Promotion of HCFC-141b hydrate production by lactone sophorolipids

doi:10.16085/j.issn.1000-6613.2023-0333

Abstract

Abstract:

Cold storage air conditioning is an important method to reduce peak-valley difference of power grid and realize peak regulation of the load side of power grid. Refrigerant hydrate as a cold storage medium has the advantages of high cold storage density and high phase change temperature. HCFC-141b refrigerant is a potential cold storage medium. In order to promote the formation of HCFC-141b refrigerant hydrate, the green environmental sophorid glycolipid was selected as a promoter to improve HCFC-141b hydrate formation. The experimental results showed that the addition of lactone sophorolipids could greatly shorten the induction time of HCFC-141b hydrate formation. The mass fraction of sophora sophorolipid affects the nucleation and growth process of hydrate. 0.5% was the optimal concentration of lactone sophorolipid to improve hydrate formation, where the average induction time of HCFC-141b hydrate formation was the shortest (about 153min). Experimental results also showed that hydrate formation is random. The addition of lactone sophorolipids could reduce the randomness of hydrate production. The standard deviation of induction time of hydrate formation with 0.5% lactone sophorolipids was smallest in this work, which showed the system with 0.5% lactone sophorolipids could steadily nucleate. The addition of lactone sophorolipids would affect the cold storage capacity of HCFC-141b hydrate. When 0.5% lactone sophorolipids were added, the average cold storage capacity of HCFC-141b hydrate reached 232.45kJ/kg.

Key words: hydrate, surfactant, kinetics, refrigerant, cold storage, lactone type sophorolipid

摘要：

蓄冷空调是降低电网峰谷差、实现电网负载侧调峰的一种重要手段，制冷剂水合物作为蓄冷介质具有蓄冷密度大和相变温度高的优点。HCFC-141b制冷剂是一种潜在的蓄冷物质，为了促进HCFC-141b制冷剂水合物的生成，实验研究了绿色环保表面活性剂槐糖脂对HCFC-141b水合物生成的影响。研究结果表明，添加适量的内酯型槐糖脂可大幅度缩短HCFC-141b水合物形成的诱导时间。槐糖脂的添加量影响水合物的成核和生长过程，质量分数为0.5%是内酯型槐糖脂的最佳浓度，促进HCFC-141b水合物生成的平均诱导时间最短，约为153min。实验结果还表明水合物的生成具有随机性，添加内酯型槐糖脂可以改善水合物生成的随机性，0.5%（质量分数）的内酯型槐糖脂的诱导时间标准方差最小，水合物成核稳定性最好。内酯型槐糖脂的添加也影响HCFC-141b水合物的蓄冷量，当添加0.5%（质量分数）的内酯型槐糖脂时，HCFC-141b水合物的平均蓄冷量达到232.45kJ/kg。

关键词: 水合物, 表面活性剂, 动力学, 制冷剂, 蓄冷, 内酯型槐糖脂

CLC Number:

TK 02

HUANG Meng, SUN Zhigao, XU Wenchao, ZHANG Huanran, YANG Yang. Promotion of HCFC-141b hydrate production by lactone sophorolipids[J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1199-1205.

黄梦, 孙志高, 徐文超, 张焕然, 杨扬. 内酯型槐糖脂促进HCFC-141b水合物生成[J]. 化工进展, 2024, 43(3): 1199-1205.

