水合物浆液流动与流变特性研究进展

doi:10.16085/j.issn.1000-6613.2015.07.002

化工进展 ›› 2015, Vol. 34 ›› Issue (07): 1817-1825.DOI: 10.16085/j.issn.1000-6613.2015.07.002

水合物浆液流动与流变特性研究进展

闫柯乐^1,2, 邹兵^1,2, 姜素霞^1,2, 张红星^1,2, 尚祖政^1,2, 王倩³

1 中国石化青岛安全工程研究院, 山东青岛 266071;
2 化学品安全控制国家重点实验室, 山东青岛 266071;
3 河南佰利联化学股份有限公司, 河南焦作 454150

收稿日期:2014-11-07 修回日期:2015-01-23 出版日期:2015-07-05 发布日期:2015-07-05
通讯作者: 闫柯乐(1986—),男,博士,主要从事多相流动安全保障、水合物抑制技术及油气回收技术等方面研究。E-mail:yankele214@163.com。
作者简介:闫柯乐(1986—),男,博士,主要从事多相流动安全保障、水合物抑制技术及油气回收技术等方面研究。E-mail:yankele214@163.com。

Review on flow characteristics and rheological properties of hydrate slurry

YAN Kele^1,2, ZOU Bing^1,2, JIANG Suxia^1,2, ZHANG Hongxing^1,2, SHANG Zuzheng^1,2, WANG Qian³

1 Research Institute of Safety Engineering, SINOPEC, Qingdao 266071, Shandong, China;
2 State Key Laboratory of Safety and Control for Chemicals, Qingdao 266071, Shandong, China;
3 Henan Billions Chemicals Co., Ltd., Jiaozuo 454150, Henan, China

Received:2014-11-07 Revised:2015-01-23 Online:2015-07-05 Published:2015-07-05

摘要/Abstract

摘要： 水合物浆液技术作为一门新型水合物防治途径和油-气-水多相安全混输的方式逐渐受到油气生产和运输部门的重视。系统综述了国内外水合物浆液流动特征和流变特性的最新研究进展, 主要从研究装置、宏观形态演化、流率/压阻等其他流动参数变化规律及水合物浆液流变性方面进行了详细讨论。介绍了高压流变仪、高压黏度计及水合物流动循环管路等实验装置, 着重分析了水合物循环管路的优缺点;阐述了水相中水合物浆液和油水体系内天然气水合物浆液宏观形态演化的异同;系统研究了水合物形成过程中体系流量/压阻等其他流动参数变化规律;归纳总结了水合物浆液流变性实验和理论模型的研究成果。

关键词: 水合物浆液, 流动特征, 流变性, 形态演化

Abstract: Hydrate slurry technology, as a new way for inhibiting hydrate plug and oil-gas-water multiphase flow assurance, has drawn much attention for oil/gas production and transportation department. Therefore, this paper systematically overviews the progress on flow characteristics and rheological properties of hydrate slurry in which common experimental apparatus, morphological evolvement of hydrate slurry, the variation of flow parameters, and hydrate slurry rheology are analyzed. A couple of experiment setups are introduced, including high-pressure rheometer, high-pressure viscometer and hydrate flow loop, in which the pros and cons of hydrate loop is specially introduced. Through observation, the difference of morphological evolvement between hydrate slurry in aqueous phase and natural gas hydrate slurry in oil/gas system is presented. The variation of flow parameters during the formation of hydrate slurry, such as flow rate and pressure drop, is systematically studied. In addition, the experimental and theoretical researches on hydrate slurry rheology are also investigated in this paper. Finally, this paper proposes the existing problems, the research direction and technical route of hydrate slurry.

Key words: hydrate slurry, flow characteristics, rheological properties, morphological evolvement

中图分类号:

TE88

闫柯乐, 邹兵, 姜素霞, 张红星, 尚祖政, 王倩. 水合物浆液流动与流变特性研究进展[J]. 化工进展, 2015, 34(07): 1817-1825.

