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Ultrasound-enhanced adsorptive removal of PFOS and PFOA by granular activated carbon
ZHAO Deming1,ZHANG Dexing1,HOFFMANN Michael R2
Chemical Industry and Engineering Progree   
A novel aldehyde-containing nanosphere prepared by self-emulsification
XIAO Naiyu1,LI Shanji2,GUO Qingbing3,ZHOU Hongjun3,LI Cuijin3
Chemical Industry and Engineering Progree   
Abstract7294)            Save
A new aldehyde-functionalized glycomonomer,1,2:3,4-Di-O-isopropylidene-6-O-(2’- formyl-4’-vinyl phenyl)-D-galactopyranose(IVDG),was designed and prepared by the reaction of 1,2:3,4-di-O-isopropylidene-6-O-(p-toluenesulfonyl)-D-galactopyranose(ITDG)with 2-hydroxy-5- vinylbenzaldehyde,and its structure was confirmed via elemental analysis,MS,and NMR spectroscopy. The radical polymerization of IVDG was successfully achieved using AIBN as initiator at 60 ℃ in THF. Removal of the protective isopropylidene group from the sugar residue in polyIVDG was carried out quantitatively using 88% formic acid at room temperature,yielding a novel polymer containing both galactopyranose and aldehyde functionalities. These amphiphilic polymers self-assembled into well-defined aldehydes-bearing polymeric micelles in aqueous solution without recourse to any surfactant. The hydrodynamic radius(Rh)of the micelles was 450nm by DLS in CONTIN algorithm. The micelles could be observed directly under TEM. The prepared nanospheres can potentially be applied in medicine and biotechnology.
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Rheological properties of konjac oligo-glucomannan with various molecular weights
YAO Xue,LUO Xuegang,HAN Benchao,HE Pan
Chemical Industry and Engineering Progree   
Abstract7234)            Save

Rheological property of konjac oligo-glucomannanKOGMwith various molecular weights in the presence of alkalisodium carbonatewas studied by dynamic viscoelastic measurements. Molecular weight and other molecular parameters of KOGM were determined by SEC-MALS. The results show that radius of gyrationRgdecreases and the relative stiffness parameterβincreases from 0.38 to 0.80 with the decrease of molecular weightMw),which means KOGM chains become short and stiff. The storage shear modulus G' and the loss shear modulus G'' increase and loss factor tand decrease with the increasing of KOGM MwKOGM concentration and alkali concentrationwhich indicates that the gels get more elastic and stable.

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Study on the purification and composition analysis of microbial flocculant MBFA1
LI Shufang1,2,YIN Hua1,2,QIN Huaming1,2,PENG Hui1,2,ZHANG Na1,2,YE Jinshao1,2,HE Baoyan1,2
Chemical Industry and Engineering Progree    2012, 31 (02): 453-457.  
Abstract6914)            Save
The purified microbial flocculant MBFA1 was obtained by centrifugation,ethanol precipitation,dialysis,gel permeation chromatography(GPC)and freezing-drying. The composition,content,molecular weight and structure of the microbial flocculant were analyzed by UV,IR,GPC and GC-MS. The results demonstrated that purified MBFA1 was lemon yellow solid mainly composed of polysaccharides. The content of polysaccharides was 91.2% and protein was 0.59%. The elemental analysis showed that 33.41% of carbon,7.69% of hydrogen,9.63% of nitrogen and 0.39% of sulphur were present in MBFA1. The mean molecular weight of MBFA1 was about 1.38×104 determined by GPC. Ultraviolet spectrum revealed that the absorption peak appeared at 199nm in MBFA1,which may be characteristic of polysaccharides. IR showed that functional groups,such as hydroxyl,amino,carboxyl,hydrogen bond and sulfate,which were beneficial to flocculation,were contained in the structure of MBFA1. GC-MS indicated that D-glucose dominated the monosaccharide composition,and a small amount of D-arabinose and D-mannose were also present in it with a molar ratio of about 100.7∶1∶8.2.
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Preparation of foam nickel-supported nanosized TiO2 by composite electrodeposition and its photocatalytic performance
YU Huajiang1,XIONG Liang2,XIONG Zhongqiong2,ZHANG Guoqing2
Chemical Industry and Engineering Progree   
Abstract6890)            Save

Foam Ni/TiO2 nano composite coatings were prepared by composite electrodepositon from Watts bath containing nanosized TiO2 particles. The surface morphologies of the composite coatings were characterized by scanning electronic microscopySEM. The composition of the coatings was analyzed by energy dispersive spectroscopyEDS. The effect of adding surfactant in the plating solution on the composite coatings was also studied. The photocatalytic activity of the foam Ni/TiO2 nano composite coatings on colibacillus and chlorella was discussed. The results showed that the appearance of coatings was fine and the amount of weight percentage of Ti in the coatings reached 5.97%. The foam Ni/TiO2 nano composite coatings with added anionic surfactant were finely dispered. The inactivation ratio of the aqueous sample containing colibacillus by the composite coatings reached 60.1% and 99.9% after 30 min and 60 min respectively. When the aqueous sample containing chlorella was treated with the composite coatingsthe content of chlorophyll-a decreased from 98.2 mg/m3 to 38.2 mg/m3 within 3 h. The coatings exhibited excellent photocatalytic activity.

