焦炭气化反应性对抚顺气煤容惰能力的评价

doi:10.16085/j.issn.1000-6613.2017-1149

化工进展 ›› 2018, Vol. 37 ›› Issue (03): 976-983.DOI: 10.16085/j.issn.1000-6613.2017-1149

焦炭气化反应性对抚顺气煤容惰能力的评价

蔡雪贞¹, 孙章^1,2, 王杰平^1,2, 孙晓伟¹, 梁英华^1,2

1 华北理工大学化学工程学院, 河北唐山 063210;
2 河北省煤化工工程技术研究中心, 河北唐山 063210

收稿日期:2017-06-10 修回日期:2017-08-18 出版日期:2018-03-05 发布日期:2018-03-05
通讯作者: 孙章,博士,副教授,主要从事煤化工研究与教学。
作者简介:蔡雪贞(1993-),女,硕士研究生。
基金资助:
国家自然科学基金（U1361212）及华北理工大学研究生创新项目（2017S08）。

Study on the inert-tolerant capacity of Fushun gas coal by the characteristics of coke-CO₂ gasification

CAI Xuezhen¹, SUN Zhang^1,2, WANG Jieping^1,2, SUN Xiaowei¹, LIANG Yinghua^1,2

1 College of Chemical Engineering, North China University of Science and Technology, Tangshan 063210, Hebei, China;
2 Coal Chemical Engineering Research Center of Hebei Province, Tangshan 063210, Hebei, China

Received:2017-06-10 Revised:2017-08-18 Online:2018-03-05 Published:2018-03-05

摘要/Abstract

摘要： 气煤是储量最丰富的炼焦煤，科学地评价其容惰能力对于提高气煤在配煤炼焦中的使用及降低配煤成本具有重要意义。本文将抚顺气煤的镜质组富集纯化后配入惰性组分（标准无烟煤）炼焦，以焦炭的气化反应特性评价抚顺气煤镜质组的容惰能力，并提出综合气化特性指数（G）、气化起始指数（G_s）、气化终止指数（G_d）3个指数考察焦炭的气化反应特性。研究结果表明，G、G_s、G_d随惰性组分的增加呈减小的趋势，且惰性组分质量分数为40%时，G、G_s、G_d出现骤降。运用Ozawa积分法计算气化活化能表明惰性组分配入量在20%~60%时，40%惰性组分的活化能相对较大。XRD和SEM分析也表明，惰性组分质量分数为40%时，所得焦炭基质致密均匀，芳香度大，晶格缺陷少。所以，抚顺气煤镜质组配入惰性组分的极限值是40%。

关键词: 镜质组, 气化反应, 活化能, 微晶结构, 容惰能力

Abstract: Gas coal is the most abundant coking coal reserves. The scientific evaluation of the inert-tolerant capacity of gas coals is of great significance to increase the proportion of gas coal in coal blending and reduce the cost of coal blending. The vitrinite obtained from Fushun gas coal was added to inert component(the standard anthracite) to prepare cokes. The characteristics of coke-CO₂ gasification were studied to evaluate the inert-tolerant capacity of vitrinite from Fushun gas coal. The comprehensive gasification index(G),gasification start index(G_s) and gasification end index(G_d) were put forward to investigate the characteristics of coke-CO₂ gasification. The results showed that with the increase of inert component content the G,G_s and G_d decreased. Especially,the G,G_s and G_d dropped rapidly in the 40% inert component content. The activation energies of coke gasification reaction derived from the Ozawa integration method indicated that the activation energy of the coke with the 40% inert component content had the relatively large value when the inert component content was in the range of 20%-60%. Also,XRD and SEM analyses showed that the coke with the 40% inert component content had the dense homogeneous matrix,high-aromatic degree and low-lattice imperfection. Therefore,the limit of inert component to the vitrinite of Fushun gas coal was 40%.

Key words: vitrinite, coke gasification, activation energy, microcrystalline structure, inert-tolerant capacity

中图分类号:

TQ520

蔡雪贞, 孙章, 王杰平, 孙晓伟, 梁英华. 焦炭气化反应性对抚顺气煤容惰能力的评价[J]. 化工进展, 2018, 37(03): 976-983.

CAI Xuezhen, SUN Zhang, WANG Jieping, SUN Xiaowei, LIANG Yinghua. Study on the inert-tolerant capacity of Fushun gas coal by the characteristics of coke-CO₂ gasification[J]. Chemical Industry and Engineering Progress, 2018, 37(03): 976-983.

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焦炭气化反应性对抚顺气煤容惰能力的评价

Study on the inert-tolerant capacity of Fushun gas coal by the characteristics of coke-CO₂ gasification

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焦炭气化反应性对抚顺气煤容惰能力的评价

Study on the inert-tolerant capacity of Fushun gas coal by the characteristics of coke-CO2 gasification

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Study on the inert-tolerant capacity of Fushun gas coal by the characteristics of coke-CO₂ gasification