Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (6): 3123-3129.DOI: 10.16085/j.issn.1000-6613.2022-1410
• Materials science and technology • Previous Articles Next Articles
YANG Xuzhao(), LI Qing, YUAN Kangkang, ZHANG Yingying, HAN Jingli, WU Shide
Received:
2022-07-27
Revised:
2022-09-23
Online:
2023-06-29
Published:
2023-06-25
Contact:
YANG Xuzhao
通讯作者:
杨许召
作者简介:
杨许召(1978—),男,博士,副教授,主要研究方向为化学工艺、精细化工。E-mail: yangxz@zzuli.edu.cn。
基金资助:
CLC Number:
YANG Xuzhao, LI Qing, YUAN Kangkang, ZHANG Yingying, HAN Jingli, WU Shide. Thermodynamic properties of Gemini ionic liquid based deep eutectic solvents[J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3123-3129.
杨许召, 李庆, 袁康康, 张盈盈, 韩敬莉, 吴诗德. 含Gemini离子液体低共熔溶剂热力学性质[J]. 化工进展, 2023, 42(6): 3123-3129.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-1410
热力学性质 | 实验值 | 文献值 | 相对误差/% | T/K |
---|---|---|---|---|
ρ/g·mL-1 | 1.1162 | 1.11676[ | -0.050 | 288.15 |
1.1021 | 1.1030[ | -0.082、-0.075、0.018、-0.056 | 308.15 | |
1.0986 | 1.0999[ | -0.118、0.457、-0.055 | 313.15 | |
1.0949 | 1.0978[ | -0.264、-0.055、-0.068 | 318.15 | |
1.0906 | 1.09105[ | -0.0412、-0.130、0.544 | 323.15 | |
η/mPa·s | 26.0965 | 26.343[ | -0.936 | 288.15 |
10.0952 | 9.2122[ | 9.585、-3.598、-10.153 | 308.15 | |
8.6371 | 7.9605[ | 8.499、-8.155 | 313.15 | |
6.8190 | 6.2933[ | 8.353、-14.172、-16.084 | 318.15 | |
6.4921 | 6.992[ | -7.150、-6.359、-4.161、19.191 | 323.15 | |
κ/μS·m-1 | 0.413 | 0.400[ | 3.250 | 303.15 |
0.516 | 0.502[ | 2.789 | 313.15 | |
0.609 | 0.600[ | 1.500 | 323.15 | |
cp /J·g-1·K-1 | 2.3462 | 2.3533[ | -0.302、-1.1254 | 293.15 |
2.3891 | 2.3826[ | 0.273、-0.130 | 298.15 | |
2.4286 | 2.4160[ | 0.522、0.688、1.445 | 303.15 | |
2.5671 | 2.478[ | 3.596 | 323.15 |
热力学性质 | 实验值 | 文献值 | 相对误差/% | T/K |
---|---|---|---|---|
ρ/g·mL-1 | 1.1162 | 1.11676[ | -0.050 | 288.15 |
1.1021 | 1.1030[ | -0.082、-0.075、0.018、-0.056 | 308.15 | |
1.0986 | 1.0999[ | -0.118、0.457、-0.055 | 313.15 | |
1.0949 | 1.0978[ | -0.264、-0.055、-0.068 | 318.15 | |
1.0906 | 1.09105[ | -0.0412、-0.130、0.544 | 323.15 | |
η/mPa·s | 26.0965 | 26.343[ | -0.936 | 288.15 |
10.0952 | 9.2122[ | 9.585、-3.598、-10.153 | 308.15 | |
8.6371 | 7.9605[ | 8.499、-8.155 | 313.15 | |
6.8190 | 6.2933[ | 8.353、-14.172、-16.084 | 318.15 | |
6.4921 | 6.992[ | -7.150、-6.359、-4.161、19.191 | 323.15 | |
κ/μS·m-1 | 0.413 | 0.400[ | 3.250 | 303.15 |