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Osmium removal from ruthenium absorption liquid in rotating packed bed reactor via oxidation and vacuum degassing
ZHANG Deyu,LIU Weisheng
Chemical Industry and Engineering Progree   
Abstract6717)            Save
Orthogonal test was used to study the osmium removal from ruthenium absorption liquid in RPBR(rotating packed bed reactor)via oxidation and vacuum degassing. Effects of reaction temperature,H2O2 dosage,rate of liquid flow and RPBR rotating speed for the oxidation and degassing of osmium were investigated. Results showed that these factors are in the order of H2O2 dosage,reaction temperature,rate of liquid flow and RPBR rotating speed. These results provided a theoretical basis for the preparation of ruthenium hydrochloric acid solution with osmium in ppm using RPBR via oxidation and vacuum degassing.
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Synthesis of 5-amino-2,4-dinitrophenol as key intermidiate for poly(p-phenylene-2-benzoimidazol-6-oxazole)
JIN Ningren,HOU Xiaohua,MAO Liancheng,JIN Tingting,ZHANG Jianting,ZHAO Deming
Chemical Industry and Engineering Progree   
Abstract6175)            Save

A novel synthesis route and technique of 5-amino-2,4-dinitrophenolADNPas key intermediate for polyp-phenylene-2-benzoimidazol-6-oxazole)(PBIOwere studied systematically. ADNP was economically prepared by a two-step reaction from 4,6-dinitro-1,3-dichlorobenzeneDCDNBwith 73.6% total yield and 98.5% purity. In the first  step5-chloro-2,4-dinitrophenolCDNPwas obtained with high yield by the selective hydrolysis of DCDNB at 100 with aqueous NaOH. In the second stepCDNP was ammonolyzed under pressure at 150 using dioxane as solvent yielding the target product. The prepared ADNP was identified by FTIR1H NMR13C NMR and MS. This process for ADNP synthesis has advantages of simple operation procedurelower organic pollutionexcellent product qualitygood economy and easy industrialization etc.which provides convenience for further development of PBIO high-preformance materials.