Figures/Tables 10

References 23

1	刘子初, 全贞花, 赵耀华, 等. 新型微通道平板热管蓄冰性能[J]. 化工学报, 2020, 71(S1): 120-128.
	LIU Zichu, QUAN Zhenhua, ZHAO Yaohua, et al. Characteristics of ice storage based on new type of flat micro heat pipe arrays[J]. CIESC Journal, 2020, 71(S1): 120-128.
2	林酿志, 李传常. 相变储能材料及其冷链运输应用[J]. 储能科学与技术, 2021, 10(3): 1040-1050.
	LIN Niangzhi, LI Chuanchang. Phase change materials for energy storage in cold-chain transportation[J]. Energy Storage Science and Technology, 2021, 10(3): 1040-1050.
3	姬利明, 祁影霞, 欧阳新萍. 制冷剂气体水合物用于蓄冷空调中的探讨[J]. 低温与超导, 2010, 38(11): 58-62.
	JI Liming, QI Yingxia, OUYANG Xinping. Exploration of refrigerant gas hydrate used as cool storage media in air conditioning[J]. Cryogenics and Superconductivity, 2010, 38(11): 58-62.
4	陈俊, 陈秋雄, 陈运文, 等. 水合物储能技术研究现状[J]. 储能科学与技术, 2015, 4(2): 131-140.
	CHEN Jun, CHEN Qiuxiong, CHEN Yunwen, et al. Current status of energy storage using hydrates[J]. Energy Storage Science and Technology, 2015, 4(2): 131-140.
5	PARK Sung Seek, KIM Nam Jin. Study on methane hydrate formation using ultrasonic waves[J]. Journal of Industrial and Engineering Chemistry, 2013, 19(5): 1668-1672.
6	LI Airong, JIANG Lele, TANG Siyao. An experimental study on carbon dioxide hydrate formation using a gas-inducing agitated reactor[J]. Energy, 2017, 134: 629-637.
7	RAJABI FIROOZABADI Solmaz, BONYADI Mohammad. A comparative study on the effects of Fe₃O₄ nanofluid, SDS and CTAB aqueous solutions on the CO₂ hydrate formation[J]. Journal of Molecular Liquids, 2020, 300: 112251.
8	孙贤, 刘德俊. 二氧化碳水合物动力学促进剂研究进展[J]. 化工进展, 2018, 37(2): 517-524.
	SUN Xian, LIU Dejun. Advances in carbon dioxide hydrate kinetic additives[J]. Chemical Industry and Engineering Progress, 2018, 37(2): 517-524.
9	夏心良. 蓄冷用制冷剂水合物生成的协同促进技术研究[D]. 苏州: 苏州科技大学, 2022.
	XIA Xinliang. Study on synergistic promotion technology of hydrate formation of refrigerant for cold storage[D]. Suzhou: Suzhou University of Science and Technology, 2022.
10	SUN Zhigao, JIAO Lijun, ZHAO Zhigui, et al. Phase equilibrium conditions of semi-calthrate hydrates of (tetra-n-butyl ammonium chloride+carbon dioxide)[J]. The Journal of Chemical Thermodynamics, 2014, 118(75): 116-118.
11	ZHENG Jianan, YANG Mingjun, LIU Yu, et al. Effects of cyclopentane on CO₂ hydrate formation and dissociation as a co-guest molecule for desalination[J]. The Journal of Chemical Thermodynamics, 2017, 104: 9-15.
12	HONG Sujin, MOON Seokyoon, LEE Yunseok, et al. Investigation of thermodynamic and kinetic effects of cyclopentane derivatives on CO₂ hydrates for potential application to seawater desalination[J]. Chemical Engineering Journal, 2019, 363: 99-106.
