Chemical Industry and Engineering Progress ›› 2018, Vol. 37 ›› Issue (01): 350-358.DOI: 10.16085/j.issn.1000-6613.2017-0687

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Ultrasound enhanced degradation of decabromodiphenyl ether by montmorillonite supported Ni-Fe nanoparticles

HAN Wenliang, CHEN Haiming   

  1. Department of Environmental Science and Engineering, College of Chemical Engineering, Huaqiao University, Xiamen 361021, Fujian, China
  • Received:2017-04-18 Revised:2017-07-12 Online:2018-01-05 Published:2018-01-05

蒙脱石搭载纳米Ni-Fe超声降解十溴二苯醚

韩文亮, 陈海明   

  1. 华侨大学化工学院环境科学与工程系, 福建 厦门 361021
  • 通讯作者: 韩文亮(1980-),男,博士,讲师,研究方向为环境污染及其防治。
  • 作者简介:韩文亮(1980-),男,博士,讲师,研究方向为环境污染及其防治。E-mail:wl_han@163.com。
  • 基金资助:
    国家自然科学基金(41203077)及泉州市科技计划(2012Z85)项目。

Abstract: In order to resolve the problem of traditional nanoscale zero valent iron (nZVI)in the degradation of pollutants, which include easily oxidization, accumulation and low reactivity, montmorillonite supported nanoscale Ni-Fe (Ni-Fe/mont)etc. were prepared and characterized. Influencing factors in the degradation of decabromodiphenyl ether (BDE-209) were investigated, which include the concentration of BDE-209 or nZVI, temperature, initial pH of solution, and ultrasounic assistance. The BDE-209 degradation efficiencies of nZVI and modified nZVI were compared. The reaction mechanisms were discussed and reaction kinetic equations were calculated. Results showed that the optimum conditions were 5.0mg/L BDE-209, 2.0g/L catalyst, temperature=35℃ and pH=3. The degradation of BDE-209 was completed within 10min for the ultrasounic treatment, and its observed rate constant (kobs, 0.519min-1)was 40 times faster than the shaking treatment (0.013min-1), and 130 times faster than the static treatment (0.004min-1). At 10min, the BDE-209 degradation rate was followed the order of Ni-Fe/mont (99.5%) > nZVI/mont (85.1%) > nanoscale Ni-Fe (64.8%) > nZVI (48.1%)>mont (4.1%) > nanoscale Ni (1.1%). At 120min, the kobs was followed the order of Ni-Fe/mont (0.519min-1) > nZVI/mont (0.209min-1) > nanoscale Ni-Fe (0.050min-1) > nZVI (0.024min-1). No significant degradation of BDE-209 was found for montmorillonite, nanoscale nickel, or ultrasound in itself.

Key words: nanoparticles, zero valent iron (ZVI), reduction, degradation, decabromodiphenyl ether (BDE-209)

摘要: 为解决传统纳米零价铁(nZVI)降解污染物时易氧化团聚、反应活性低的问题,通过改性手段制备并表征了蒙脱石搭载纳米Ni-Fe(Ni-Fe/蒙脱石)等复合材料,考察污染物和纳米材料质量浓度、温度、溶液初始pH、超声辅助等对其降解十溴二苯醚(BDE-209)的影响,比较nZVI改性前后的降解效果,分析其机理并建立了反应动力学方程。结果表明:最佳反应条件为5mg/L的BDE-209、2g/L的nZVI、温度35℃、pH=3。超声处理10min时BDE-209基本降解完,其表观速率常数(kobs,0.519min-1)是震荡处理(0.013min-1)的40倍、静置处理(0.004min-1)的130倍。几种材料在10min时对BDE-209的降解率为:Ni-Fe/蒙脱石(99.5%) > nZVI/蒙脱石(85.1%) > 纳米Ni-Fe(64.8%) > nZVI(48.1%) > 蒙脱石(4.1%) > 纳米Ni(1.1%),120min时kobs为:Ni-Fe/蒙脱石(0.519min-1) > nZVI/蒙脱石(0.209min-1) > 纳米Ni-Fe(0.050min-1) > nZVI(0.024min-1)。蒙脱石、纳米Ni及超声本身基本不降解BDE-209。

关键词: 纳米粒子, 零价铁, 还原, 降解, 十溴二苯醚

CLC Number: 

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