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Ultrasonic synthesis and characterization of Zr-pillared montmorillonite for MTO catalytic reaction
WEI Zhaoni,CHEN Shufang,LIN Cheng
Chemical Industry and Engineering Progree   
Photocatalytic activity of BiVO4 and its positron annihilation spectrum
LIU Zili,LI Hui,QIN Zuzeng,CHEN Shengzhou,KE Gang,CHEN Guoshu,LIANG Hong
Chemical Industry and Engineering Progree   
Abstract5955)            Save
Positron lifetime technique is one of a few methods sensitive to voids on the mono-atomic scale. The photocatalytic activity of BiVO4 was studied when the degradation of 2,4-dinitrophenol was used as a probe reaction. The effect of calcination temperature on the photocatalytic activity of BiVO4 was analyzed by positron annihilation spectrum. The results showed that the amount of surface defects and the microstructure of photocatalyst changed with the calcination temperature. More surface defects,amount of photo produced electrons-hole,heterogeneity and the electronic density of defect sites were found on BiVO4 calcined at 900 ℃ than other temperatures,which increased the photocatalytic oxidation activity of BiVO4,that is,the degradation rate of 2,4-dinitrophenol was increased.
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Synthesis and properties of fumaropimaric acid-type
waterborne polyurethane
XU Xu,SHANG Shibin,SONG Zhanqian
Chemical Industry and Engineering Progree   
Abstract5804)            Save
Rosin-based waterborne polyurethanes(RWPU)were prepared from fumaropimaric acid polyester polyol(FAPP),polyether glycol(N-210)and toluene diisocyanate. Effects of the amount of dimethylol propionic acid(DMPA),R values and the amount of FAPP on properties of emulsions and RWPU films were studied. Properties of the products were characterized by FTIR spectra,specular gloss,pendulum hardness,tensile strength,impact strength,elongation at break and water-resistance. RWPU with excellent comprehensive properties was obtained when the amount of DMPA was 5%,R was 1.2,and the amount of FAPP was 35%,respectively.
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Synthesis of K2MnAl11O19 catalysts by using different methods and
investigation on their catalytic activity of methane combustion
REN Xiaoguang,ZHENG Jiandong,SONG Yongji
Chemical Industry and Engineering Progree   
Abstract5365)            Save
K2MnAl11O19 catalysts were prepared by co-precipitation or hydrolysis of metal alkoxide. The effects of preparation methods on crystal structure and properties of the catalysts were investigated by means of XRD,BET,SEM,TG-DTA and activity evaluation for methane combustion. The results showed that the catalyst with good crystallinity was obtained after calcination at 1200 ℃ for 4 h by these two methods. At the same time the catalysts had high catalytic activity and stability. The catalyst prepared by hydrolysis of metal alkoxide maintained high surface area and had higher catalytic activity for methane combustion.
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Effect of influent loading and reflux ratio on de-nitrification under low sludge concentration
ZHANG Lanhe1,2,WANG Luyao1,ZHANG Wanyou1,WANG Xuming3
Chemical Industry and Engineering Progree    2012, 31 (03): 693-698.  
Abstract4861)            Save
A long-term continuous experiment of simulated wastewater was carried out using A2/O process and effect of influent loading and reflux ratio on the removal efficiency of nitrification was investigated at low MLSS of (1500±200) mg/L. The results show that the influent loading increases gradually from 5.03 gCOD/(gMLSS·d)to 10.05 gCOD/(gMLSS·d)and removal efficiency of COD is higher than 95% when influent loading is changed by adjusting influent flow rate. Removal efficiency of NH4+-N increases from 69.59% to 95% and removal efficiency of TN increases from 53.53% to 80%,respectively. Furthermore,when influent loading is enhanced to 20.31 gCOD/(gMLSS·d),removal efficiencies of NH4+-N and TN decrease to 50% and 40%,respectively. The influent loading increases from 10.05 gCOD/(gMLSS·d) to 124.11 gCOD/(gMLSS·d) when influent loading is changed by adjusting influent COD. Removal efficiencies of COD and NH4+-N are all higher than 90% and removal efficiency of TN increases gradually from 70% to 80%,respectively. When the reflux ratio of mixture is 300%,200% and 100%,respectively,removal efficiencies of COD and NH4+-N are less affected by reflux ratio. Removal efficiencies of COD and NH4+-N are higher than 90% and 95%,respectively. And meantime,removal efficiency of TN drops with the increasing reflux ratio,which is greatly influenced by reflux ratio. When the internal reflux ratio is 100%,removal efficiency of TN reaches the highest and it is higher than 80%.
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Effect of activation condition on n-hexane isomerization performance of Pt/SO42?/ZrO2-Al2O3 catalyst
TIAN Jing, SONG Yueqin, FENG Minchao, JIN Yaqing, ZHOU Xiaolong
Chemical Industry and Engineering Progree   
Advance in pyrolysis and gasification of municipal solid waste study
YUAN Haoran1,LU Tao1,XIONG Zuhong1,HUANG Hongyu2,KOBAYASHI Noriyuki2,CHEN Yong3,LI Zhiqiang4
Chemical Industry and Engineering Progree    2012, 31 (02): 421-427.  
Abstract4807)            Save
Pyrolysis and gasification process of municipal solid waste was briefly clarified in this paper starting with various ways of municipal solid waste thermal conversion. The advantages and drawbacks of pyrolysis and gasification reactors were discussed. The research progress in municipal solid waste pyrolysis and gasification and the pilot test of pyrolysis and gasification technology together with their application status were all introduced. The effects of pyrolysis temperature and heating process on the yields and distribution of pyrolysis products,the effects of gasification temperature and oxygen equivalence ratio (RO) on the oxygen gasification reaction and the effects of gasification temperature,water vapor and the municipal solid waste mass ratio (S/M) on the steam gasification reaction were all illustrated clearly by comparing various experimental studies. It was found that the research on municipal solid waste pyrolysis and gasification focused on optimizing control parameters,improving reaction rate,promoting high-value target product and inhibiting the formation of other products and contaminants. Finally the research direction of municipal solid waste pyrolysis and gasification technology in the future was propsed that current research on municipal solid waste pyrolysis and gasification involved few research on the migration of pollutants during pyrolysis and gasification process and lagging study of the mechanisms of pyrolysis and gasification.
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Research on the preparation of ethylene from bio-ethanol
JIA Baoying,DU Ping,DU Fengguang,SUN Peiyong,NIU Delong
Chemical Industry and Engineering Progree   
Improved synthesis of levothyroxine sodium
ZHANG Wenwen1,LUO Fang2,CHEN Huiru1,WANG Bingheng1,JI Min2
Chemical Industry and Engineering Progree   
Abstract4729)            Save

Levothyroxine sodium was synthesized from L-tyrosine as raw material by six-step reactions. The catalyst in the key step of coupling reaction was improved. Some factors of coupling reaction were analyzed including the effect of amount catalystsolvent amountreaction temperature and reaction time. Under the optimal reaction conditionsthe yield of coupling reaction could reached up to 60.5%which was about 18.5% higher than beforethe total yield of levothyroxine sodium could reached up to 22.5%which was about 11.1% higher than before.

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Study on improvement of effective heat transfer temperature difference and enhancement of compound heat transfer in laminar flow
DENG Xianhe 1,HONG Yuxiang 1,LIU Haimin 2
Chemical Industry and Engineering Progree   
Research advances in forward osmosis membrane separation
SHI Renli,YANG Qingfeng
Chemical Industry and Engineering Progree   
Abstract4496)            Save

Forward osmosisFOis a concentration-driven membrane processin which water transports across a semi-permeable membrane from a dilute feed solution into a concentrated draw solution. The basic factors of FOdriving forcedraw solution and membrane materialsare introduced. The major hindrance to permeate water flux performance is the prevalence of concentration polarization on both sides of the membrane. Flux models that account for the presence of both internal and external concentration polarization for the two possible membrane orientations are presented. Internal concentration polarization is found to play a significant role in the reduction of driving force. This article comments the effect of membrane materialfeed solution concentrationand draw solution concentration on FO and pressure-retarded osmosisPROwater flux performance. In additionmembrane fouling as well as energy consumption of FO is evaluated.

