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Table of Content
25 April 2006, Volume 25 Issue 4
    进展与述评
    Challenges for Chinese energy chemical industry and approaches (Ⅱ)
    HU Xuteng,LI Zhenyu,WANG Zhengyuan
    2006, 25(4):  351. 
    Abstract ( 2028 )  
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    Based on the analysis of current situation,the development strategy of Chinese energy chemical industry is pointed out. The development should be in line with national strategy of oil security, national strategy of sustainable development and national strategy of independent innovation, and meet the demand of building a conservation-conscious society.
    Alkylation of thiophenic sulfur technology in the production of clean fuel
    KE Ming,ZHOU Aiguo,ZHAO Zhensheng,JIANG Qingzhe,SONG Zhaozheng
    2006, 25(4):  357. 
    Abstract ( 1666 )  
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    New regulations aiming at strict standard of the quality of motor gasoline, especially a drastic reduction of sulfur content have been adopted by many countries. The article focuses on the desulfurization of FCC gasoline by olefin alkylation of thiophenic sulfur technology. The processes and catalysts are discussed.
    Recycling and reuse of brominated flame-retardant plastics

    OU Yuxiang,ZHAO Yi,FANG Xiaomin

    2006, 25(4):  362. 
    Abstract ( 1430 )  
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    The recovery of brominated flame-retardant plastics is basically the recovery of the electric and electronic equipment made from this kind of plastics. Three methods for recycling and reuse of brominated flame-retarded plastics are summarized. Mechanical recycling;②Incineration with energy recovery;③Incineration of pyrolysis with recovery of bromine or hydrobromic acid. The discussions focus on the environmental issue in the recycling processes. From the ecological and economical points of view, both the mechanical and incineration methods are practical and safe. But the incineration process should be carried out properly and the production and release of dioxins must be strictly controlled and monitored.
    On-line detection techniques in supercritical CO2 fluid extraction
    LEI HuapingGE Fahuan
    2006, 25(4):  367. 
    Abstract ( 1504 )  
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    Supercritical fluid extraction is a new and “green”technique for extraction and separation with such advantages as high efficiency, high speed, and less pollution. This paper reviews the on-line detection techniques in supercritical fluid extraction, including supercritical fluid chromatography, gas chromatography, high-performance liquid chromatography, nuclear magnetic resonance, and near infrared spectrometry.
    Research and application of magnetic fluidized bed
    ZENG Ping,ZHOU Tao,CHEN Guanqun,GE Zhiqiang
    2006, 25(4):  371. 
    Abstract ( 1529 )  
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    The principle of a magnetic fluidized bed (MFB) and the new progress in the basic research and application of MFB are presented. Its application to environmental protectionbiochemical engineering and energy sources is reviewed. The commercialization and problems of MFB are analyzed.
    Advances on hydrophilic modification of polytetrafluoroethylene porous membrane
    SUN Haixiang,ZHANG Lin,CHEN Huanlin
    2006, 25(4):  378. 
    Abstract ( 1669 )  
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    The advances on the hydrophilic modification of polytetrafluoroethylene (PTFE) membranes are reviewed. The mechanisms, characteristics and the results of some modification methods, including plasma treatment, grafting copolymerization, chemical reduction, irradiation grafting and spattering coating are summarized. The applications of membranes in biochemical industry are also introduced.
    Preparation of nano-structured MnO2 and its applications in chemical power sources
    YANG Yujuan,HUANG Chengde
    2006, 25(4):  383. 
    Abstract ( 1556 )  
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    The current research of low dimensional nano-structured MnO2 is summarized, including the synthetic methods of nano-particles, nano-wires (nano-tubes or nano-rods) and nano-sheets.And its applications as electrode active material for super-capacitors, lithium-ion batteries and alkaline ZnMnO2 batteries are reviewed. In addition, its application prospects are introduced, too.
    Preparation and application of micro-encapsulated/ nano-encapsulated phase change materials
    ZHUANG Qiuhong,ZHANG Zhengguo,FANG Xiaoming
    2006, 25(4):  388. 
    Abstract ( 2326 )  
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    Micro-encapsulated / nano-encapsulated phase change materials are novel composite phase change materials, which are prepared by micro-encapsulation and nano-encapsulation technology. In this paper, the methods and the recent progress of preparing micro-encapsulated /nano-encapsulated phase change materials are reviewed, and their advantages and disadvantages are analyzed. Additionally, the application fields and prospects of the micro-encapsulated / nano-encapsulated phase change materials are introduced.
