Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (3): 1371-1383.DOI: 10.16085/j.issn.1000-6613.2020-0875
• Energy processes and technology • Previous Articles Next Articles
ZHOU Sili1(), ZHANG Zhengguo1,2, FANG Xiaoming1,2()
Received:
2020-05-20
Online:
2021-03-17
Published:
2021-03-05
Contact:
FANG Xiaoming
通讯作者:
方晓明
作者简介:
周四丽(1993—),女,硕士研究生,研究方向为复合相变材料及其应用。E-mail:基金资助:
CLC Number:
ZHOU Sili, ZHANG Zhengguo, FANG Xiaoming. Research progress of solid-solid phase change materials for thermal energy storage[J]. Chemical Industry and Engineering Progress, 2021, 40(3): 1371-1383.
周四丽, 张正国, 方晓明. 固-固相变储热材料的研究进展[J]. 化工进展, 2021, 40(3): 1371-1383.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2020-0875
多元醇 | 固-固转变 | 固-液转变 | ||
---|---|---|---|---|
相变温度/℃ | 转变热/J·g-1 | 相变温度/℃ | 转变热/J·g-1 | |
2-氨基-2-甲基-1,3-丙二醇(AMP) | 56.96 过冷严重 | 114.06 — | 108.72 102.25 | 28.02(加热) 25.61(冷却) |
新戊二醇(NPG) | 44.09 17.51 | 116.54 81.90 | 123.05 119.04 | 28.80(加热) 25.61(冷却) |
三羟甲基乙烷(PG) | 81.76 | 172.58 | 199.63 | 42.65(加热) |
三羟甲基氨基甲烷(TAM) | 133.83 | 270.31 | 171.72 | 24.99(加热) |
季戊四醇(PE) | 185.45 165.19 | 209.45 180.93 | 257.07 244.99 | 33.61(加热) 13.70(冷却) |
多元醇 | 固-固转变 | 固-液转变 | ||
---|---|---|---|---|
相变温度/℃ | 转变热/J·g-1 | 相变温度/℃ | 转变热/J·g-1 | |
2-氨基-2-甲基-1,3-丙二醇(AMP) | 56.96 过冷严重 | 114.06 — | 108.72 102.25 | 28.02(加热) 25.61(冷却) |
新戊二醇(NPG) | 44.09 17.51 | 116.54 81.90 | 123.05 119.04 | 28.80(加热) 25.61(冷却) |
三羟甲基乙烷(PG) | 81.76 | 172.58 | 199.63 | 42.65(加热) |
三羟甲基氨基甲烷(TAM) | 133.83 | 270.31 | 171.72 | 24.99(加热) |
季戊四醇(PE) | 185.45 165.19 | 209.45 180.93 | 257.07 244.99 | 33.61(加热) 13.70(冷却) |
PCM | 熔化温度/℃ | 熔化焓/J·g-1 | 结晶温度/℃ | 结晶焓/J·g-1 | 升温速率/℃·min-1 | 参考文献 |
---|---|---|---|---|---|---|
纤维素-g-PEG | 40.7~60.1 | 77.6~203.2 | 25.1~40.6 | 44.7~203.2 | 10 | [ |
CDA/PEG4000 | 40 | 73.6 | — | — | 5 | [ |
NCC/PEG4000 | 47.2 | 103.8 | — | — | 5 | [ |
纤维素-g-mPEG | 40.2~50.4 | 133.0~175.4 | 12.2~28.9 | 97.8~157.7 | 10 | [ |
HB-PUPCM6000 | 57.5~67.0 | 91.2~138.2 | 7.8~33.2 | 89.4~132.3 | 10 | [ |
HB-PUPCM6000 | 66.6 | 124.8 | 33.1 | 121.4 | 10 | [ |
HB-PUPCM | 56.15~56.99 | 117.1~146.6 | 36.61~36.98 | 88.35~125.6 | 10/5 | [ |
PEG10000-MDI-BDO | 65.28 | 138.7 | 38.58 | 126.2 | 10 | [ |
PEG6000-MDI-BDO/SA | 65.28 | 152.7 | — | — | 10 | [ |
