化工进展 ›› 2018, Vol. 37 ›› Issue (02): 752-760.DOI: 10.16085/j.issn.1000-6613.2017-0860

• 资源与环境化工 • 上一篇    下一篇

含铬制革废弃物处理的研究现状和研究思路

蒋旭光1, 方纯琪1, 金余其1, 吕国钧1, 袁伟中2, 陈锡炯2, 罗伟忠2   

  1. 1 浙江大学能源清洁利用国家重点实验室, 浙江 杭州 310027;
    2 浙江浙能长兴发电有限公司, 浙江 长兴 313100
  • 收稿日期:2017-05-10 修回日期:2017-06-16 出版日期:2018-02-05 发布日期:2018-02-05
  • 通讯作者: 蒋旭光(1965-),男,教授,博士生导师,主要从事废弃物能源化与资源化方面的研究。
  • 作者简介:蒋旭光(1965-),男,教授,博士生导师,主要从事废弃物能源化与资源化方面的研究。E-mail:jiangxg@zju.edu.cn。
  • 基金资助:
    国家自然科学基金创新群体(51621005)、国家重点基础研究发展计划(2011CB201500)、国家高技术研究发展计划(2012AA063505)、国家科技支撑计划(2007BAC27B043)及环保公益性行业科研专项(201209023-4)项目。

Research status and research ideas of chrome tanning waste disposal

JIANG Xuguang1, FANG Chunqi1, JIN Yuqi1, LÜ Guojun1, YUAN Weizhong2, CHEN Xijiong2, LUO Weizhong2   

  1. 1 State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;
    2 Zhejiang Zheneng Changxing Electric Power Generation Co., Ltd., Changxing 313100, Zhejiang, China
  • Received:2017-05-10 Revised:2017-06-16 Online:2018-02-05 Published:2018-02-05

摘要: 含铬制革废弃物经过适当处理可以回收其中的能量、重金属铬和胶原蛋白,但目前不合理的处置造成了环境污染及资源浪费。本文简述了含铬制革废弃物的来源和处置现状,综合国内外最新的含铬制革废弃物处理的文献,系统总结了含铬制革废弃物处理方式的相关研究,将处置方式分为直接处理和间接处理两大类分别进行阐述,详细介绍了吸附剂、热解、焚烧这3种直接处理方式及氧化法、酸水解法、碱水解法、酶水解法这4种间接处理方式,分析了每种处置方式的原理、存在的优缺点和应用前景,简述了各种处置方式的主要作用以及优缺点对比。最后提出了含铬制革废弃物处置的研究思路,特别是开展含铬制革废弃物热解和焚烧过程中燃烧和污染物排放机理研究。

关键词: 皮革, 含铬铬鞣, 废弃物, 废物处理, 环境, 资源化利用

Abstract: The disposal of chromium containing tannery waste can recover the energy, chromium and collagen, but the unreasonable disposal has caused environment pollution and waste of resources. In this paper, the source and the current situation of disposal of chromium containing leather wastes were described. Based on the latest domestic and foreign chromium tanning waste processing literatures, the related researches of chrome tanning waste treatment and disposal were summarized. The disposal methods can be divided into two categories:direct treatment and indirect treatment. Three direct treatments including adsorbent, pyrolysis, incineration and four indirect treatments including oxidation, acid hydrolysis, alkaline hydrolysis, enzymatic hydrolysis were described in detail. The principle, advantages and disadvantages,and application prospect of each disposal method were analyzed. The main functions of various disposal methods were briefly described. Besides, the advantages and disadvantages of each method were compared. At last, the research ideas of chromium leather waste disposal were put forward. Especially, the mechanism of combustion and pollutant emission during the process of pyrolysis and incineration of chromium containing tannery wastes will be studied.

Key words: leather, chromium-tanning, waste, waste treatment, environment, resource utilization

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