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Research progress of foam SiC ceramic materials
LIU Xia1,LI Hong1,2,GAO Xin1,2,LI Xin1,WANG Lei3,DUAN Hong3,LI Xingang1,2
Chemical Industry and Engineering Progree   
Performance of unitized regenerative fuel cell
ZHANG Xinrong,WANG Tao,ZHANG Wei,LIU Xiang,SUN Yi,WANG Dong
Chemical Industry and Engineering Progree   
Abstract4490)            Save

The influence of reaction conditions on the performance of a unit cell of unitized regenerative fuel cellURFCwas reported. The cycling performance and polarization curves of the unit cell of URFC in the hydrogen and oxygen fuel cell and water electrolysis modes were tested. The unit cell of URFC exhibited excellent performance and stability in cycling test during URFC operation. The results showed that the optimum reaction temperature was from 60 to 70 in both fuel cell and water electrolysis modes. In fuel cell modeincreasing oxygen pressure would improve remarkably the performance of URFC. At hydrogen relative humidity of 100%oxygen relative humidity had less influence on the performance of URFC in fuel cell mode. The performance of the unit cell by oxygen without humidifying was identical to that of the unit cell by oxygen relative humidity of 100% in fuel cell mode when current density was greater than 500 mA/cm2.

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Chemical preparation methods of ferriferrous oxide nanomaterials
MA Qianli,DONG Xiangting,WANG Jinxian,LIU Guixia,YU Wensheng
Chemical Industry and Engineering Progree    2012, 31 (03): 562-573.  
Abstract4451)            Save
Applications of ferriferrous oxide nanomaterials in magnetic materials,multifunctional materials,catalysts and medical field are described in this paper. Preparation methods of ferriferrous oxide nanometerials,including precipitation method,sol-gel method,micro-emulsion method,hydrothermal and solvothermal method,thermal decomposition method and electrospinning method,are introduced. Applied fields of ferriferrous oxide nanomaterials with various morphologies,such as nanoparticles,nanorods,nanowire,nanofilm,hybrid and core-shell nanomaterials are discussed. In this paper the advances of these methods are summarized. The advantages and disadvantages of these methods are discussed. Moreover,combining with our work on the preparation of ferriferrous oxide nanomaterials,the development trends of these fabrication methods are also proposed:the preparation of ferriferrous oxide nanometerials with special morphologies,the decrease of agglomeration and the oxidation of ferriferrous oxide nanometerials,the combination of several preparation methods and a way to realize industrial production.
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Research advances of preparation of Pickering emulsions and their stability
QI Yabing, WU Zibo, YANG Qingcui
Chemical Industry and Engineering Progress    2024, 43 (4): 2017-2030.   DOI: 10.16085/j.issn.1000-6613.2023-0528
Abstract4412)   HTML141)    PDF(pc) (2615KB)(1413)       Save

Pickering emulsion refers to an emulsion which is stabilized by ultrafine solid particles or solid colloidal particles instead of traditional surfactants. It is widely applied in many fields involving petroleum, water treatment, cosmetics, food, pharmacy and materials industries due to its advantages such as excellent stability, convenient regulation, environment protection and low cost. In view of preparation and stability of Pickering emulsions, the preparation methods of Pickering emulsions were reviewed systematically. Then, the pattern and research progress of solid emulsifier particles were sketched. Besides, the stability mechanism of Pickering emulsions were revealed. Furthermore, the influencing factors on stability of Pickering emulsions were analyzed. And then, the existing problems of Pickering emulsions were discussed. Finally, the development trends of Pickering emulsions were outlooked. In future, the progress of Pickering emulsion were mainly shown in the following three aspects. ① The cheap, environment-friendly and reused Pickering emulsions with unmodified or modified natural solid nanoparticles were realized. ② The intelligent responsive Pickering emulsions (temperature, pH, magnetic and other response types) were applied in preparation of materials, slowly release or recovery of substance, catalytic reaction and so on. ③ The structure of solid emulsifier particles and emulsions were accurately controlled, and the systemized theory of emulsions preparation was established through deeply investigating the stability mechanism of Pickering emulsions.

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  Advances in biochar production from wastes and its applications
WANG Huaichen,FENG Leiyu,CHEN Yinguang
Chemical Industry and Engineering Progree    2012, 31 (04): 907-914.  
Abstract4366)            Save
Biochar,a kind of multifunctional materials,has drawn much attention in recent years. In this paper,the main organic waste as feedstock and the main process for biochar production were reviewed. The physicochemical properties of biochar such as the element content,alkalinity,surface characterization and the microscopic pore structure were introduced. Also,the potential application of biochar in the field of agriculture and environment was summarized,such as the utilization of soil conditioner for improving fertility,enhancing carbon fixation and reducing greenhouse gas emission,and as an effective adsorbent for removing heavy metals and organic pollutants from wastewater. Finally,the future research direction of biochar was forecasted,which indicated that more studies should be focused on large-scale,efficient and low-cost production of biochar as soon as possible. Also,the specific surface area of biochar as the alternative of activated carbon should be enhanced in the field of material and process. Moreover,further investigation on the mechanism of improvement and restoration of soil,the promotion of growth and production of crops as well as the greenhouse gas reduction by the biochar is highly desirable,so as to provide the data support from the large amount and long-term experiments.
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Separation of ethanol-isopropanol binary mixture by azeotropic distillation
ZHANG Luan,ZHU Hongji,BAI Peng
Chemical Industry and Engineering Progree   
Synthesis,characterization and thermal stability of resorcinol bis[di(pentaerythritol phosphate)] phosphate
SU Haixiao1,3,HOU Xufeng2,ZHONG Liu 1,LIU Zhiguo1,3
Chemical Industry and Engineering Progree   
Abstract4304)            Save