D-HBPU | 59.0 | 125.0 | 36.8 | 120.6 | 10 | [ |
TPUPCM | 56.1 | 137.4 | 37.5 | 127.6 | — | [ |
PU高聚物-6 | 57.1 | 142.5 | 33.2 | 137.7 | 10 | [ |
PU高聚物-10 | 60.8 | 152.3 | 34.8 | 149.7 | 10 | [ |
SPCM | 44.3 | 122.4 | 37.2 | 120.3 | 10 | [ |
TPCM | 47.8 | 127.7 | 38.5 | 130.2 | 10 | [ |
PEG/MDI/丙三醇 | 41.8 | 128.5 | 38.1 | 112.3 | 10 | [ |
PEG/MDI/TMP | 42.5 | 119.3 | 38.3 | 106.7 | 10 | [ |
PEG6000/PAPI | 50.48 | 111.7 | 41.38 | 110.4 | 10 | [ |
BPU | 43.4/52.8 | 86.0/114.9 | 24.5/28.8 | 83.1/111.2 | 10 | [ |
NPU | 55.8/55.7 | 136.5/137.5 | 27.7/33.6 | 128.0/129.8 | 10 | [ |
Eu-PEG | 62.46~72.13 | 19.83~96.62 | 24.96~44.89 | 16.38~83.18 | — | [ |
聚苯乙烯-g-PEG6000 | 44.95~58.04 | 111.48~179.47 | 34.36~38.48 | 99.43~143.6 | 5 | [ |
SMA-g-PEG6000 | 39.69~45.03 | 107.04~155.21 | 23.68~33.56 | 109.86~142.62 | 10 | [ |
DC-PCM | 40.6~71.0 | 44.3~87.8 | 7.5~39.2 | 29.3~107.2 | 5 | [ |
Fe3+-PEG | — | 97.6 | — | 92.9 | 5 | [ |
Poly(S-PA-S) | 18.72~21.47 | 26.20~39.78 | 17.65~18.72 | 20.02~39.19 | 5 | [ |
SAN-g-PA | 24.7~36.1 | 11.7~24.4 | 23.9~33.8 | 11.6~23.7 | 10 | [ |
SMA-g-SA | 67.2~67.4 | 59.3~126.7 | 62.9~63.8 | 60.7~125.0 | 5 | [ |
SMA-g-PA | 61.0~61.6 | 41.7~119.8 | 55.6~57.1 | 42.4~117.7 | 5 | [ |
SMA-g-MA | 53.0~54 | 35.7~109.7 | 45.8~47.5 | 32.4~114.8 | 5 | [ |
SMA-g-LA | 42.3~43.7 | 17.6~84.2 | 37.3~38.7 | 13.4~74.8 | 5 | [ |
MBA/PEGA | 52.99~57.15 | 74.13~168.96 | 30.59~38.27 | 42.01~145.97 | 10 | [ |
纤维素-g-E2C16 | 28.2~28.6 | 21~33 | 12.9~14.9 | 18~30 | 30/10 | [ |
CA-g-PAn | 17.4~53.2 | 15~95 | 5.1~36.7 | 15~92 | 10 | [ |
PCM | 熔化温度/℃ | 熔化焓/J·g-1 | 结晶温度/℃ | 结晶焓/J·g-1 | 升温速率/℃·min-1 | 参考文献 |
---|---|---|---|---|---|---|
纤维素-g-PEG | 40.7~60.1 | 77.6~203.2 | 25.1~40.6 | 44.7~203.2 | 10 | [ |
CDA/PEG4000 | 40 | 73.6 | — | — | 5 | [ |
NCC/PEG4000 | 47.2 | 103.8 | — | — | 5 | [ |
纤维素-g-mPEG | 40.2~50.4 | 133.0~175.4 | 12.2~28.9 | 97.8~157.7 | 10 | [ |
HB-PUPCM6000 | 57.5~67.0 | 91.2~138.2 | 7.8~33.2 | 89.4~132.3 | 10 | [ |
HB-PUPCM6000 | 66.6 | 124.8 | 33.1 | 121.4 | 10 | [ |
HB-PUPCM | 56.15~56.99 | 117.1~146.6 | 36.61~36.98 | 88.35~125.6 | 10/5 | [ |
PEG10000-MDI-BDO | 65.28 | 138.7 | 38.58 | 126.2 | 10 | [ |
PEG6000-MDI-BDO/SA | 65.28 | 152.7 | — | — | 10 | [ |
D-HBPU | 59.0 | 125.0 | 36.8 | 120.6 | 10 | [ |
