Progress of non-hydrodesulfurization technologies of producing clean fuels and pre-desulfurization of crude oil

Chemical Industry and Engineering Progree

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Progress of non-hydrodesulfurization technologies of producing clean fuels and pre-desulfurization of crude oil

ZHENG Kaiyuan 1，QU Fengjiao 1，CHEN Yingjie2，LIU Dong 1，LI Wen 3，ZOU Jinglun 4，HOU Xulian 1

1State Key Laboratory of Heavy Oil，School of Chemical Engineering，China University of Petroleum（East China），Qingdao 266555，Shandong，China；2Product Quality Supervision and Inspection Department of Linyi，Linyi 276007，Shangdong，China；3PetroChina Xinjiang Oilfield Company，Karamay 83400，Xingjiang，China；4China Petroleum & Chemical Corporation Shengli Oilfield Technology Testing Center，Dongying 257000，Shandong，China

Online:2013-12-05 Published:2013-12-05

非加氢脱硫技术研究进展及其在原油预脱硫中的应用展望

郑凯元1，曲凤娇1，陈英杰2，刘东1，李雯3，邹京伦4，侯绪连1

1中国石油大学（华东）化学工程学院重质油国家重点实验室，山东青岛 266555；2临沂市产品质量监督检验所，山东临沂 276007；3中国石油新疆油田公司，新疆克拉玛依 834000；4中国石油化工股份有限公司胜利油田分公司技术检测中心，山东东营 257000

Abstract

Abstract: Research progress of several non-hydrodesulfurization technologies and processes of crude oil pre-desulfurization were reviewed. For light distillates，the non-hydrodesulfurization technologies including oxidative desulfurization，adsorptive desulfurization，solvent extraction desulfurization，extraction desulfurization and membrane separation desulfurization were introduced，and the characteristics and desulfurization effects of these non-hydrodesulfurization technologies were summarized. For crude oil，the desulfurization technologies of physical method，ultrasonic-oxidation method，electrochemical method and microorganism method were introduced. The non- hydrodesulfurization technologies with low energy consumption and mild operating conditions would be the trend of deep desulfurization，and comprehensive utilization of non-hydrodesulfurization technologies for crude oil pre-desulfurization would be an important research orientation.

Key words: non-hydrodesulfurization, oxidation, adsorption, crude oil

摘要： 综述了目前轻质油品非加氢脱硫以及原油预脱硫的相关技术，关于轻质油品非加氢脱硫技术详细叙述了氧化脱硫、吸附脱硫和溶剂萃取脱硫等技术的研究进展，简要介绍了络合脱硫、膜分离脱硫等技术，阐述了各非加氢脱硫技术的特点及脱硫效果；针对原油预脱硫技术，主要介绍了物理法原油预脱硫、超声-氧化法原油预脱硫、电化学法原油预脱硫以及微生物法原油预脱硫等技术的研究进展，指出应用能耗低、操作条件温和、脱硫效果好的非加氢脱硫手段是未来的发展趋势，同时指出综合应用非加氢脱硫技术对原油进行预脱硫处理将是未来重要的研究方向。

关键词: 非加氢脱硫, 氧化, 吸附, 原油

ZHENG Kaiyuan 1，QU Fengjiao 1，CHEN Yingjie2，LIU Dong 1，LI Wen 3，ZOU Jinglun 4，HOU Xulian 1. Progress of non-hydrodesulfurization technologies of producing clean fuels and pre-desulfurization of crude oil[J]. Chemical Industry and Engineering Progree.

郑凯元1，曲凤娇1，陈英杰2，刘东1，李雯3，邹京伦4，侯绪连1. 非加氢脱硫技术研究进展及其在原油预脱硫中的应用展望[J]. 化工进展.

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Progress of non-hydrodesulfurization technologies of producing clean fuels and pre-desulfurization of crude oil

非加氢脱硫技术研究进展及其在原油预脱硫中的应用展望

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