溶剂热法制备Fe3O4纳米粒子的研究进展

doi:10.16085/j.issn.1000-6613.2016-2205

摘要/Abstract

摘要： 四氧化三铁是一种重要的功能材料，因其具有优异的磁性能和较高的化学稳定性而被广泛应用于水体净化、磁流体和靶向药物等领域。四氧化三铁的合成方法主要有共沉淀法、热分解法、微乳液法及溶剂热法。其中，溶剂热法因流程简单、所得产物形貌多样、规整度高而得到广泛关注。该法所用的溶剂、矿化剂、表面活性剂等对Fe₃O₄纳米粒子的形貌及性能有较大影响。基于此，本文对溶剂热法制备Fe₃O₄纳米粒子进行了回顾，阐述了溶剂热法合成空心Fe₃O₄纳米粒子的机理。结果表明：在合成过程中，溶剂不仅作为还原剂，还提供合成所需的液相环境；矿化剂可促使铁前体的溶解，从而保证合成反应顺利进行；表面活性剂可与Fe₃O₄晶面作用，其种类和浓度不同，作用的晶面不同，进而诱导Fe₃O₄生长为不同形貌的纳米粒子。最后，本文对溶剂热法合成Fe₃O₄纳米粒子今后的发展趋势进行了展望，指出在空心Fe₃O₄纳米粒子的基础上，通过选择黏度较大的溶剂和表面活性剂合成多层壳状Fe₃O₄纳米粒子是研究者努力的方向。

关键词: 溶剂热法, 四氧化三铁, 粒子, 晶面, 合成, 纳米材料

Abstract: Fe₃O₄ is an excellent functional material widely applied to water purification, magnetic fluid, targeted drugs, etc. due to excellent magnetic property and high chemical stability. The main synthetic methods include coprecipitation, thermal decomposition, micro-emulsion and solvothermal method. The solvothermal method, benefiting from diverse products varying in shapes and appearances, high regularity and simple procedures, gains the most popularity. The solvent, mineralizer and surfactant applied in this method have relatively great impact on the shape, appearance and performance of Fe₃O₄ nano particle. In such context, in the paper, the preparation procedures of Fe₃O₄ nano particle by use of the solvothermal method has been described, based on which the mechanism for synthesis of hollow Fe₃O₄ nano particle by the solvothermal method has also been expounded. In conclusion, the solvent serves as the reductive agent while providing necessary liquid-phase environment for the synthesis; the mineralizer facilitates the dissolution of iron precursor thus ensuring the smooth proceeding of the synthetic reaction; the shapes and appearances of Fe₃O₄ nano particle vary with the types, concentrations of the surfactants, and acting Fe₃O₄ crystal faces. In the end, the author has looked to the development trend of the synthesis of Fe₃O₄ nano particle by use of the solvothermal method. On the basis of hollow Fe₃O₄, the researcher's focus is on how to synthesize multilayered crustiform Fe₃O₄ nano particle by use of high-viscosity solvent and surfactant.

Key words: solvothermal method, Fe₃O₄, particle, crystal face, synthesis, nanomaterial

中图分类号:

O611.4

吕龙飞, 廖俊杰, 刘洋, 李利红, 郭晓琴, 赵妮, 常丽萍. 溶剂热法制备Fe₃O₄纳米粒子的研究进展[J]. 化工进展, 2017, 36(S1): 326-331.

LÜ Longfei, LIAO Junjie, LIU Yang, LI Lihong, GUO Xiaoqin, ZHAO Ni, CHANG Liping. Advance in preparation of Fe₃O₄ nanoparticles by solvothermal method[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 326-331.

