energy gap and diverse coordinations. However,high prices,rare reserves and low utilization have severely restricted their extensive application. So developing excellent functional carriers has become a hot area recently,which makes noble metals be separated from the reaction system easily and recycled effectively and avoids trace residues within the system,reducing environmental pollution. This paper reviewed recent studies of the cheap,non-toxic chitosan green materials which are rich in hydroxyl groups,amino groups and used as noble metal carriers. It also introduced domestic and international representative academic achievements which apply functionlized chitosan in adsorption,catalysis,medicine and other applications. Influences of different surface modification methods on the interaction between noble metals and chitosan carrier have been compared and analyzed. And we outlined the current problems in the noble metal research,such as relatively limited study on morphology and difficulties in controllable large-scale preparation. And its development in biological medicine has been also forecasted.

Key words: composites, ion exchange, catalyst support, adsorption, microchannels

中图分类号:

TQ028.8

崔青, 赵红, 张长桥, 徐建鸿. 壳聚糖功能微球负载贵金属的研究进展[J]. 化工进展, 2017, 36(02): 595-601.

CUI Qing, ZHAO Hong, ZHANG Changqiao, XU Jianhong. Research progress in noble metal-supported chitosan functional microspheres[J]. Chemical Industry and Engineering Progree, 2017, 36(02): 595-601.

