Development trend of preparation and application of nickel nano-powder

doi:10.16085/j.issn.1000-6613.2018-1515

Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (05): 2252-2261.DOI: 10.16085/j.issn.1000-6613.2018-1515

• Materials science and technology • Previous Articles Next Articles

Development trend of preparation and application of nickel nano-powder

Kai YE^1,²(),Feng LIANG^1,^2,³(),Yaochun YAO^1,²,Wenhui MA^1,^2,³,Bin YANG^1,^2,³,Yongnian DAI^1,^2,³

1. The National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
2. Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
3. State Key Laboratory of Complex Nonferrous Metal Resources Clear Utilization, Kunming University of Science and Technology, Kunming 650093, Yunnan, China

Received:2018-07-22 Revised:2018-12-04 Online:2019-05-05 Published:2019-05-05
Contact: Feng LIANG

纳米镍粉的制备与应用的发展趋势

叶凯^1,²(),梁风^1,^2,³(),姚耀春^1,²,马文会^1,^2,³,杨斌^1,^2,³,戴永年^1,^2,³

1. 昆明理工大学真空冶金国家工程实验室，云南昆明 650093
2. 昆明理工大学云南省有色金属真空冶金重点;实验室，云南昆明650093
3. 昆明理工大学省部共建复杂有色金属资源清洁利用国家重点实验室，云南昆明650093

通讯作者: 梁风
作者简介:<named-content content-type="corresp-name">叶凯</named-content>（1995—），男，硕士研究生，研究方向为电弧等离子体制备纳米材料。E-mail：<email>18672008847@163.com</email>。|梁风，副教授，硕士生导师，研究方向为等离子体技术制备纳米材料、高能量密度储能器件等。E-mail：<email>liangfeng@kmust.edu.cn</email>。
基金资助:
国家自然科学基金(51704136，11765010);云南省应用基础研究面上项目(2016FB087);云南省院士自由探索基金(2018HA006)

Abstract

Abstract:

This paper introduces the common preparation methods of nickel nano-powder such as the plasma, liquid phase reduction, spark discharge erosion and high energy ball milling. The advantages and disadvantages of these methods are summarized. There are however still several problems in the preparation of nickel nano-powder. For instance, it is difficult to achieve large-scale production and the purity and performance are difficult to meet the application requirements. The research trends are concluded as analyzing the nucleation and growth mechanism, and finding the best synthesis conditions to prepare the nickel nano-powder controllably. In addition, this paper describes the application status and demands of nickel nano-powder in MLCC and catalysts and points out that the problems of easy oxidation, poor matching with other materials need to be overcome. It is necessary to optimize its performance by surface modification or by other ways. At last, the research tendency of nickel nano-powder in the future are to bind the application of nickel nano-powder with its preparation method, that is using the most suitable preparation method to meets the application requirement.

Key words: nanomaterials, preparation, plasma method, liquid phase reduction method, multilayer ceramic capacitor, catalyst

摘要：

介绍了等离子体法、液相还原法、电火花放电腐蚀法和高能球磨法等几种纳米镍粉的常见制备方法，总结了各种方法的优缺点，归纳了在纳米镍粉的制备过程中存在着难以实现规模化生产、纯度难以控制等问题；其研究趋势是通过分析其成核与生长机理，找到最佳合成条件以实现纳米镍粉的可控制备。另外，本文重点叙述了纳米镍粉在多层陶瓷电容器（MLCC）和催化剂等领域的应用现状，从应用的角度阐述了各个领域对纳米镍粉的需求。在纳米镍粉的应用中，存在着易氧化及同其他材料匹配性差等问题，需要通过表面改性等手段优化其应用性能。最后，文章指出将纳米镍粉的应用与其制备方法相结合，用最合适的方法制备出符合应用要求的纳米镍粉，是未来纳米镍粉的研究趋势。

关键词: 纳米材料, 制备, 等离子体法, 液相还原法, 多层陶瓷电容器, 催化剂

CLC Number:

TB31

Kai YE, Feng LIANG, Yaochun YAO, Wenhui MA, Bin YANG, Yongnian DAI. Development trend of preparation and application of nickel nano-powder[J]. Chemical Industry and Engineering Progress, 2019, 38(05): 2252-2261.

叶凯, 梁风, 姚耀春, 马文会, 杨斌, 戴永年. 纳米镍粉的制备与应用的发展趋势[J]. 化工进展, 2019, 38(05): 2252-2261.

Figures/Tables 10

References 55

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制备方法	优点	缺点
等离子体法	产物纯度高、尺寸小、粒径分布均匀、形状与尺寸可控、制备过程对环境友好	设备要求高、规模化生产难度高
液相还原法	原料来源广泛、尺寸小、粒径分布均匀、形状与尺寸可控	环境污染、产率较低、分散性较差
电火花放电腐蚀法	设备简单、产物纯度高、粒径分布均匀	尺寸较大、产物易氧化
高能球磨法	操作简单、成本低、产量高、粒径可控	产物纯度较低、粒径分布不够均匀、粉末易发生团聚

制备方法	优点	缺点
等离子体法	产物纯度高、尺寸小、粒径分布均匀、形状与尺寸可控、制备过程对环境友好	设备要求高、规模化生产难度高
液相还原法	原料来源广泛、尺寸小、粒径分布均匀、形状与尺寸可控	环境污染、产率较低、分散性较差
电火花放电腐蚀法	设备简单、产物纯度高、粒径分布均匀	尺寸较大、产物易氧化
高能球磨法	操作简单、成本低、产量高、粒径可控	产物纯度较低、粒径分布不够均匀、粉末易发生团聚

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Development trend of preparation and application of nickel nano-powder

纳米镍粉的制备与应用的发展趋势

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