参考文献

[1] 郭飞鸽,张秋禹,张和鹏,等. Fe₃O₄/P(AA-MMA-GMA)磁性复合微球的制备及其偶联抗体的性能[J]. 化工进展,2010,29(9):1693-1699.
[2] ZHOU S,YIN T,ZOU Q,et al. Labeling adipose derived stem cell sheet by ultrasmall super-paramagnetic Fe₃O₄ nanoparticles and magnetic resonance tracking in vivo[J]. Scientific Reports,2017,7:42793.
[3] FREY N A,PENG S,CHENG K,et al. Magnetic nanoparticles:synthesis,functionalization,and applications in bioimaging and magnetic energy storage[J]. Chemical Society Reviews,2009,38(9):2532-2542.
[4] 程昌敬,左芳,吴莉莉.羧甲基化壳聚糖修饰磁性Fe₃O₄纳米粒子去除Cu(Ⅱ)离子[J]. 化工进展,2011,30(11):2549-2553.
[5] KUMAR R,SINGH R K,VAZ A R,et al. Self-assembled and one-step synthesis of interconnected 3D network of Fe₃O₄/reduced graphene oxide nanosheets hybrid for high-performance supercapacitor electrode[J]. ACS Applied Materials & Interfaces,2017. In Press.
[6] AZARI A,GHARIBI H,KAKAVANDI B,et al. Magnetic adsorption separation process:an alternative method of mercury extracting from aqueous solution using modified chitosan coated Fe₃O₄ nanocomposites[J]. Journal of Chemical Technology & Biotechnology,2017,92(1):188-200.
[7] TIAN H,LIU H,YANG T,et al. Fabrication of core-shell,yolk-shell and hollow Fe₃O₄@carbon microboxes for high-performance lithium-ion batteries[J]. Materials Chemistry Frontiers,2017, In Press. DOI:10.1039/C7QM00059F
[8] HUANG W,XIAO X,ENGELBREKT C,et al. Graphene encapsulated Fe₃O₄ nanorods assembled into a mesoporous hybrid composite used as a high-performance lithium-ion battery anode material[J].Materials Chemistry Frontiers,2017(6):1185-1193.
[9] 郭雷,胡小芳.弱外磁场诱导氧化沉淀法制备Fe₃O₄纳米粒子[J]. 化工进展,2009,28(8):1410-1414.
[10] 朱春山,宋佳,邱莉,等.油酸低温水洗改性磁性四氧化三铁纳米粒子[J]. 化工进展,2011,30(7):1552-1555.
[11] 江元汝,张忠奎,黄永萱,李兆. 硫铁矿烧渣水热-热解法制备纳米Fe₃O₄[J]. 化工进展,2013,32(5):1097-1101.
[12] ZHOU Z H,WANG J,LIU X,et al. Synthesis of Fe₃O₄ nanoparticles from emulsions[J]. Journal of Materials Chemistry,2001,11(6):1704-1709.
[13] XIONG Y,YE J,GU X Y,et al. Synthesis and assembly of magnetite nanocubes into flux-closure rings[J]. The Journal of Physical Chemistry C,2007,111(19):6998-7003.
[14] ZHANG Q,ZHENG Z,LIU C X,et al. Biodiesel production using lipase immobilized on epoxychloropropane-modified Fe₃O₄sub-microspheres[J]. Colloids and Surfaces B:Biointerfaces,2016,140:446-451.
[15] LIU J,SUN Z K,DENG Y H,et al. Highly water-dispersible biocompatible magnetite particles with low cytotoxicity stabilized by citrate groups[J]. Angewandte Chemie International Edition,2009,48(32):5875-5879.
[16] NGUYEN D T,IM K S. Analysis on development of magnetite hollow spheres through one-pot solvothermal process[J]. AIChE Journal,2013,59(10):3594-3600.
[17] DENG H,LI X L,PENG Q,et al. Monodisperse magnetic single-crystal ferrite microspheres[J]. Angewandte Chemie,2005,117(18):2842-2845.
[18] WANG D,YANG P,MA Q,et al. Micro-and nano-structures of iron oxide with tunable morphologies fabricated via solvothermal process[J]. CrystEngComm,2013,15(44):8959-8965.
[19] BYRAPPA K,ADSCHIRI T. Hydrothermal technology for nanotechnology[J]. Progress in Crystal Growth and Characterization of Materials,2007,53(2):117-166.
[20] HE T,CHEN D,JIAO X. Controlled synthesis of Co₃O₄ nanoparticles through oriented aggregation[J]. Chemistry of Materials,2004,16(4):737-743.
[21] SUN H Y,CHEN B,JIAO X L,et al. Solvothermal synthesis of tunable electroactive magnetite nanorods by controlling the side reaction[J]. The Journal of Physical Chemistry C,2012,116(9):5476-5481.
[22] BI H Y,WANG X Q,LI H B,et al. Synthesis of hollow microsphere chains and their magnetic properties[J]. Solid State Communications,2009,149(45-46):2115-2119.
[23] LIU X,LI Y F,ZHU W W,et al. Building on size-controllable hollow nanospheres with superparamagnetism derived from solid Fe₃O₄ nanospheres:preparation,characterization and application for lipase immobilization[J]. CrystEngComm,2013,15(24):4937-4947.
[24] LI Y F,JIANG R L,LIU T Y,et al. One-pot synthesis of grass-like Fe₃O₄ nanostructures by a novel microemulsion-assisted solvothermal method[J]. Ceramics International,2014,40(1):1059-1063.
[25] LUO Y,YANG J,YAN Y,et al. RGD-functionalized ultrasmall iron oxide nanoparticles for targeted T1-weighted MR imaging of gliomas[J]. Nanoscale,2015,7(34):14538-14546.
[26] YUAN K F,NI Y H,ZHANG L. Facile hydrothermal synthesis of polyhedral Fe₃O₄ nanocrystals, influencing factors and application in the electrochemical detection of H₂O₂[J]. Journal of Alloys and Compounds,2012,532:10-15.