参考文献

[1] CHEN X,LAM K F,MAK S F,et al. Precious metal recovery by selective adsorption using biosorbents[J]. J. Hazard Mater.,2011,186(1):902-910.
[2] CREAMER N J,BAXTER-PLANT V S,HENDERSON J,et al. Palladium and gold removal and recovery from precious metal solutions and electronic scrap leachates by desulfovibrio desulfuricans[J]. Biotechnol Lett.,2006,28(18):1475-1484.
[3] KAVAKLI C,MALCI S,TUNCEL S A,et al. Selective adsorption and recovery of precious metal ions from geological samples by 1,5,9,13-tetrathiacyclohexadecane-3,11-diol anchored poly(p-CMS-DVB) microbeads[J]. Reactive and Functional Polymers,2006,66:275-285.
[4] KADIB E,ABDELKRIM. Chitosan as a sustainable organocatalyst:a concise overview[J]. ChemSusChem,2015,8(2):217-244.
[5] 赵红,徐晓敏,徐建鸿,等. 微流控制备壳聚糖功能材料研究进展[J]. 化工学报,2016,67(2):373-378. ZHAO Hong,XU Xiaomin,XU Jianhong,et al. Research progress in microfluidic preparation of chitosan functional materials[J]. CIESC Journal,2016,67(2):373-378.
[6] MLADENOVA E,KARADJOVA I,TSALEV D L. Solid-phase extraction in the determination of gold,palladium,and platinum[J]. Journal of Separation Science,2012,35:1249-65.
[7] BAIG R B N,NADAGOUDA M N,VARMA R S. Ruthenium on chitosan:a recyclable heterogeneous catalyst for aqueous hydration of nitriles to amides[J]. Metrology & Measurement Technique,2003,16(4):2122-2127.
[8] VO K D N,GUILLON E,DUPONT L,et al. Influence of Au(III) interactions with chitosan on gold nanoparticle formation[J]. Journal of Physical Chemistry C,2014,118(8):4465-4474.
[9] HUANG H,YANG X. Synthesis of chitosan-stabilized gold nanoparticles in the absence/presence of tripolyphosphate[J]. Biomacromolecules,2004,5(6):2340-6.
[10] VINCENT T,GUIBAL E. Chitosan-supported palladium catalyst. 5. nitrophenol degradation using palladium supported on hollow chitosan fibers[J]. Environmental Science & Technology,2004,38(15):4233-40.
[11] 徐晓宁,曹发海. 二氧化硅微球负载钌催化剂的制备及其在苯乙酮不对称氢转移反应中的应用[J]. 化工学报,2016,67(6):2340-2348. XU Xiaoning,CAO Fahai. Preparation of mesoporous silica microsphere supported ruthenium catalysts for asymmetric transfer hydrogenation of acetophenone[J]. CIESC Journal,2016,67(6):2340-2348.
[12] HASANI-SADRABADI M M,TARANEJOO S,DASHTIMOGHADAM E,et al. Microfluidic manipulation of core/shell nanoparticles for oral delivery of chemotherapeutics:a new treatment approach for colorectal cancer[J]. Advanced Materials,2016,28(21):4134-4141.
[13] AND D J M,HARDY J J E. Applications of functionalized chitosan in catalysis[J]. Ind. Eng. Chem. Res.,2005,44(23):8499-8520.
[14] ANTONY R,MANICKAM S T D,SARAVANAN K,et al. Synthesis,spectroscopic and catalytic studies of Cu(Ⅱ),Co(Ⅱ) and Ni(Ⅱ) complexes immobilized on Schiff base modified chitosan[J]. Journal of Molecular Structure,2013,1050(42):53-60.
[15] SHI B,ZHANG M,BI J,et al. Development of a novel folic acid chitosan supported imidazole Schiff base for tumor targeted gene delivery system and drug therapy[J]. Journal of Controlled Release,2013,172(1):e98.
[16] WANG J,LIAN Z,WANG H,et al. Synthesis and antimicrobial activity of Schiff base of chitosan and acylated chitosan[J]. Journal of Applied Polymer Science,2012,123(6):3242-3247.
[17] OSHITA K,OSHIMA M,GAO Y H,et al. Adsorption behavior of mercury and precious metals on cross-linked chitosan and the removal of ultratrace amounts of mercury in concentrated hydrochloric acid by a column treatment with cross-linked chitosan[J]. Analytical Sciences the International Journal of the Japan Society for Analytical Chemistry,2002,18(10):1121-1125.
[18] RAMPINO A,BORGOGNA M,BLASI P,et al. Chitosan nanoparticles:preparation,size evolution and stability[J]. International Journal of Pharmaceutics,2013,455(1/2):219-228.
[19] MONIER M,ABDEL-LATIF D A,ABOU El-REASH Y G. Ion-imprinted modified chitosan resin for selective removal of Pd(II) ions[J]. Journal of Colloid & Interface Science,2016,469:344-354.
[20] GUIBAL E,SWEENEY N V O. Competitive sorption of platinum and palladium on chitosan derivatives[J]. International Journal of Biological Macromolecules,2001,28(5):401-408.
[21] PARDESHI C V,KULKARNI A D,SURANA S J. In vitro,ex vivo and in vivo performance of chitosan-based spray-dried nasal mucoadhesive microspheres of diltiazem hydrochloride[J]. Journal of Drug Delivery Science & Technology,2015,31(1):108-117.
[22] OLIVEIRA,FSANTANA B,RÉ M H A,et al. Spray-dried chitosan microspheres cross-linked with d,l-glyceraldehyde as a potential drug delivery system:preparation and characterization[J]. Brazilian Journal of Chemical Engineering,2005,22(3):353-360.
[23] ZHOU Z,JIANG F,LEE T C,et al. Two-step preparation of nano-scaled magnetic chitosan particles using Triton X-100 reversed-phase water-in-oil microemulsion system[J]. Journal of Alloys & Compounds,2013,581(18):843-848.
[24] XU J H,LI S W,TOTADO C,et al. Preparation of monodispersed chitosan microspheres and in situ encapsulation of BSA in a co-axial microfluidic device[J]. Biomedical Microdevices,2009,11(1):243-249.
[25] LIU L,YANG J P,JU X J,et al. Monodisperse core-shell chitosan microcapsules for pH-responsive burst release of hydrophobic drugs[C]//AIChE Meeting,2011:4821-4827.
[26] FUJIWARA,KENSUKE Ramesh,ATTINTI,et al. Adsorption of platinum(Ⅳ),palladium(Ⅱ) and gold(Ⅲ) from aqueous solutions onto L-lysine modified crosslinked chitosan resin[J]. Journal of Hazardous Materials,2007,146(1/2):39-50.
[27] DONIA A M,YOUSIF A M,ATIA A A,et al. Efficient adsorption of Ag(Ⅰ) and Au(Ⅲ) on modified magnetic chitosan with amine functionalities[J]. Desalination & Water Treatment,2014,52(13):2537-2547.
[28] LI L,CUI L,BAO C,et al. Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au(Ⅲ) and Pd(Ⅱ)[J]. Talanta,2012,93(2):350-357.
[29] GANDHI M R,MEENAKSHI S. Withdrawn:preparation and characterization of silica gel/chitosan composite for the removal of Cu(Ⅱ) and Pb(II)[J]. International Journal of Biological Macromolecules,2011,31(1):247-248.
[30] SHARIFIFARD H,ASHITIAI F Z,SOLEIMANI M. Adsorption of palladium and platinum from aqueous solutions by chitosan and activated carbon coated with chitosan[J]. Asia-Pacific Journal of Chemical Engineering,2013,8(3):384-395.
[31] WON S W,KOTTE P,WEI W,et al. Biosorbents for recovery of precious metals[J]. Bioresource Technology,2014,160(6):203-212.
[32] ARGUELLO L,HERNANDEZ-MARTINEZ A R,RODRIGUEZ A,et al. Novel chitosan/polyurethane/anatase titania porous hybrid composite for removal of metal ions wastes[J]. Journal of Chemical Technology & Biotechnology,2016,91(8):2185-2197.
[33] ZHOU L,XU J,LIANG X,et al. Adsorption of platinum(Ⅳ) and palladium(Ⅱ) from aqueous solution by magnetic cross-linking chitosan nanoparticles modified with ethylenediamine[J]. Journal of Hazardous Materials,2010,182(1/2/3):518-524.
[34] FRINDY S,PRIMO A,LAHNICI M,et al. Pd embedded in chitosan microspheres as tunable soft-materials for Sonogashira cross-coupling in water-ethanol mixture[J]. Green Chem.,2015,17(3):1893-1898.
[35] MOUCEL R,PERRIGAUD K,GOUPIL J M,et al. Importance of the conditioning of the chitosan support in a catalyst-containing ionic liquid phase immobilised on chitosan:the Palladium-catalysed allylation reaction c ase[J]. Advanced Synthesis & Catalysis,2010,352(2/3):433-439.
[36] PEIRANO F,VINCENT T,QUIGNARD F,et al. Palladium supported on chitosan hollow fiber for nitrotoluene hydrogenation[J]. Journal of Membrane Science,2009,329(1/2):30-45.
[37] SARKAR S,GUIBAL E,QUIGNARD F,et al. Polymer-supported metals and metal oxide nanoparticles:synthesis,characterization,and applications[J]. Journal of Nanoparticle Research,2012,14(2):1-24.
[38] SCHUBLER S,BLAUBACH N,STOLLE A,et al. Application of a cross-linked Pd-chitosan catalyst in liquid-phase-hydrogenation using molecular hydrogen[J]. Applied Catalysis A General,2012,s445/446(6):231-238.
[39] BANERJEE S L,KHAMRAI M,SARKAR K,et al. Modified chitosan encapsulated core-shell Ag Nps for superior antimicrobial and anticancer activity[J]. International Journal of Biological Macromolecules,2016,85:157-167.
[40] RUBINA M S,KAMITOVA E E,ZUBAVICHUS Y V,et al. Collagen-chitosan scaffold modified with Au and Ag nanoparticles:synthesis and structure[J]. Applied Surface Science,2016,366:365-371.