YAN Kele, ZOU Bing, JIANG Suxia, ZHANG Hongxing, SHANG Zuzheng, WANG Qian. Review on flow characteristics and rheological properties of hydrate slurry[J]. Chemical Industry and Engineering Progree, 2015, 34(07): 1817-1825.

参考文献

[1] Sloan E D, Koh C A. Clathrate Hydrates of Natural Gases[M]. Third Edition. New York:CRC Press, 2008.
[2] Wang W X, Christopher L B, Dave J A, et al. Methane storage in dry water gas hydrate[J]. J. Am. Chem. Soc., 2008, 130(35):11608-11609.
[3] Pang W X, Chen G J, Dandekar A, et al. Experimental study on the scale-up effect of gas storage in the form of hydrate in a quiescent reactor[J]. Chem. Eng. Sci., 2007, 62(8):2198-2208.
[4] Hao W F, Wang J Q, Fan S S, et al. Evaluation and analysis method for natural gas hydrate storage and transportation processes[J]. Energ. Convers. Manage., 2008, 49(10):2546-2553.
[5] 马昌峰. 水合物技术应用于气体混合物分离的研究[D]. 北京:中国石油大学, 2001.
[6] 孙长宇. 水合法分离气体混合物相关基础研究[D]. 北京:中国石油大学, 2001.
[7] 张世喜. 水合物生成动力学及水合法分离气体混合物的研究[D]. 北京:中国石油大学, 2003.
[8] 张凌伟. 水合法分离裂解气的实验及模拟研究[D]. 北京:中国石油大学, 2005.
[9] 王林军, 邵磊, 张学民, 等. 气体水合物应用技术研究进展[J]. 甘肃科学学报, 2012, 24(1):49-54.
[10] 熊颖, 王宁升, 丁咚, 等. 天然气水合物的应用技术[J]. 天然气与石油, 2008, 26(4):12-15.
[11] Kelland M A. History of the development of low dosage hydrate inhibitors[J]. Engery Fules, 2006, 20(3):825-847.
[12] 穆亮, 李文志, 陈光进, 等. 一种复配型水合物防聚剂[J]. 化工进展, 2012, 31(s1):354-357.
[13] Webb E B, Koh C A, Liberatore M W. Rheological properties of methane hydrate slurries formed from AOT + water + oil microemulsions[J]. Langmuir, 2013, 29(35):10997-11004.
[14] Webb E B, Rensing P J, Koh C A, et al. High-pressure rheology of hydrate slurries formed from water-in-oil emulsions[J]. Energy Fuels, 2012, 26(6):3504-3509.
[15] 赵建奎, 宫敬, 陈光进. 天然气水合物浆液黏度的实验研究[J]. 天然气工业, 2007, 27(9):96-98, 139.
[16] Moradpour H, Chapoy A, Tohidi B. Bimodal model of predicting the emulsion-hydrate mixture viscosity in high water cut susytems[J]. Fuel, 2011, 90(11):3343-3351.
[17] Aalvik J. An investigation from hydrate formation in flowing fluids[D]. Trondheim, Norway:University of Trondheim, The Norwegian Institute of Technology, Division of Refrigeration Engineering, 1987.
[18] Reed R L, Kelley L R, Neumann D L, et al. Some preliminary results from a pilot-size hydrate flow loop[J]. Ann. N. Y Acad. Sci., 1994, 715(1):430-446.
[19] Delahaye A, Fournaison L, Jerbi S, et al. Rheological properties of CO₂ hydrate slurry flow in the presence of additives[J]. Ind. Eng. Chem. Res., 2011, 50(13):8344-8353.
[20] Delahaye A, Fournaison L, Marinhas S, et al. Rheological study of CO₂ hydrate slurry in a dynamic loop applied to secondary refrigeration[J]. Chem. Eng. Sci., 2008, 63(13):3551-3559.
[21] Clain P, Delahaye A, Fournaison L, et al. Rheological properties of tetra-n-butylphosphonium bromide hydrate slurry flow[J]. Chem. Eng. J., 2012, 193-194:112-122.
[22] Fidel-Dufour A, Gruy F, Herri J M. Rheology of methane hydrate slurries during their crystallization in a water in dodecane emulsion under flowing[J]. Chem. Eng. Sci., 2006, 61(2):505-515.
[23] Kumano H, Hirata T, Kudoh T. Experimental study on the flow and heat transfer characteristics of a tetra-n-butyl ammonium bromide hydrate slurry (first report:Flow characteristics)[J] . Int. J. Refrig., 2011, 34(8):1953-1962.
[24] Suzuki H, Itotagawa T, Indartono Y S, et al. Rheological characteristics of trimethylolethane hydrate slurry treated with drag-reducing surfactants[J]. Rheologica Acta, 2006, 46(2):287-295.