A novel phosphorus-containing flame retardantresorcinol bis[di(2,6,7-trioxa-1- phosphabicyclo [2.2.2]-octane-1-oxo-4-hydroxymethyl)] phosphateRBPPwas synthesized from pentaerythritolphosphorus oxychloride and resorcinol. The title compound was characterized by elemental analysisFTIRand 1H NMR. The results showed that the structure of the title compound was consistent with expectation. ThermogravimetryTginvestigation on thermal stability of RBPP showed that mass loss of 5% was at about 350 and residue at 600 was as high as 57.4%. The limiting oxygen indexLOIvalue coulds reach 31.8% and flame retardancy was UL-94 V-0 when mass fraction in E-51 epoxy resin was 15.2%.

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Batch extractive distillation for separation of ether-isopropanol-water azeotropic system
YE Qing,HUANG Lu,LU Yeqian,DU Guangyao
Chemical Industry and Engineering Progree   
Abstract4201)            Save

Batch extractive distillation for ether-isopropanol-water mixture was studied by using glycol as the extractant. The influence of solvent feeding ratereflux ratio and solvent feeding temperature was investigated. Under the optimal operation conditionssolvent feeding location at the column topreflux ratio was 2solvent feeding rate 11.4g/min in the step of isopropyl ether collection and 8.08 g/min in the step of isopropanol collectionsolvent feeding temperature 70.0 in the step of isopropyl ether collection and 100.0 in the step of isopropanol collectionthe mass fraction of isopropyl ether at the column top could reach 0.95 and its yield was 0.985the mass fraction of isopropanol at the column top could reach 0.97 and its yield was 0.968.

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Progress of reduction methods of graphene oxide
WU Jie
Chemical Industry and Engineering Progree   
Progress in synthesis and application of SSZ-13 zeolite
YANG Bo,GUO Cuili,CHENG Jingyao
Chemical Industry and Engineering Progree   
Research progress of electrolytes in supercapacitors
LI Zuopeng,ZHAO Jianguo,WEN Yaqiong,LI Jiang,XING Baoyan,GUO Yong
Chemical Industry and Engineering Progree   
Study on the removals of calcium and magnesium from seawater using CO2
ZHANG Jijun1,2,YUAN Junsheng1,2,LI Xia1
Chemical Industry and Engineering Progree    2012, 31 (03): 681-686.  
Abstract4043)            Save
Researches on the precipitation of calcium and magnesium from seawater have been carried out using CO2. The precipitation in the seawater,Mg-free seawater and Ca-free seawater system have been studied at pH value between 8.0 and 9.0. It was found that the removal rate of calcium can reach 90% when the pH value is between 8.0 and 9.0. Meanwhile,the removal rate of magnesium can reach 10% to 60%. In the Mg-free seawater system,the removal rate of calcium can reach 99% when the pH value is between 8.0 and 9.0. In the Ca-free seawater system,there is no precipitation between pH 8.0 and 8.3. The removal rate of magnesium can reach 60% when the pH value is between 8.5 and 9.0. The precipitated solids were characterized using X ray diffraction(XRD)analysis. The results show that they consist of CaCO3·H2O at pH 8.0,of CaCO3·H2O and MgCO3·3H2O between pH 8.3 and 9.0 in the seawater system. In the Mg-free seawater system,the precipitated solids consist of CaCO3. In the Ca-free seawater system,the precipitated solids consist of MgCO3·3H2O.
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Applications of deep desulfurization technology for MTBE production
ZHANG Jianmin,ZHAO Jinhai,CHEN Jun
Chemical Industry and Engineering Progree   
Activated carbon modification condition and its influence on the performance of the adsorption of hydrogen sulfide
LIU Xiaokun,LIU Yongjun
Chemical Industry and Engineering Progree    2012, 31 (03): 676-680.  
Abstract3977)            Save
The H2S adsorption breakthrough time and breakthrough capacity of industrial activated carbons which were untreated,modified by NaOH,Na2CO3,Fe(NO3)3,Cu(AC)2 impregnant respectively,and treated by oxidation sulfur bacteria biofilm were compared under the same condition. The results indicated that the activated carbon modified by NaOH was significantly better than any other modifier under the same condition. Compared with the modifier at different concentration of NaOH,the activated carbon modified by 20% NaOH had the best effect on the removal of hydrogen sulfide. The breakthrough time and the breakthrough capacity were 78.25 mg/g and 2000 min above respectively. After the oxidation sulfur bacteria biofilm was formed on the modified activated carbon,which had certain effect on the removal of hydrogen sulfide. The saturated activated carbon modified by NaOH can be regenerated by oxidation sulfur bacteria biofilm,and achieve 100% on the removal of hydrogen sulfide. The activated carbon treated by oxidation sulfur bacteria biofilm has a good effect on the removal of hydrogen sulfide.
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Determination of perfluoroisobutylene in fluorine chemicals production
LEI Shulei
Chemical Industry and Engineering Progree   
Abstract3949)            Save
Determination of perfluoroisobutylene (PFIB) in fluorine chemicals production is reviewed. The difficulties of determination of PFIB are analyzed. Also,the preparation of PFIB standard,chromatography column (packed column and capillary column),detector are reviewed. PFIB gas chromatography operational condition is given for reference. Finally,requirement for determination of PFIB at different concentrations and the probable trend of PFIB determination are presented.

