Apparent viscosity behavior of potassium erucic/three hydroxyethyl benzyl ammonium chloride wormlike micelles

doi:10.16085/j.issn.1000-6613.2015.11.027

Abstract

Abstract: The wormlike micelles were prepared by self-assembled with anionic surfactant Potassium erucic(KEU) and organic counterion three hydroxyethyl benzyl ammonium chloride(BTHEAC). Styrene and twin tail hydrophobic monomer N, N-twin tails substituted acrylamides(DiC_nAM) as monomers. 2, 2'-Azobis[2-(2-imidazolin-2-yl)propane] dihydrochloride (VA-044) acted as initiators. The new wormlike micelles, solubilized and polymerized, were synthesized at a certain temperature. The properties of wormlike micelles were measured by viscometer. The results showed that the wormlike micelles added with monomers and polymerized, the concentration of styrene was 0.02mol/L, the molar ratio of n(KEU):n(BTHEAC)=5:3, n(styrene):n(DiC₈AM)=5:2, the best apparent viscosity of the wormlike micelles was obtained, which is 1320mPa·s, higher than the apparent viscosity of KEU/BTHEAC wormlike micelles, and it was also good at high temperature.

Key words: surfactants, wormlike micelles, apparent viscosity

摘要： 以阴离子表面活性剂芥酸钾(KEU)与有机反离子三羟乙基苄基氯化铵(BTHEAC)通过自组装形成的蠕虫状胶束为主要研究对象,苯乙烯与N,N-孪尾取代丙烯酰胺(DiC_nAM)为可聚合单体,偶氮二异丙基咪唑啉盐酸盐(VA-044)为引发剂,在一定温度下,合成了系列增溶单体并聚合的蠕虫状胶束,通过黏度法研究了该合成条件对蠕虫状胶束表观黏度的影响。结果表明,当单体增溶并聚合后,蠕虫状胶束表观黏度显著增大。当苯乙烯的浓度为0.02mol/L、摩尔比n(KEU):n(BTHEAC)=5:3、n(苯乙烯):n(DiC₈AM)=5:2时,合成的蠕虫状胶束表观黏度最大,为1320mPa·s,明显大于KEU/BTHEAC蠕虫状胶束的表观黏度,且耐温性能良好。

关键词: 表面活性剂, 蠕虫状胶束, 表观黏度

CLC Number:

TQ423.1

LI Ni, ZHANG Rui. Apparent viscosity behavior of potassium erucic/three hydroxyethyl benzyl ammonium chloride wormlike micelles[J]. Chemical Industry and Engineering Progree, 2015, 34(11): 3995-4000.

李妮, 张蕊. 芥酸钾/三羟乙基苄基氯化铵蠕虫状胶束的黏度行为[J]. 化工进展, 2015, 34(11): 3995-4000.

References

[1] 赵剑曦,谢丹华. 阴离子蠕虫状胶束[J]. 化学进展,2012,24(4):456-462

[2] 卢拥军,方波,房鼎业. 粘弹性胶束压裂液的形成与流变性质[J]. 油田化学,2003,20(4):327-330.

[3] 李钦,陈馥. 黏弹性表面活性剂及其在油田中的应用[J]. 日用化学工业,2004,34(3):173-175.

[4] 隋智慧,林冠发,朱友益,等. 三次采油用表面活性剂的制备、应用及进展[J]. 化工进展,2003,22(4):355-360.

[5] 任杰,范晓东. 蠕虫状胶束的形成及其油田应用[J]. 材料导报:综述篇,2010,24(12):60-63.

[6] Marcelo Calderon,Manuel I Velasco,Miriam C Strumia. Synthesis of amphiphilic dendrons and their interactions in aqueous solutions with cetyltrimethylammonium p-toluenesulfonate (CTAT)[J]. Journal of Colloid and Interface Science,2009,336:462-469.

[7] 庞明君,魏进家,王剑峰,等. 提高表面活性剂减阻溶液传热研究进展[J]. 化工进展,2009,28(10):1693-1700.

[8] 杨翠英,主曦曦,姚旭阳. 表面活性剂分子有序组合体研究动态[J]. 山东科技大学学报,2011,30(3):66-71.

[9] Sharma S C,Shrestha L K,Tsuchiya K,et al. Viscoelastic wormlike micelles of long polyoxyethylene chain phytosterol with lipophilic nonionic surfactant in aqueous solution[J]. Journal of Physical Chemistry B,2009,113(10):3043-3050.

[10] Zhu Zhiyuan,Gonzalez Y I,Xu Hangxun,et al. Polymerization of anionic wormlike micelles[J]. Langmuir,2006,22:949-955.

[11] Eecerra F,Soltero J F A,Puig J E,et al. Free-radical polymerization of styrene in worm-like micelles[J]. Colloid and Polymer Science,2003,282(2):282.

[12] 姚峰,朱霞. SN7－33井表面活性剂驱油研究与应用[J]. 复杂油气藏,2014,7(1):73-76.

[13] 王治国,王树众,孙晓,等. OTAC/NaSal 蠕虫状胶束流体微观结构与线性黏弹性[J]. 力学学报,2013,45(6):854-860.

[14] 江路明,宋昭铮,檀国荣,等. 表面活性剂复配在三次采油中的应用进展[J]. 广州化工,2014,42(3):9-11.

[15] 张鑫淼,张佳伟,魏光耀,等. 蠕虫状聚离子复合型胶束的合成、组装和胶体稳定性[J]. 高等学校化学学报,2012,33(9):2085-2091.

[16] 李化真,杨海洋,周珊,等. 黏度法研究非离子型高分子对盐水溶液中油酸钾聚集行为的影响[J]. 高分子材料科学与工程,2012,28(1):56-59.

[17] 张为灿,李干佐,牟建海,等. 十六烷基三甲基溴化铵蠕虫状胶束的形成及其性质[J]. 科学通报,2000,45(11):1138-1141.

[18] 林微,陈光进,吴志恺. 表面活性剂促进乙烯水合物的生成[J]. 化工进展,2003,22(s1):278-281.

[19] 吴文辉,王建全,耿同谋. 全国功能高分子行业委员会第九届年会论文集[C]//成都:中国精细化工协会,2006.

[20] 吴文辉,王建全,耿同谋. N,N-孪尾长链烷基取代丙烯酰胺疏水缔合水溶性共聚物[C]//全国功能高分子行业委员会第九届年会论文集,2007.

[21] 穆瑞花,吴文辉. 阳离子三联表面活性剂/NaSS/S_t蠕虫状胶束及性能[J]. 化工学报,2013,64(11):4161-4166.