[25] Suzuki H, Kakanori K, Komoda Y, et al. Flow and heat transfer characteristics of ammonium alum hydrate slurries[J]. Int. J. Refrig., 2013, 36(1):81-87.
[26] Kumano H, Hirata T, Kudoh T, et al. Experimental study on the flow and heat transfer characteristics of a tetra-n-butyl ammonium bromide hydrate slurry (second report:heat transfer characteristics)[J]. Int. J. Refrig., 2011, 34(8):1963-1971.
[27] 李文志, 陈光进, 孙长宇, 等. 含阻聚剂水合物浆液在循环管路中的性能[J]. 石油化工, 2012(3):313-318.
[28] 黄强, 杨琨超, 孙长宇, 等. 水合物浆液流动特性研究[J]. 油气储运, 2007(4):16-20.
[29] Peng B Z, Chen J, Sun C Y, et al. Flow characteristics and morphology of hydrate slurry formed from (natural gas + diesel oil/condensate oil + water) system containing anti-agglomerant[J]. Chem. Eng. Sci., 2012, 84:333-344.
[30] Yan K L, Sun C Y, Chen J, et al. Flow characteristics and rheological properties of natural gas hydrate slurry in the presence of anti-agglomerant in a flow loop apparatus[J]. Chem. Eng. Sci., 2014, 106:99-108.
[31] Wang F X, Sun C Y, Chen G J, et al. Study on flow characteristics of (diesel oil + methane +tetrahydrofuran + water) hydrate slurry system[C]//Proceedings of the 6th International Conference on Gas Hydrates, Ancouver, British Columbia, Canada, 2008.
[32] Yan K L, Sun C Y, Song Z Y, et al. Flow characteristics and morphological evolvement of gas hydrate slurry in the presence of different hydrate inhibitors[C]//Proceedings of the 8th International Conference on Gas Hydrates, Beijing, China, 2014.
[33] Wang W C, Fan S S, Liang D Q, et al. Experimental study on flow characteristics of tetrahydrofuran hydrate slurry in pipelines[J]. J. Nat. Gas Chem., 2010, 19(3):318-322.
[34] Wang W C, Fan S S, Liang D Q, et al. Experimental study on flow characters of CH₃CCl₂F hydrate slurry[J]. Int. J. Refrig., 2008, 31(3):371-378.
[35] Austvik T. Hydrate formation and behaviour in pipes, in division of thermodynamics[D]. Trondheim, Norway:University of Trondheim, The Norwegian Institute of Technology, 1992.
[36] Lund A. Comments to some preliminary results from the Exxon hydrate flow loop[J]. Ann. N.Y Acad. Sci., 1994, 715(1):447-449
[37] Chen J, Yan K L, Chen G J, et al. Insights into the formation mechanism of hydrate plugging in pipelines[J]. Chem. Eng. Sci., 2015. 122:284-290.
[38] 巫术胜, 肖睿, 黄冲, 等. 四丁基溴化铵水合物浆在水平直圆管内的流动压降研究[C]//第四届全国制冷空调新技术研讨会, 南京, 2006.
[39] 王武昌, 李玉星, 樊拴狮, 等. 四氢呋喃水合物浆流动特性[J].化工进展, 2010, 29(8):1418-1422.
[40] Sinquin A, Palermo T, Peysson Y. Rheological and flow properties of gas hydrate suspensions[J]. Oil & Gas Science and Technology:Rev. IFP, 2004, 59(1):41-57.
[41] Joshi S V, Grasso G A, Lafond P G, et al. Experimental flowloop investigations of gas hydrate formation in high water cut systems[J]. Chem. Eng. Sci., 2013, 97:198-209.
[42] 姚海元, 李清平, 陈光进, 等. 加入阻聚剂后水合物浆液流动压降规律研究[J]. 化学工程, 2009, 37(12):20-23.
[43] Darbouret M, Cournil M, Herri J M. Rheological study of TBAB hydrate slurries as secondary two-phase refrigerants[J]. Int. J. Refrig., 2005, 28(5):663-671.
[44] Xiao R, Wu S S, Tang L G, et al. Experimental investigation of pressure-drop of clathrate hydrate slurry (CHS) flow of tetra butyl ammonium bromide (TBAB) in straight pipe[C]//Proceedings of 10th International Conference on Thermal Energy Storage, USA, New Jersey, 2006.
[45] Ma Z W, Zhang P, Wang R Z, et al. Forced flow and convective melting heat transfer of clathrate hydrate slurry in tubes[J]. Int. J. Heat Mass Transfer, 2010, 53:3745-3757.