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Mechanisms of phosphorus fixation in soils and efficient utilization of phosphate fertilizer
AN Di,YANG Ling,WANG Guanda,LAN Rui,WANG Tingjie,JIN Yong
Chemical Industry and Engineering Progree   
Research progress of hydrogen production with methanol steam reforming
YAN Yuejun1,2,LIU Qibin1,SUI Jun1,JIN Hongguang1
Chemical Industry and Engineering Progree   
Research progress of thiol-yne click chemistry
CAI Lei,XIONG Xingquan,TANG Zhongke,XU Yuanhong
Chemical Industry and Engineering Progree   
Abstract3860)            Save

Click chemistry has already received extensive attention owing to its obvious characteristicssuch as readily available starting materialsmoderate reaction conditionshigh yields and selectivity. Thiol-yne coupling reaction has been recently demonstrated as a novel click reactionowning to the features of simplicityhigh efficiency and versatilitymoderate reaction conditionsand a single product. Hereinthe definitioncharacteristicshistory as well as applications of click chemistry are reviewed. The mechanism of thiol-yne reaction and the advance in the preparation of functional polymers and surface modification based on this reaction are discussedincluding not only synthesis of dendrimershyperbranched polymersnetworksfunctional materialsbiomolecules and supramoleculesbut also surface modification of materials. The prospects of thiol-yne reaction are also presented.

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  Advance in production process and key manufacture technology
for methionine
GAO Wenliang,LI Linfeng,ZHANG Jingjing,LI Xueming,ZHENG Daomin
Chemical Industry and Engineering Progree    2012, 31 (04): 866-872.  
Abstract3836)            Save
Methionine has been used in many industrial fields,such as organism,medication,feedstuff and foodstuff,and shows a promising market demanding and a potential application prospect. This paper briefly reviews its domestic and foreign advance in production process,including enzymatic decomposition,microbial fermentation,and chemical synthesis. Chemical synthesis,including amino lactone method,malonic ester method,catalytic alkylation by solid-liquid phase transfer and hydantoin method,is emphasized,the key manufacture technique for hydantoin hydrolysis and methionine crystallization is especially intensively described. In the end,the development direction and application perspective in the domestic market are also prospected,which suggest that modern enterprise for methionine production should be built up as soon as possible using petrochemical byproducts.
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Research advance in resource recovery treatment of sewage sludge by pyrolysis
JIN Zhengyu1,ZHANG Guochen2,WANG Kaijun1
Chemical Industry and Engineering Progree    2012, 31 (01): 1-9.  
Abstract3810)            Save
Pyrolysis,as a new kind of thermochemical treatment in the field of waste treatment,can convert the material into stable and transportable form of energy. In this article,the fundamental principle,classification and kinetics of sewage sludge pyrolysis are introduced. Characteristics,development and state-of-art of different kinds of sewage sludge pyrolysis processes are also described according to phases of their target products,along with their possible effective usages. Additionally,Hybrid pyrolysis processes and future trends of pyrolysis process in sewage sludge treatment are discussed.
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Development of residuum hydroprocessing technologies
FANG Xiangchen
Chemical Industry and Engineering Progree   
Abstract3808)            Save

Driven by inferior crude oil supply and strict product specificationsresiduum hydroprocess is gradually becoming a major upgrading process and being quickly developed. The development statusits application characteristics and its development trend are discussed. It is believed from the application viewpoint that the fix bed process will still be the major selection by the industrybut how to process more inferior feedstock and extend its on-through time are the technical problems to be resolved. The ebullated bed process has very good application future and can be a good combination method with fix bed process if its high investment and operating difficulties can be resolved. The slurry bed process has its unique advantages while treating the ultra heavy crude.

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Catalytic reductive amination of glucose promoted by nano Ni supported on active carbon
DI Jianhui,LI Yunqing,WANG Jiaxi
Chemical Industry and Engineering Progree   
Abstract3805)            Save

Supported nickelNi/ACwas prepared by reduction of NiCl2 with NaBH4 in the presence of activated carbon. The catalystNi/Cwas characterized by SEMTEMand XRD. The effects of preparation and catalytic reaction conditions on catalytic activity were evaluated by using reductive amination of glucose with methylamine as a model reaction. The reaction product was analyzed by NMR. The glucose reacted with methylamine to form cyclo-methylamino-glucosethen was reduced under the action of the catalyst to form N-methyl-D-glucamine. The NaCl formed in the reduction preparation of the catalyst inhibited the catalytic reductive amination. The catalyst performance could be improved by adding triethylamine. The yield of N-methyl-D-glucamine was up to 98% at reaction temperature of 80 H2 pressure of 5.0 MPamolar ratio of glucose to Niglucose to MeNH2 and glucose to Et3N 9111.8 and 12.5respectively.

