TiO2/羟基磷灰石复合微球的合成

doi:10.16085/j.issn.1000-6613.2016.05.032

化工进展 ›› 2016, Vol. 35 ›› Issue (05): 1484-1489.DOI: 10.16085/j.issn.1000-6613.2016.05.032

TiO₂/羟基磷灰石复合微球的合成

那驰, 董如林, 张汉平, 陈智栋, 金长春, 王芳

常州大学石油化工学院, 江苏常州 213164

收稿日期:2015-07-15 修回日期:2015-12-02 出版日期:2016-05-05 发布日期:2016-05-05
通讯作者: 董如林,研究员,主要从事无机功能材料及复合材料的研究。E-mail dongrl@cczu.edu.cn。
作者简介:那驰(1990-),男,硕士研究生。
基金资助:
国家自然科学基金项目(51273027)。

Synthesis of TiO₂/hydroxyapatite composite microspheres

NA Chi, DONG Rulin, ZHANG Hanping, CHEN Zhidong, JIN Changchun, WANG Fang

School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China

Received:2015-07-15 Revised:2015-12-02 Online:2016-05-05 Published:2016-05-05

摘要/Abstract

摘要： 将乙酰丙酮稳定的钛酸四正丁酯分散到含有硬脂酸的水中,接着加入Ca²⁺、H₂PO₄^-源,然后通过150℃的水热过程,合成了TiO₂/羟基磷灰石(HAP)复合微球。其中的硬脂酸作为界面媒介吸附Ca²⁺,确保生成的羟基磷灰石的粒子吸附在分散的钛酸四正丁酯球形"油滴"表面。经水热过程,分散的油滴转化为TiO₂为内核,HAP为壳层的复合微球。HAP粒子组成的微球外壳层对内核钛酸四正丁酯水解及缩聚反应而引起的体积收缩产生抑制作用,从而对最终的TiO₂内核的微结构产生影响。亚甲基蓝的紫外光催化降解实验结果表明,复合微球的光催化性能与微球对亚甲基蓝的平衡吸附量有密切的关系,并取决于产品的微结构。当复合微球中羟基磷灰石的理论质量分数为1%~1.5%时,微球对亚甲基蓝显示了较高的光催化降解效率。

关键词: 二氧化钛, 羟基磷灰石, 水热, 水解, 吸附, 降解

Abstract: Titanium dioxide/hydroxyapatite (HAP) composite microspheres were synthesized by dispersing acetylacetone-stabilized tetra-n-butyltitanate in water containing stearic acid, then adding Ca²⁺and H₂PO₄^- sources, and finally employing a hydrothermal process at 150℃. Stearic acid was used as interface intermediary to adsorb Ca²⁺ and ensure the adsorption of subsequently formed hydroxyapatile particles on the surface oftetra-n-butyltitanate "oil droplets". The dispersed droplets transformed into composite microspheres with TiO₂ core and HAP shell after hydrothermal process. The shell consisting of HAP particles suppressed the volume shrinkage of the core induced by the hydrolysis and condensation reaction of tetra-n-butyltitanate under hydrothermal condition, and therefore influenced the microstructure of final TiO₂core. The result of the degradation of methylene blue under UV light irradiation indicated that the photocatalytic property of the composite microspheres was closely related to the equilibrium adsorption capacity for methylene blue, and simultaneously depended on the microstructure of composite microspheres. The composite spheres showed fairly high photocatalytic efficiency for degrading methylene blue when the theoretical hydroxyapatite mass fraction was controlled at 1%-1.5%.

Key words: titanium dioxide, hydroxyapatite, hydrothermal, hydrolysis, adsorption, degradation

中图分类号:

O643.36

那驰, 董如林, 张汉平, 陈智栋, 金长春, 王芳. TiO₂/羟基磷灰石复合微球的合成[J]. 化工进展, 2016, 35(05): 1484-1489.

NA Chi, DONG Rulin, ZHANG Hanping, CHEN Zhidong, JIN Changchun, WANG Fang. Synthesis of TiO₂/hydroxyapatite composite microspheres[J]. Chemical Industry and Engineering Progree, 2016, 35(05): 1484-1489.