TPUPCM | 56.1 | 137.4 | 37.5 | 127.6 | — | [ |
PU高聚物-6 | 57.1 | 142.5 | 33.2 | 137.7 | 10 | [ |
PU高聚物-10 | 60.8 | 152.3 | 34.8 | 149.7 | 10 | [ |
SPCM | 44.3 | 122.4 | 37.2 | 120.3 | 10 | [ |
TPCM | 47.8 | 127.7 | 38.5 | 130.2 | 10 | [ |
PEG/MDI/丙三醇 | 41.8 | 128.5 | 38.1 | 112.3 | 10 | [ |
PEG/MDI/TMP | 42.5 | 119.3 | 38.3 | 106.7 | 10 | [ |
PEG6000/PAPI | 50.48 | 111.7 | 41.38 | 110.4 | 10 | [ |
BPU | 43.4/52.8 | 86.0/114.9 | 24.5/28.8 | 83.1/111.2 | 10 | [ |
NPU | 55.8/55.7 | 136.5/137.5 | 27.7/33.6 | 128.0/129.8 | 10 | [ |
Eu-PEG | 62.46~72.13 | 19.83~96.62 | 24.96~44.89 | 16.38~83.18 | — | [ |
聚苯乙烯-g-PEG6000 | 44.95~58.04 | 111.48~179.47 | 34.36~38.48 | 99.43~143.6 | 5 | [ |
SMA-g-PEG6000 | 39.69~45.03 | 107.04~155.21 | 23.68~33.56 | 109.86~142.62 | 10 | [ |
DC-PCM | 40.6~71.0 | 44.3~87.8 | 7.5~39.2 | 29.3~107.2 | 5 | [ |
Fe3+-PEG | — | 97.6 | — | 92.9 | 5 | [ |
Poly(S-PA-S) | 18.72~21.47 | 26.20~39.78 | 17.65~18.72 | 20.02~39.19 | 5 | [ |
SAN-g-PA | 24.7~36.1 | 11.7~24.4 | 23.9~33.8 | 11.6~23.7 | 10 | [ |
SMA-g-SA | 67.2~67.4 | 59.3~126.7 | 62.9~63.8 | 60.7~125.0 | 5 | [ |
SMA-g-PA | 61.0~61.6 | 41.7~119.8 | 55.6~57.1 | 42.4~117.7 | 5 | [ |
SMA-g-MA | 53.0~54 | 35.7~109.7 | 45.8~47.5 | 32.4~114.8 | 5 | [ |
SMA-g-LA | 42.3~43.7 | 17.6~84.2 | 37.3~38.7 | 13.4~74.8 | 5 | [ |
MBA/PEGA | 52.99~57.15 | 74.13~168.96 | 30.59~38.27 | 42.01~145.97 | 10 | [ |
纤维素-g-E2C16 | 28.2~28.6 | 21~33 | 12.9~14.9 | 18~30 | 30/10 | [ |
CA-g-PAn | 17.4~53.2 | 15~95 | 5.1~36.7 | 15~92 | 10 | [ |
PCM | 相变温度/℃ | 相变焓/J·g-1 | 熔化温度/℃ | 熔化焓/J·g-1 | 参考文献 |
---|---|---|---|---|---|
(C12H25NH3)2ZnCl4 | 88.23 | 105.01 | — | — | [ |
(C12H25NH3)2CoCl4 | 63.85,67.85 | 33.72,59.30 | — | — | [ |
(C12H25NH3)2MnCl4 | 53.85,55.85 | 74.31,6.59 | — | — | [ |
(C10H21NH3)2CuCl4 | 33.77 | 55.13 | 36.91 | 7.53 | [ |
(C10H21NH3)2ZnCl4 | 80.14 | 82.90 | 162.79 | 18.14 | [ |
(C10H21NH3)2CdCl4 | 27.0,61.0 | 34.5,8.25 | 121.0 | 13.13 | [ |
(C10H21NH3)2HgCl4 | 36.73 | 28.02 | 203.0 | 50.42 | [ |
(C10H21NH3)2MnCl4 | 32.80 | 77.44 | — | — | [ |
(C10H21NH3)2CoCl4 | 77.71 | 74.38 | 165.0 | 13.70 | [ |
(C10H21NH3)2NiCl4 | 32.0,58.0 | 15.2 | 135.0 | 65.76 | [ |
PCM | 相变温度/℃ | 相变焓/J·g-1 | 熔化温度/℃ | 熔化焓/J·g-1 | 参考文献 |
---|---|---|---|---|---|