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采用数值模拟方法对火电厂SCR系统的预报具有经济、快捷和实用的优点。本文在总结国内外大量文献资料的基础上,对数值模拟技术在烟气SCR脱硝中的应用进行了综述。并把SCR模拟的发展归纳为:非均相动力学模型;均相反应速率模型;催化剂单孔道反应数值模拟;系统流场的数值模拟。在此基础上,提出了三维流动和详细反应的耦合是今后SCR模拟的一个重要发展方向。
Research progress in numerical simulation for flue gas denitration using selective catalytic reduction
Chemical Industry and Engineering Progree   
Abstract3798)            Save

Numerical simulation for selective catalytic reductionSCRsystem of power plant is of economicefficient and practical advantages. Based on literature investigationthe application of numerical simulation technology in flue gas denitration is reviewed. The development of mathematical models for SCR reaction is summarizedincluding kinetics and rate order based models. The numerical simulation for SCR system and catalyst channels is discussed. The coupling of three-dimensional turbulent flow and SCR reaction is proposed as an important development direction for SCR simulation.

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Preparation of glycolic acid by the fermentation of ethylene glycol
WEI Shenghua1,MENG Na1,ZHENG Changlong2,LI Wanzhen1
Chemical Industry and Engineering Progree    2012, 31 (02): 397-401.  
Abstract3783)            Save
In this paper the fermentation process of glycolic acid from ethylene glycol by Gluconobacter oxydans is studied. The results showed that the optimal fermentation condition was as follows:the ethylene glycol concentration was 80 g/L,adding 40 g/L of sorbitol to the medium as supplement carbon source in order to promote cell growth,1.0mol/L of sodium hydroxide and ammonia mixture was the neutralizer used in the fermentation process to maintain pH of 5.5. After 40hrs fermentation,the production of glycolic acid was 97.4 g/L,the yield was 96.8%. The method established the foundation for the biological production of glycolic acid.
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An overview of proton exchange membrane fuel cell
GAO Weitao, LEI Yijie, ZHANG Xun, HU Xiaobo, SONG Pingping, ZHAO Qing, WANG Cheng, MAO Zongqiang
Chemical Industry and Engineering Progress    2022, 41 (3): 1539-1555.   DOI: 10.16085/j.issn.1000-6613.2021-2003
Abstract3697)   HTML272)    PDF(pc) (3475KB)(3101)       Save

Proton exchange membrane fuel cell (PEMFC) has been considered as one of the most promising next-generation power sources for clean automobiles because of their advantages in efficiency, power density, environmental friendliness, low temperature start ability, etc.. However, the gap between the durability and cost of PEMFC and those of commercialization requirements is still large. To overcome the above-mentioned two major problems, joint efforts and progress of the entire fuel cell process chain are required. In this paper, the recent research progress of the entire PEMFC process chain, from catalysts, membrane electrode assemblies (MEA), fuel cell stacks to fuel cell engines, are analyzed and classified reviewed, and research hotspots such as single-atom catalysts, non-noble metal catalysts, special morphology catalysts, ordered catalyst layers, high-temperature proton exchange membranes, MEA interlayer interface optimization, integrated porous bipolar plates, hydrogen circulation, are introduced. This paper points out that low/non-platinum catalyst layers, ultra-thin proton exchange membranes, gradient/ordered MEA, high-temperature operation and self-humidification of fuel cells are the future development trends, of which further innovation and breakthrough are urgently needed.

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Synthesis technologies for glyphosate
CHEN Dan1,LI Jian4,LI Guoru3,CHEN Biaohua1,YIN Fengxiang2,3
Chemical Industry and Engineering Progree   
Research progress of technological processes of lactic acid production by simultaneous saccharification and fermentation
PENG Zhihong
Chemical Industry and Engineering Progree   
Abstract3641)            Save

As important chemical raw materialslactic acid and its derivatives have been widely used in foodpharmacytextile and other chemical related industries. In recent yearssimultaneous saccharification and fermentationSSFhas been gradually applied to the lactic acid fermentation process. In this paperthe effect of such factors as raw materialsstrainsglucoamylase and temperature on the productivity of SSF are reviewedthese factors and their interactions are discussed and development of the lactic acid production by SSF is prospected. Compared with traditional fermentationSSF has the advantage of shortening the production cyclesaving equipment investmentincreasing productivityand reducing energy consumption.