0.516 | 0.502[ | 2.789 | 313.15 | |
0.609 | 0.600[ | 1.500 | 323.15 | |
cp /J·g-1·K-1 | 2.3462 | 2.3533[ | -0.302、-1.1254 | 293.15 |
2.3891 | 2.3826[ | 0.273、-0.130 | 298.15 | |
2.4286 | 2.4160[ | 0.522、0.688、1.445 | 303.15 | |
2.5671 | 2.478[ | 3.596 | 323.15 |
溶剂 | 熔点/℃ |
---|---|
C3(MIM)2Br2 | 171[ |
乙二醇 | -13[ |
DES1 | -98 |
DES2 | -108 |
DES3 | -110 |
DES4 | -114 |
溶剂 | 熔点/℃ |
---|---|
C3(MIM)2Br2 | 171[ |
乙二醇 | -13[ |
DES1 | -98 |
DES2 | -108 |
DES3 | -110 |
DES4 | -114 |
热力学性质 | 溶剂 | A | B | R2 | σ |
---|---|---|---|---|---|
密度 | DES1 | 1.57066 | -6.78488×10-4 | 0.99997 | 0.00011 |
DES2 | 1.53140 | -6.82138×10-4 | 0.99998 | 0.00011 | |
DES3 | 1.51577 | -6.82252×10-4 | 0.99999 | 0.00011 | |
DSE4 | 1.48676 | -6.83652×10-4 | 0.99998 | 0.00009 | |
比热容 | DES1 | 0.95372 | 0.00308 | 0.99766 | 0.0025 |
DES2 | 0.55713 | 0.00531 | 0.99847 | 0.0034 | |
DES3 | 0.01762 | 0.0078 | 0.99858 | 0.0048 | |
DES4 | -0.51295 | 0.01004 | 0.99900 | 0.0051 |
热力学性质 | 溶剂 | A | B | R2 | σ |
---|---|---|---|---|---|
密度 | DES1 | 1.57066 | -6.78488×10-4 | 0.99997 | 0.00011 |
DES2 | 1.53140 | -6.82138×10-4 | 0.99998 | 0.00011 | |
DES3 | 1.51577 | -6.82252×10-4 | 0.99999 | 0.00011 | |
DSE4 | 1.48676 | -6.83652×10-4 | 0.99998 | 0.00009 | |
比热容 | DES1 | 0.95372 | 0.00308 | 0.99766 | 0.0025 |
DES2 | 0.55713 | 0.00531 | 0.99847 | 0.0034 | |
DES3 | 0.01762 | 0.0078 | 0.99858 | 0.0048 | |
DES4 | -0.51295 | 0.01004 | 0.99900 | 0.0051 |
热力学性质 | 溶剂 | A | B | T0/K | R2 |
---|---|---|---|---|---|
黏度 | DES1 | -2.08244 | 892.19761 | 170 | 0.99992 |
DES2 | -2.21258 | 850.66318 | 158 | 0.99983 | |
DES3 | -2.14673 | 798.55697 | 163 | 0.99998 | |
DES4 | -2.50824 | 832.22644 | 159 | 1 | |
电导率 | DES1 | 3.16148 | -107.04625 | 249 | 0.99994 |
DES2 | 3.55785 | -166.03872 | 221 | 0.99997 | |
DES3 | 3.70920 | -191.57429 | 210 | 0.99999 | |
DES4 | 3.85660 | -206.90876 | 203 | 0.99995 |
热力学性质 | 溶剂 | A | B | T0/K | R2 |
---|---|---|---|---|---|
黏度 | DES1 | -2.08244 | 892.19761 | 170 | 0.99992 |
DES2 | -2.21258 | 850.66318 | 158 | 0.99983 | |
DES3 | -2.14673 | 798.55697 | 163 | 0.99998 | |
DES4 | -2.50824 | 832.22644 | 159 | 1 | |
电导率 | DES1 | 3.16148 | -107.04625 | 249 | 0.99994 |
DES2 | 3.55785 | -166.03872 | 221 | 0.99997 | |
DES3 | 3.70920 | -191.57429 | 210 | 0.99999 | |
DES4 | 3.85660 | -206.90876 | 203 | 0.99995 |
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