参考文献

[1] SHANG S Q, JIAO X L, CHEN D R.Template-free fabrication of TiO₂ hollow spheres and their photocatalytic properties[J].ACS Applied Materials and Interface, 2012, 4: 860-865.
[2] YU J G, ZHANG J.A simple template-free approach to TiO₂ hollow spheres with enhanced photocatalytic activity[J]. Dalton Transactions, 2010, 39: 5860-5867.
[3] YU J G, LI Q L, SHU Z.Dye-sensitized solar cells based on double-layered TiO₂ composite films and enhanced photovoltaic performance[J].Electrochimica Acta, 2011, 56: 6293-6298.
[4] JIANG J, GU F, SHAO W, et al.Fabrication of spherical multi-hollow TiO₂ nanostructures for photoanode film with enhanced light-scattering performance[J].Industrial and Engineering Chemistry Research, 2012, 51: 2838-2845.
[5] TAYLOR J C, DRISCOLL C F, CUNNINGHAM M D, et al.Failure of a hydroxyapatite-coated endosteal dental implant: a clinical report[J].The Journal of Prosthetic Dentistry, 1996, 75: 353-355.
[6] 李波, 徐文峰, 廖晓玲.磷酸钙微球骨修复材料研究进展[J].无机材料学报, 2014, 29: 1009-1017.
[7] 李俊杰, 姚晖, 陈亦平, 等. 微纳米羟基磷灰石及其复合材料研究进展[J].化工进展, 2006, 25(6): 651-657
[8] TAKASHIMA S, HAYAKAWA S, OHTSUKI C, et al. Adsorption of proteins by calcium phosphate with varied Ca to P ratios[J].Bioceramics, 1996, 9: 217-220.
[9] TAKASHIMA S, KUSUDO Y, TOKEMOTO S, et al.Synthesis of carbonate-hydroxy apatite and selective adsorption activity against specific pathogenic substances[J].Bioceramics, 2002, 14: 175-178.
[10] TAKEMOTO S, KUSUDO Y, TSURU K, et al.Selective protein adsorption and blood compatibility of hydroxy-carbonate apatites[J].Journal of Biomedical Materials Research, 2004, 69: 544-551.
[11] JIN X D, GUO Y W, WANG J, et al.The preparation of TiO₂/hydroxylapatite (TiO₂/HA) composite and sonocatalytic damage to bovine serum albumin (BSA) under ultrasonic irradiation[J].Journal of Molecular Catalysis A: Chemical, 2011, 341: 89-96.
[12] HU X J, LIU J K, LU Y, et al.Facile synthesis and characterization of hydroxylapatite nanoparticle chains[J].Materials Letters, 2008, 62: 3824-3826.
[13] 杨辉, 王栋, 蔡日强.共沉淀法制备高纯度纳米羟基磷灰石的研究[J].精细化工, 2010, 27(1): 5-10.
[14] DONG R L, LIU S Y, LI Z Y, et al.TiO₂ microspheres with variable morphology, size and density synthesized by a facile emulsion-mediated hydrothermal process[J].Materials Letters, 2014, 123: 135-137.

[1]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[2]	崔守成, 徐洪波, 彭楠. 两种MOFs材料用于O₂/He吸附分离的模拟分析[J]. 化工进展, 2023, 42(S1): 382-390.
[3]	陈崇明, 陈秋, 宫云茜, 车凯, 郁金星, 孙楠楠. 分子筛基CO₂吸附剂研究进展[J]. 化工进展, 2023, 42(S1): 411-419.
[4]	许春树, 姚庆达, 梁永贤, 周华龙. 共价有机框架材料功能化策略及其对Hg(Ⅱ)和Cr(Ⅵ)的吸附性能研究进展[J]. 化工进展, 2023, 42(S1): 461-478.
[5]	顾永正, 张永生. HBr改性飞灰对Hg⁰的动态吸附及动力学模型[J]. 化工进展, 2023, 42(S1): 498-509.
[6]	郭强, 赵文凯, 肖永厚. 增强流体扰动强化变压吸附甲硫醚/氮气分离的数值模拟[J]. 化工进展, 2023, 42(S1): 64-72.
[7]	王晋刚, 张剑波, 唐雪娇, 刘金鹏, 鞠美庭. 机动车尾气脱硝催化剂Cu-SSZ-13的改性研究进展[J]. 化工进展, 2023, 42(9): 4636-4648.
[8]	葛全倩, 徐迈, 梁铣, 王凤武. MOFs材料在光电催化领域应用的研究进展[J]. 化工进展, 2023, 42(9): 4692-4705.
[9]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[10]	李由, 吴越, 钟禹, 林琦璇, 任俊莉. 酸性熔盐水合物预处理麦秆高效制备木糖及其对酶解效率的影响[J]. 化工进展, 2023, 42(9): 4974-4983.
[11]	王雪婷, 顾霞, 徐先宝, 赵磊, 薛罡, 李响. 水热预处理对餐厨垃圾厌氧发酵产戊酸的影响[J]. 化工进展, 2023, 42(9): 4994-5002.
[12]	杨莹, 侯豪杰, 黄瑞, 崔煜, 王兵, 刘健, 鲍卫仁, 常丽萍, 王建成, 韩丽娜. 利用煤焦油中酚类物质Stöber法制备碳纳米球用于CO₂吸附[J]. 化工进展, 2023, 42(9): 5011-5018.
[13]	张振, 李丹, 陈辰, 吴菁岚, 应汉杰, 乔浩. 吸附树脂对唾液酸的分离纯化[J]. 化工进展, 2023, 42(8): 4153-4158.
[14]	杨静, 李博, 李文军, 刘晓娜, 汤刘元, 刘月, 钱天伟. 焦化污染场地中萘降解菌的分离及降解特性[J]. 化工进展, 2023, 42(8): 4351-4361.
[15]	姜晶, 陈霄宇, 张瑞妍, 盛光遥. 载锰生物炭制备及其在环境修复中应用研究进展[J]. 化工进展, 2023, 42(8): 4385-4397.

TiO₂/羟基磷灰石复合微球的合成

Synthesis of TiO₂/hydroxyapatite composite microspheres

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价