Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (9): 4677-4691.DOI: 10.16085/j.issn.1000-6613.2022-2004
• Industrial catalysis • Previous Articles Next Articles
ZHANG Qi(), ZHAO Hong, RONG Junfeng()
Received:
2022-10-27
Revised:
2023-01-20
Online:
2023-09-28
Published:
2023-09-15
Contact:
RONG Junfeng
通讯作者:
荣峻峰
作者简介:
张启(1998—),男,硕士研究生,研究方向为氢燃料电池。E-mail:andy1106@vip.qq.com。
基金资助:
CLC Number:
ZHANG Qi, ZHAO Hong, RONG Junfeng. Research progress of anti-toxicity electrocatalysts for oxygen reduction reaction in PEMFC[J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4677-4691.
张启, 赵红, 荣峻峰. 质子交换膜燃料电池中氧还原反应抗毒性电催化剂研究进展[J]. 化工进展, 2023, 42(9): 4677-4691.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2004
污染物 | 浓度/mg·m-3 | 最大电流降/% | 最小电流降/% | 平均电流降/% |
---|---|---|---|---|
SO2 | 0.286 | 6 | 0 | 2 |
2.86 | 88 | 53 | 62 | |
11.44 | 95 | 67 | 85 | |
NO2 | 2.05 | 13 | 1 | 4 |
20.50 | 91 | 31 | 66 | |
30.75 | 95 | 42 | 69 | |
NO | 1.34 | 63 | 11 | 33 |
13.40 | 96 | 36 | 67 | |
20.10 | 97 | 43 | 72 | |
NH3 | 0.759 | 4 | 0 | 1 |
2.28 | 34 | 0 | 9 | |
6.072 | 75 | 30 | 51 |
污染物 | 浓度/mg·m-3 | 最大电流降/% | 最小电流降/% | 平均电流降/% |
---|---|---|---|---|
SO2 | 0.286 | 6 | 0 | 2 |
2.86 | 88 | 53 | 62 | |
11.44 | 95 | 67 | 85 | |
NO2 | 2.05 | 13 | 1 | 4 |
20.50 | 91 | 31 | 66 | |
30.75 | 95 | 42 | 69 | |
NO | 1.34 | 63 | 11 | 33 |
13.40 | 96 | 36 | 67 | |
20.10 | 97 | 43 | 72 | |
NH3 | 0.759 | 4 | 0 | 1 |
2.28 | 34 | 0 | 9 | |
6.072 | 75 | 30 | 51 |
结构 | 吸附能 /kJ·mol-1 | 距离/nm | ||
---|---|---|---|---|
S/Pt(111) | -604.0 | 0.2310 | 0.2311 | 0.2312 |
S/PtMo(111) | -466.8 | 0.2353 | 0.2355 | 0.2354(S—Mo) |
SO3/Pt(111) | -282.8 | 0.2291 | 0.2153(O—Pt) | 0.2160(O—Pt) |
SO3/PtMo(111) | -114.6 | 0.2222 | 0.2130(O—Pt) | 0.1964(O—Mo) |
结构 | 吸附能 /kJ·mol-1 | 距离/nm | ||
---|---|---|---|---|
S/Pt(111) | -604.0 | 0.2310 | 0.2311 | 0.2312 |
S/PtMo(111) | -466.8 | 0.2353 | 0.2355 | 0.2354(S—Mo) |
SO3/Pt(111) | -282.8 | 0.2291 | 0.2153(O—Pt) | 0.2160(O—Pt) |
SO3/PtMo(111) | -114.6 | 0.2222 | 0.2130(O—Pt) | 0.1964(O—Mo) |
毒化物浓度 /mol·L-1 | Pt/C | 5% WO x -Pt/C | ||
---|---|---|---|---|
初始覆盖率 | 损失程度/% | 初始覆盖率 | 损失程度/% | |
0.001 | 0.50±0.04 | 37±2 | 0.53±0.0.4 | 45±2 |
0.01 | 0.84±0.06 | 45±3 | 0.85±0.05 | 50±2 |
0.1 | 1.00±0.07 | 43±3 | 1.00±0.06 | 47±3 |
毒化物浓度 /mol·L-1 | Pt/C | 5% WO x -Pt/C | ||
---|---|---|---|---|
初始覆盖率 | 损失程度/% | 初始覆盖率 | 损失程度/% | |
0.001 | 0.50±0.04 | 37±2 | 0.53±0.0.4 | 45±2 |
0.01 | 0.84±0.06 | 45±3 | 0.85±0.05 | 50±2 |
0.1 | 1.00±0.07 | 43±3 | 1.00±0.06 | 47±3 |
吸附物 | 吸附能/eV | ||
---|---|---|---|
Fe-N4 | Fe-N2C2 | N掺杂石墨烯 | |
O2 | -1.01 | -2.34 | -0.15 |
SO2 | -0.81 | -1.63 | -0.17 |
NO | -1.97 | -3.37 | -0.09 |
NO2 | -1.45 | -2.63 | -0.43 |
CO | -1.61 | -2.09 | -0.01 |
吸附物 | 吸附能/eV | ||
---|---|---|---|
Fe-N4 | Fe-N2C2 | N掺杂石墨烯 | |
O2 | -1.01 | -2.34 | -0.15 |
SO2 | -0.81 | -1.63 | -0.17 |
NO | -1.97 | -3.37 | -0.09 |
NO2 | -1.45 | -2.63 | -0.43 |
CO | -1.61 | -2.09 | -0.01 |
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