13	YANG Mingjun, SONG Yongchen, LIU Weiguo, et al. Effects of additive mixtures (THF/SDS) on carbon dioxide hydrate formation and dissociation in porous media[J]. Chemical Engineering Science, 2013, 90(1): 69-76.
14	孟汉林, 郭荣波, 王飞, 等. 不同表面活性剂对甲烷水合物生成的影响[J]. 可再生能源, 2017, 35(3): 329-336.
	MENG Hanlin, GUO Rongbo, WANG Fei, et al. Effect of different surfactants on methane hydrate formation[J]. Renewable Energy Resources, 2017, 35(3): 329-336.
15	吴虹, 汪薇, 韩双艳. 鼠李糖脂生物表面活性剂的研究进展[J]. 微生物学通报, 2007, 34(1): 148-152.
	WU Hong, WANG Wei, HAN Shuangyan. Recent progress on rhamnolipid biosurfactant[J]. Microbiology China, 2007, 34(1): 148-152.
16	李荣, 孙志高, 宋佳. 静态条件下氨基酸对HCFC-141b水合物生成的促进[J]. 低温工程, 2021(4): 59-64.
	LI Rong, SUN Zhigao, SONG Jia. Study on HCFC-141b hydrate formation promoted by amino acids in quiescent conditions[J]. Cryogenics, 2021(4): 59-64.
17	FAKHARIAN H, GANJI H, NADERI FAR A, et al. Potato starch as methane hydrate promoter[J]. Fuel, 2012, 94(1): 356-360.
18	王树立, 代文杰, 刘墨夫, 等. 鼠李糖脂促进CO₂水合物生成实验[J]. 常州大学学报(自然科学版), 2017, 29(4): 66-72.
	WANG Shuli, DAI Wenjie, LIU Mofu, et al. Experimental research on CO₂ hydrate formation promoted by rrhamnolipid[J]. Journal of Changzhou University (Natural Science Edition), 2017, 29(4): 66-72.
19	张龙明, 李璞, 李娜, 等. 混合量热法测定水合物浆体蓄冷密度[J]. 制冷学报, 2014, 35(6): 47-52.
	ZHANG Longming, LI Pu, LI Na, et al. Determination of hydrate slurry's cool-storage density with mixing calorimetry method[J]. Journal of Refrigeration, 2014, 35(6): 47-52.
20	敬加强, 杨航, 张帅, 等. 水合物生成诱导期研究进展[J]. 天然气化工—C1化学与化工, 2021, 46(6): 24-32.
	JING Jiaqiang, YANG Hang, ZHANG Shuai, et al. Research progress of hydrate formation induction period[J]. Natural Gas Chemical Industry, 2021, 46(6): 24-32.
21	闫明月, 王岳, 刘嘉琪, 等. 表面活性剂对甲烷水合物生成影响研究进展[J]. 应用化工, 2021, 50(8): 2317-2325.
	YAN Mingyue, WANG Yue, LIU Jiaqi, et al. Research progress on influence factors of methane hydrate formation in surfactant solution[J]. Applied Chemical Industry, 2021, 50(8): 2317-2325.
22	ANDO Naoki, KUWABARA Yui, MORI Yasuhiko H. Surfactant effects on hydrate formation in an unstirred gas/liquid system: An experimental study using methane and micelle-forming surfactants[J]. Chemical Engineering Science, 2012, 73(1): 79-85.
23	WANG Fei, GUO Gang, LIU Guoqiang, et al. Effects of surfactant micelles and surfactant-coated nanospheres on methane hydrate growth pattern[J]. Chemical Engineering Science, 2016,144: 108-115.