    Recent research on preparation of two-dimensional zinc sulfides
    SHEN Zonghua,WANG Anjie,XIE Jianguo,LI Xiang,REN Jing,LU Mohong
    2006, 25(4):  392. 
    Abstract ( 1561 )  
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    Zinc sulfide, an important wide band-gap semiconductor, has attracted much attention owing to its wide applications. However, the recent review on the preparation of two-dimensional zinc sulfide is relatively rare. The preparation methods of two-dimensional zinc sulfide materials are presented in this paper. The prospect of the preparation of two dimensional zinc sulfides is also discussed.
    Current situation of off-site pre-sulfurizing technique for hydrotreatment catalysts
    ZHANG Xiwen,LING Fengxiang,SUN Wanfu,FANG Xiangchen,LI Ruifeng
    2006, 25(4):  397. 
    Abstract ( 1605 )  
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    The routes of off-site pre-sulfurizing technique for hydrotreatment catalysts, the characteristics of sulfurizing agent for preparing such catalysts, and some problems which should be dealt with for researching such technique are introduced.
    Advance in chemical synthesis and chiral resolution of l-menthol
    NIAN Baoyi,XU Gang,YANG Lirong
    2006, 25(4):  401. 
    Abstract ( 1629 )  
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    The chemical structure, properties and application of l–menthol are reviewed. The recent advances of its synthesis, chiral resolution, closed loop mechanism and its future development are presented. The synthesis pathway of l–menthol from isoprene is discussed.
    Surface coating technology of near-UV emitting phosphors
    YANG Qinghua,LI Liquan,WANG Haibo,ZHU Xianzhong
    2006, 25(4):  406. 
    Abstract ( 1621 )  
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    The reasons for the loss of efficiency of phosphor during lamp operation are introduced in this paper. The surface coating technology of near-UV emitting phosphors, especially silicates phosphors is reviewed, as well as its influence on physical performance and maintenance of phosphors.
    研究开发
    Preparation and modification by Ag of solid super-acid nano- SO42--TiO2 photo-catalyst
    LIU HongLIU PanGU KongliangLI JingSUN Xuan
    2006, 25(4):  411. 
    Abstract ( 1597 )  
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    Solid super-acid nano-SO -TiO2 powder photo-catalyst were prepared by the sol-gel method using Ti(OC4H9)4 as raw material and adding 49% sulfuric acid into the original liquid. Then the SO /Ag-TiO2 photo-catalyst was modified by AgNO3. The prepared samples were characterized with UV-vis, IR, XRD and BET measurements. The photo-catalytic reactivity of samples was evaluated by using methyl orange and phenol aqueous solution as simulated contaminants. The results showed that the photo-catalytic reactivity of SO -TiO2 was 10 times higher than that of unmodified TiO2 and the photo-catalytic reactivity of SO /Ag-TiO2 was even higher than that of P-25.
    Production and characterization of activated carbon from tobacco stems by potassium hydroxide activation
    ZHANG Libo,PENG Jinhui,TU Jianhua,ZHANG Shimin,FAN Xingxiang
    2006, 25(4):  415. 
    Abstract ( 2103 )  
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    A series of activated carbons were prepared from tobacco stems as raw materials and potassium hydroxide as activating agent by a one-step carbonization process. The effects of the preparation variables on the yield and adsorption properties of activated carbon were systematically studied via orthogonal experiments, and the optimum condition was obtained. The iodine value of the activated carbon prepared under the optimum condition was 1198.27mg/g and the methylene blue adsorption was 3 times of that the first grade product specified in the National Standard. Furthermore, the nitrogen isotherm of the sample was determined. The porous structures were investigated with the Horvath-Kawazoe equations and density function theory. The results of the pore structures analysis was consistent with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) study.
    Determination of the relative molecular weight of chitosan
    FANG Wenjian,SUI Siguang,ZHENG Lianying
    2006, 25(4):  420. 
    Abstract ( 1535 )  
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    The relative molecular weight of chitosan was determined by the relationships of three methods, HPLC, intrinsic viscosity, and dynamics viscosity. The intrinsic viscosity of chitosan solution was measured with one-point Ubbelohde viscometer, the relative molecular weight of chitosan was determined with HPLC, and the MHS equation was obtained as [η] = 3.72 × 10-5Mw 1.37. This paper also sets up the relationship between dynamics viscosity and the molecular weight of chitosan during 10 mg/mL solution degradation by chitosanase.