[27] LIU Y B,WANG Y Q,ZHOU S M,et al. Synthesis of high saturation magnetization superparamagnetic Fe₃O₄ hollow microspheres for swift chromium removal[J]. ACS Applied Materials & Interfaces,2012,4(9):4913-4920.
[28] KIM S,KATSUMATA K-I,OKADA K,et al. Highly dispersed iron oxide nanoparticles synthesized by solvothermal method adding electrostatic stabilizers[J]. IEEE Transaction on Magnetics,2015,51(7):1-4.
[29] LIU R Z,ZHAO Y Z,HUANG R X,et al. Shape evolution and tunable properties of monodisperse magnetite crystals synthesized by a facile surfactant-free hydrothermal method[J]. European Journal of Inorganic Chemistry,2010,2010(28):4499-4505.
[30] LIANG X,WANG X,ZHUANG J,et al. Synthesis of nearly monodisperse iron oxide and oxyhydroxide nanocrystals[J]. Advanced Functional Materials,2006,16(14):1805-1813.
[31] GENG B Y,MA J Z,YOU J H. Controllable synthesis of single-crystalline Fe₃O₄polyhedra possessing the active basal facets[J]. Crystal Growth & Design,2008,8(5):1443-1447.
[32] ZHANG X T,WAN J Q,CHEN K Z,et al. Controlled synthesis of spherical and cubic magnetite nanocrystal clusters[J]. Journal of Crystal Growth,2013,372:170-174.
[33] ZHANG X L,NIU C Y,WANG Y Q,et al. Gel-limited synthesis of dumbbell-like Fe₃O₄-Ag composite microspheres and their SERS applications[J]. Nanoscale,2014,6(21):12618-12625.
[34] LIANG J,MA H R,LUO W,et al. Synthesis of magnetite submicrospheres with tunable size and superparamagnetism by a facile polyol process[J]. Materials Chemistry and Physics,2013,139(2/3):383-388.
[35] ZHANG Y,DING M,MA L,et al. Effects of Ag on morphology and catalytic performance of iron catalysts for Fischer-Tropsch synthesis[J]. RSC Advances,2015,5(72):58727-58733.
[36] DENG Y F,ZHANG Q M,SHI Z C,et al. Synergies of the crystallinity and conductive agents on the electrochemical properties of the hollow Fe₃O₄spheres[J]. Electrochimica Acta,2012,76:495-503.
[37] NI H,SUN X W,LI Y D,et al. Solvothermal self-assembly of magnetic Fe₃O₄ nanochains by ethylenediamine functionalized nanoparticles for chromium(VI) removal[J]. Journal of Materials Science,2015,50(12):4270-4279.
[38] LAURENT S,FORGE D,PORT M,et al. Magnetic iron oxide nanoparticles:synthesis,stabilization,vectorization,physicochemical characterizations,and biological applications[J]. Chemical Reviews,2008,108(6):2064-2110.
[39] CHENG C M,WEN Y H,XU X F,et al. Tunable synthesis of carboxyl-functionalized magnetite nanocrystal clusters with uniform size[J]. Journal of Materials Chemistry,2009,19(46):8782-8788.
[40] LIANG J,LI L,LUO M,et al. Synthesis and properties of magnetite Fe₃O₄ via a simple hydrothermal route[J]. Solid State Sciences,2010,12(8):1422-1425.
[41] CHEN Z M,GENG Z R,TAO T X,et al. Shape-controlled synthesis of Fe₃O₄ rhombic dodecahedrons and nanodiscs[J]. Materials Letters,2014,117:10-13.
[42] OOI F,DUCHENE J S,QIU J,et al. A facile solvothermal synthesis of octahedral Fe₃O₄ nanoparticles[J]. Small,2015,11(22):2649-2653.
[43] LI Z W,YANG Z H. Microwave absorption properties and mechanism for hollow nanosphere composites[J]. Journal of Magnetism and Magnetic Materials,2015,387:131-138.
[44] LI X X,ZHENG X Y,SHAO J,et al. Synergistic ternary composite (carbon/Fe₃O₄@graphene) with hollow microspherical and robust structure for Li-ion storage[J]. Chemistry-A European Journal,2016,22(1):376-381.
[45] MOU Y,YANG H,XU Z. Morphology,surface layer evolution,and structure-dye adsorption relationship of porous Fe₃O₄ mnps prepared by solvothermal/gas generation process[J]. ACS Sustainable Chemistry & Engineering,2017,5(3):2339-2349.
[46] YAN S J,TANG J K,LIU P,et al. The influence of hollow structure on the magnetic characteristics for Fe₃O₄ submicron spheres[J]. Journal of Applied Physics,2011,109(7):07B5351-07B5353.
[47] LIN X H,JI G B,LIU Y B,et al. Formation mechanism and magnetic properties of hollow Fe₃O₄ nanospheres synthesized without any surfactant[J]. CrystEngComm,2012,14(24):8658-8663.
[48] WANG T,ZHANG L Y,WANG H Y,et al. Controllable synthesis of hierarchical porous Fe₃O₄ particles mediated by poly(diallyldimethylammonium chloride) and their application in arsenic removal[J]. ACS Applied Materials & Interfaces,2013,5(23):12449-12459.

溶剂热法制备Fe₃O₄纳米粒子的研究进展

Advance in preparation of Fe₃O₄ nanoparticles by solvothermal method

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