内酯型质量分数/%	诱导时间/min	平均诱导时间/min	诱导时间方差	形成持续时间/min	平均持续时间/min
0.3	143,133,189,218,349	206	77	40,43,38,40,37	39
0.5	172,112,155,122,206	153	34	37,41,42,50,39	41
1.0	248,324,515,430,331	369	92	38,41,39,40,40	39
2.0	378,384,435,446,559	440	65	36,35,38,38,41	37

内酯型质量分数/%	诱导时间/min	平均诱导时间/min	诱导时间方差	形成持续时间/min	平均持续时间/min
0.3	143,133,189,218,349	206	77	40,43,38,40,37	39
0.5	172,112,155,122,206	153	34	37,41,42,50,39	41
1.0	248,324,515,430,331	369	92	38,41,39,40,40	39
2.0	378,384,435,446,559	440	65	36,35,38,38,41	37

项目	0.3%	0.5%	1.0%	2.0%
1	197.70	224.39	186.12	171.26
2	192.96	235.55	187.64	174.29
3	181.47	237.42	185.95	177.29
平均蓄冷量	189.04	232.45	186.57	174.28

项目	0.3%	0.5%	1.0%	2.0%
1	197.70	224.39	186.12	171.26
2	192.96	235.55	187.64	174.29
3	181.47	237.42	185.95	177.29
平均蓄冷量	189.04	232.45	186.57	174.28

[1]	GU Hailin, CHEN Binkang, GUO Jiaqi, FENG Jie, JIAN Qingshan, WANG Jinqing, ZHANG Guangxue. Atomization characteristics of surfactant-containing solutions and enhanced removal of fine particulate matter [J]. Chemical Industry and Engineering Progress, 2024, 43(2): 865-871.
[2]	GU Yongzheng, ZHANG Yongsheng. Dynamic behavior and kinetic model of Hg⁰ adsorption by HBr-modified fly ash [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 498-509.
[3]	WANG Peng, ZHANG Yang, FAN Bingqiang, HE Dengbo, SHEN Changshuai, ZHANG Hedong, ZHENG Shili, ZOU Xing. Process and kinetics of hydrochloric acid leaching of high-carbon ferrochromium [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 510-517.
[4]	ZHAO Jingchao, TAN Ming. Effect of surfactants on the reduction of industrial saline wastewater by electrodialysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 529-535.
[5]	WANG Jinhang, HE Yong, SHI Lingli, LONG Zhen, LIANG Deqing. Progress of gas hydrate anti-agglomerants [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4587-4602.
[6]	LI You, WU Yue, ZHONG Yu, LIN Qixuan, REN Junli. Pretreatment of wheat straw with acidic molten salt hydrate for xylose production and its effect on enzymatic hydrolysis efficiency [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4974-4983.
[7]	YIN Xinyu, PI Pihui, WEN Xiufang, QIAN Yu. Application of special wettability materials for anti-hydrate-nucleation and anti-hydrate-adhesion in oil and gas pipelines [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4076-4092.
[8]	WANG Junjie, PAN Yanqiu, NIU Yabin, YU Lu. Molecular level catalytic reforming model construction and application [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3404-3412.
[9]	ZHANG Kai, LYU Qiunan, LI Gang, LI Xiaosen, MO Jiamei. Morphology and occurrence characteristics of methane hydrates in the mud of the South China Sea [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3865-3874.
[10]	YANG Yang, SUN Zhigao, LI Cuimin, LI Juan, HUANG Haifeng. Promotion on the formation of HCFC-141b hydrate under static conditions by surfactant OP-13 [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2854-2859.
[11]	LIU Jia, LIANG Deqing, LI Junhui, LIN Decai, WU Siting, LU Fuqin. A review of flow assurance studies on hydrate slurry in oil-water system [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1739-1759.
[12]	GE Weitong, LIAO Yalong, LI Mingyuan, JI Guangxiong, XI Jiajun. Preparation and dechlorination kinetics of Pd-Fe/MWCNTs bimetallic catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1885-1894.
[13]	YANG Zhuang, LI Runhua, QIANG Zengshou, WANG Yajun, YAO Wenqing. Photocatalytic degradation of waste refrigerant R134a [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 2109-2114.
[14]	LI Yun, CUI Nan, XIONG Xingxing, HUANG Zhiyuan, WANG Dongliang, XU Dan, LI Jun, LI Zebing. Influence of rare earth element Er(Ⅲ) on performance of short-cut nitrification and its inhibition kinetics [J]. Chemical Industry and Engineering Progress, 2023, 42(3): 1659-1668.
[15]	WANG Wei, ZHANG Dongxu, LI Zunzhao, WANG Xiaolin, HUANG Qiyu. Research progress on the growth behavior of hydrates in water-in-oil emulsion systems [J]. Chemical Industry and Engineering Progress, 2023, 42(3): 1155-1166.