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Research progress in organic wastewater treatment by low-temperature plasma discharge technology
QU Guangzhou1,2,LI Jie3,4,LIANG Dongli1,2,QU Dong1,2,HUANG Yimei1,2
Chemical Industry and Engineering Progree    2012, 31 (03): 662-670.  
Abstract3641)            Save
The high voltage discharge can produce low-temperature plasma and induce both physical and chemical processes. The processing technology has the comprehensive action of high-energy electron,ultraviolet light,ozone etc. The technology that integrates light,electronic and chemical oxidation into one process has a good development prospect in wastewater treatment. In this paper,the degradation processes and mechanism of organic wastewater by low temperature plasma technology are introduced. The research status and development trend of pulsed corona discharge,dielectric barrier discharge,glow discharge and gliding arc discharge plasma for organic wastewater treatment at home and abroad are summarized. The current main existing problems include single treatment object orientedand high processing cost. In the future,the study about this technique should be focused on the optimization process,the reduction of the processing cost and energy consumption,so that this technology can be applied to practical wastewater treatment as soon as possible.
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Advance in biosynthesis of polyhydroxyalkanoate
HUANG Jinbiao1,SHANG Long’an2
Chemical Industry and Engineering Progree   
Abstract3634)            Save

PolyhydroxyalkanoatePHAis a type of polymer which can be synthesized by a variety of microbes. This new kind of material can be used as a substitute for the traditional petrochemical plastics because of its complete bio-degradability. PHA biosynthesis paths in different microbes have been studied widely and extensively to these days. In order to reduce PHA price and realize industrialisationmany researches have been focused on screening high-productivity strain and using cheap carbon source to synthesis PHA. This review introduces the PHA biosynthesis pathways and advance in biosynthesis of PHA.

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Preparation and characterization of blend anion-exchange membrane from quarternized hydroxyethylcellulose/quaternized poly(vinyl alcohol)
DONG Rui,LI Yuanbing,ZHANG Jianxun,SUN Xiaobin,MA Lei,XU Wen
Chemical Industry and Engineering Progree    2012, 31 (03): 612-616.  
Abstract3632)            Save
Anion exchange membrane is the key of alkaline direct methanol fuel cell (ADMFC). A series of quarternized hydroxyethylcellulose(QHEC)and quaternized poly (vinyl alcohol)(QPVA) blend anion exchange membranes were produced by mixing QPVA and QHEC at different ratios,hot crosslinked and characterized. The morphology of the blend membranes showed that its structure was compact and uniform.TG-DSC showed that the blend membranes were stable below 300 ℃. The conductivity of the composite membrane increased with the content increasing of quaternized poly(vinyl alcohol)and temperature. It was between 2.0×10-2 s/cm and 7.8×10-2 s/cm. The QHEC membrane has good impediment effect to the methanol and the lowest methanol permeability of QHEC membrane was 2.49×10-6 cm2/s at 20 ℃. With the increase of QPVA contents,the methanol permeability of blend membranes would increase slightly.
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Technology of recovering urea from urea inclusion compounds producted in the separation of fatty acids using urea complexation
Lü Wei,JIANG Jianchun,XU Junming
Chemical Industry and Engineering Progree    2012, 31 (01): 201-207.  
Abstract3618)            Save
The technology using methanol-toluene binary solvent mixtures to recover urea and fatty acids from urea inclusion compounds was chosen as the best method through comparative experiments among five kinds of processes. The recovered yields of fatty acids and urea were 99.12% and 99.46% respectively,when the ratio of urea inclusion compounds - methanol - toluene was 1∶3∶3(g∶mL∶mL). Recovered fatty acids was analyzed using FT-IR,GPC and GC-MS. FT-IR spectroscopy identified the structure of recovery material,finding that both saturated and unsaturated fatty acids were contained. Relative molecular weight of recovery fatty acids was 443 with a content of 93.92%. Six kinds of fatty acids were identified and content of UFAs(93.96%)were detected in recovery fatty acids via GC-MS. In recovered urea,long needle-like cylindrical crystal structure was observed using SEM,with a better crystallinity. Recovered urea reused for isolating PUFAs were investigated six times. The contents and yields of PUFAs purified by recovery urea were among 81%~89% and 60%~72% respectively,and the purity of UFAs was 100%.
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Removals of nitrogen and phosphorus in the water by submerged hydrophytes
ZUO Qili,LI Ziyan,YANG Xiaolin,LIU Kaiqing,DU Liang,DU Jinhong,QIU Li,JIANG Hao
Chemical Industry and Engineering Progree    2012, 31 (01): 217-221.  
Abstract3611)            Save
Through static simulation test,three kinds of submerged plant including Elodea densaPlanch.Casp.Ceratophyllum demersum LCabomba Fanwort were studied. They were highly efficient in removing total nitrogen(TN),total phosphor(TP). The change of the biomass at the different nutritional levels was also investigated. The nutritional levels were described by mesotrophic concentration,eutrophic concentration,hyperbolic concentration and stress concentration. The research results indicate that three kinds of submerged hydrophytes are capable of removing nitrogen and phosphorus effectively at the different nutritional levels in the water. At mesotrophic concentration,eutrophic concentration and hyperbolic concentration,Ceratophyllum demersum L showed well TN removal efficiency in the water,Elodea densaPlanch.Casp.showed well removal efficiency on both TN and TP in the water at the different nutritional levels. At hyperbolic concentration and stress concentration nutritional levels,the removal efficiency of Elodea densaPlanch.Casp.is higher than Ceratophyllum demersum L,and Cabomba Fanwort.
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