    Study on the content of free phenol in the production of Novolac

    JING Chenli,CHEN Lixin,WANG Yunfang,SONG Jiale,CHEN Weiwei
    2006, 25(4):  424. 
    Abstract ( 1496 )  
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    Novolac was synthesized by using a new catalyst. The effects of the concentration of catalyst, sort of solvents, time of reaction etc. on the content of free phenol generated during the production of Novolac were discussed in the paper. The concentration of free phenol in the waste water was measured by the 4-amino antipyrine method. The results showed that the concentration of free phenol was below 100 mg/kg. An optimized technique was recommended.
    Adsorption-flocculation treatment of bagasse black liquid
    LIU Xingsheng,HUANG Guolin,ZHANG Hongyan,DONG Lijun,LIU Yunzhi
    2006, 25(4):  428. 
    Abstract ( 1550 )  
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    This paper discusses the treatment of bagasse black liquor in alkalescent condition. The suitable adsorption and flocculation conditions were as follows: bentonite 120 g/L, dicyandiamide–formaldehyde 6 mL/L, reaction temperature 40 ℃,fast stirring time 2 min and clarification time 25 hours. It was found that N, K and lots of lignin were present in the adsorption and flocculation mud, which could be used as the raw material to prepare organic solid fertilizer. The clarified black liquor could be recycled as the process water.
    应用技术
    Life cycle assessment of ethylene production(Ⅱ)
    YUAN Baorong,NIE Zuoren,DI Xianghua,ZUO Tieyong
    2006, 25(4):  432. 
    Abstract ( 1591 )  
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    Based on the life cycle inventory of ethylene production, the life cycle impact assessment was performed, and the overall impact indicator was 1.12×10-10 a-1. According to the life cycle interpretation, the impact of the depletion of non-renewable resources was more than 58% in the overall impact. The life cycle impact assessment of individual pollutants showed that the direct emissions of ethylene and NOx were the main sources of environmental burden, and their shares were both about 1/4.
    Study on contamination–free and transparent two–component
    PU adhesive
    DU Ying,GONG Jianxian,GAO Guosheng
    2006, 25(4):  436. 
    Abstract ( 1450 )  
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    A two-component, solvent-free, transparent, epoxy resin modified polyurethane adhesive is introduced in this paper. The mechanims of PU/EP synthesis was tracked by IR spectroscopy. The chemical reactions among groups and the change of products with time were analyzed. The result showed that several properties of modified products were greatly improved. Under the suitable raw material ratio and experiment condition, the viscosity, flow ability, stability, storage life, were satisfactory. When PU/EP curing agent was 5∶3, the skin drying time was 45min, the shearing intensity was more than 19MPa, the product was tough, solvent resistant and temperature resistant. During curing process no bubble was created, which was good for usein bonding and sealing.
    Separation of L-leucine from pig blood hydrolysate using precipitation
    method by reacting with 3,4-dimethyl-benzenesulfonic acid
    WENG Lianjin,YANG Xin,GAN Linhuo,HAN Yuanyuan,WANG Shibin
    2006, 25(4):  439. 
    Abstract ( 1845 )  
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    The effects of pH, temperature, mol ratio of 3,4-dimethyl-benzenesulfonic acid to L-leucine and NH4Cl concentration on the L-leucine precipitation yield by reacting with 3,4-dimethyl-benzenesulfonic acid were investigated. The pH value must be kept lower than 1.5, the optimal mol ratio of 3,4–dimethyl-benzenesulfonic acid to L-leucine was 3∶1. A low temperature was favorable for precipitation, preferably 0C.The yield decreased with the increase of NH4Cl concentration. L-leucine was separated from pig blood hydrolysate after removal of acid, and the precipitation rate was 90.62%. The L-leucine after refinement was in agreement with the standard of Pharmacopoeia of the People’s Republic of China (2000 edition, the second section)。
    Treatment of soybean whey with dual-step ultrafiltration system

    LÜ Sihao,CHEN Fuming,WANG Xiaolin,WANG Xiaoyu

    2006, 25(4):  444. 
    Abstract ( 1499 )  
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    An experiment was conducted to investigate the treatment of soybean whey with a dual-step ultrafiltration system which consisted of an air blasting enhanced vibratory ultrafiltration (MWCO50kDa) and a cross-flow ultrafiltration (MWCO10kDa). The results revealed that the operation duration of each cycle in the treatment of soybean whey with the dual-step ultrafiltration system reached more than 23h. The protein concentration of soybean whey was reduced from 0.5% to 0.04%; and both total sugar and salinity were retained at a lowered rate of about 10%. The membrane permeate flux of the fouled system was restored to more than 90% by chemical cleaning in 2h. The separation property of the membranes adopted in the system was not changed remarkably during long-term operation. The whey protein obtained in the experiment was a satisfactory product in that the protein concentration was higher than 70% and the salinity was around 10%.
    Application of Z-18 retarder activator in the RFCC unit of Sudan refinery
    LIU Xiangpu,CHENG Gang,ZHANG Zhouming,SHEN Zhe
    2006, 25(4):  448. 
    Abstract ( 1752 )  
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    This article summarizes the commercial application of the Z-18 catalyst molecular sieve retarder activator in the residuum fluid catalytic cracking unit (RFCC) of Khartoum Refinery Co. Ltd (KRC). The application result showed that this activator could maintain effectively catalyst activity by adjusting acid sites, consequently reducing coking on the surface of catalyst, and improving product distribution and product quality.
    Leakage analysis of dry gas seal in ammonia compressor and
    revamping with China-made parts
    LIU Dian,ZHAO Guohua,YANG Chunhui,ZHANG Jingtao,GONG Maojin
    2006, 25(4):  452. 
    Abstract ( 1929 )  
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    The reasons for worn dry gas seal on T slot, leakage and the short life of application were analyzed for the ammonia plant in Jilin Chemical Industry Company. Revamping with China-made parts was discussed. Applying dry gas seal on a spiral slot could reduce wear of surface, and postpone the life of application.
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