水合物浆液流动与流变特性研究进展

Review on flow characteristics and rheological properties of hydrate slurry

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 11

编辑推荐

Metrics

本文评价

[1]	罗源皓, 林凌, 郭拥军, 杨玉坤, 熊贵霞, 任仁, 屈沅治. 纳米材料在抗高温钻井液中的应用进展[J]. 化工进展, 2022, 41(9): 4895-4906.
[2]	陈哲坤, 潘伟童, 姚顶松, 丁路, 王辅臣. 质子交换膜燃料电池微孔层浆液微观结构与流变性[J]. 化工进展, 2022, 41(7): 3808-3815.
[3]	裴海华, 刘冬鑫, 张贵才, 单景玲, 蒋平. 塔河超稠油掺苯乙烯焦油降黏实验及黏度预测模型[J]. 化工进展, 2020, 39(S2): 135-141.
[4]	饶永超, 王树立, 代文杰, 郑亚星, 刘朝阳, 姜英豪. 天然气水合物浆体流变性与安全流动边界研究进展[J]. 化工进展, 2015, 34(10): 3551-3556.
[5]	郑保辉，罗观，舒远杰，王平胜. 熔铸炸药研究现状与发展趋势[J]. 化工进展, 2013, 32(06): 1341-1346.
[6]	苏磊静，丁雪佳，雷晓慧，何金迎，王林生，李熙然. 聚烯烃包覆石蜡相变材料的结构和初步热性能[J]. 化工进展, 2013, 32(04): 853-856.
[7]	晋刚，赵新亮，雷玉才. 转矩流变仪表征熔融聚合物的流变性能 [J]. 化工进展, 2011, 30(2): 371-.
[8]	张雨，丁雪佳，郭甜甜，周克斌，韩海军，张丽娟. PC/PETG共混物熔体的流变性能[J]. 化工进展, 2011, 30(12): 2685-.
[9]	王武昌1，李玉星1，樊栓狮2，梁德青3. 四氢呋喃水合物浆流动特性 [J]. 化工进展, 2010, 29(8): 1418-.
[10]	薛海蛟，丁雪佳，李洪波，吴恒澜，唐斌. 聚氨酯改性聚醚多元醇对硬质聚氨酯泡沫性能的影响 [J]. 化工进展, 2009, 28(10): 1777-.
[11]	张红霞，王德忠，顾卫国. 表面活性剂湍流减阻研究进展 [J]. 化工进展, 2009, 28(10): 1701-.