(C12H25NH3)2ZnCl4 | 88.23 | 105.01 | — | — | [ |
(C12H25NH3)2CoCl4 | 63.85,67.85 | 33.72,59.30 | — | — | [ |
(C12H25NH3)2MnCl4 | 53.85,55.85 | 74.31,6.59 | — | — | [ |
(C10H21NH3)2CuCl4 | 33.77 | 55.13 | 36.91 | 7.53 | [ |
(C10H21NH3)2ZnCl4 | 80.14 | 82.90 | 162.79 | 18.14 | [ |
(C10H21NH3)2CdCl4 | 27.0,61.0 | 34.5,8.25 | 121.0 | 13.13 | [ |
(C10H21NH3)2HgCl4 | 36.73 | 28.02 | 203.0 | 50.42 | [ |
(C10H21NH3)2MnCl4 | 32.80 | 77.44 | — | — | [ |
(C10H21NH3)2CoCl4 | 77.71 | 74.38 | 165.0 | 13.70 | [ |
(C10H21NH3)2NiCl4 | 32.0,58.0 | 15.2 | 135.0 | 65.76 | [ |
SS-PCM | 热导率/W·m-1·K-1 | 参考文献 |
---|---|---|
NPG | 0.12~0.24 | [ |
PG | 0.232~0.36 | [ |
PE | 0.106 | [ |
聚苯乙烯-g-PEG | 0.10~0.13 | [ |
聚(S-PA-S) | 0.13~0.2 | [ |
硬脂酸 | 0.18 | [ |
S-AA-SE | 0.12~0.15 | [ |
(n-C6H13)2NH2Br | 0.12~0.17 | [ |
SS-PCM | 热导率/W·m-1·K-1 | 参考文献 |
---|---|---|
NPG | 0.12~0.24 | [ |
PG | 0.232~0.36 | [ |
PE | 0.106 | [ |
聚苯乙烯-g-PEG | 0.10~0.13 | [ |
聚(S-PA-S) | 0.13~0.2 | [ |
硬脂酸 | 0.18 | [ |
S-AA-SE | 0.12~0.15 | [ |
(n-C6H13)2NH2Br | 0.12~0.17 | [ |
SS-PCM | 过冷度/℃ | 参考文献 |
---|---|---|
PE | 24.3 | [ |
NPG | 43.3 | [ |
(C8H17NH3)2ZnCl4 | 9.9 | [ |
(C10H21NH3)2ZnCl4 | 6.5 | [ |
(C14H29NH3)2ZnCl4 | 6.6 | [ |
(C8H17NH3)2CoCl4 | 9.3 | [ |
(C8H17NH3)2CaCl4 | 8.4 | [ |
(C10H21NH3)2CaCl4 | 8.7 | [ |
(C14H29NH3)2CaCl4 | 9.1 | [ |
(C18H37NH3)2CaCl4 | 9.5 | [ |
(C10H21NH3)2ZnCl4-(C10H21NH3)2CoCl4 | 7 | [ |
(C18H37NH3)2CuCl4-(C18H37NH3)2MnCl4 | 9 | [ |
(C16H33NH3)2CuCl4-(C18H37NH3)2CoCl4 | 8 | [ |
(C10H21NH3)2CoCl4-(C10H21NH3)2CaCl4 | 9 | [ |
(C8H17NH3)2MnCl4 | 0.6 | [ |
(C10H21NH3)2MnCl4 | 1.3 | [ |
(C12H25NH3)2MnCl4 | 1.4 | [ |
SS-PCM | 过冷度/℃ | 参考文献 |
---|---|---|
PE | 24.3 | [ |
NPG | 43.3 | [ |
(C8H17NH3)2ZnCl4 | 9.9 | [ |
(C10H21NH3)2ZnCl4 | 6.5 | [ |
(C14H29NH3)2ZnCl4 | 6.6 | [ |
(C8H17NH3)2CoCl4 | 9.3 | [ |
(C8H17NH3)2CaCl4 | 8.4 | [ |
(C10H21NH3)2CaCl4 | 8.7 | [ |
(C14H29NH3)2CaCl4 | 9.1 | [ |
(C18H37NH3)2CaCl4 | 9.5 | [ |
(C10H21NH3)2ZnCl4-(C10H21NH3)2CoCl4 | 7 | [ |
(C18H37NH3)2CuCl4-(C18H37NH3)2MnCl4 | 9 | [ |
(C16H33NH3)2CuCl4-(C18H37NH3)2CoCl4 | 8 | [ |
(C10H21NH3)2CoCl4-(C10H21NH3)2CaCl4 | 9 | [ |
(C8H17NH3)2MnCl4 | 0.6 | [ |
(C10H21NH3)2MnCl4 | 1.3 | [ |
(C12H25NH3)2MnCl4 | 1.4 | [ |
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