Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (10): 5147-5161.DOI: 10.16085/j.issn.1000-6613.2022-2033
• Industrial catalysis • Previous Articles Next Articles
YUAN Li(), WANG Xueqian(), LI Xiang, WANG Langlang, MA Yixing, NING ping(), XIONG Yiran
Received:
2022-11-01
Revised:
2023-01-31
Online:
2023-11-11
Published:
2023-10-15
Contact:
WANG Xueqian, NING ping
袁礼(), 王学谦(), 李翔, 王郎郎, 马懿星, 宁平(), 熊亦然
通讯作者:
王学谦,宁平
作者简介:
袁礼(1991—),男,博士研究生,研究方向为工业废气净化及资源化。E-mail:634105655@qq.com。
基金资助:
CLC Number:
YUAN Li, WANG Xueqian, LI Xiang, WANG Langlang, MA Yixing, NING ping, XIONG Yiran. Research advances on catalytic removal COS and H2S from by-product gas in iron and steel industry[J]. Chemical Industry and Engineering Progress, 2023, 42(10): 5147-5161.
袁礼, 王学谦, 李翔, 王郎郎, 马懿星, 宁平, 熊亦然. 催化脱除钢铁副产煤气中COS和H2S的研究进展[J]. 化工进展, 2023, 42(10): 5147-5161.
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催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能 (转化率)/% | 穿透容量 /mg·g-1 | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
Pd/γ-Al2O3 | — | — | — | 3000 | 200 | COS:60mg·kg-1 CS2:55mg·kg-1 | 100 | — | [ |
K2CO3-TiO2-γ-Al2O3 | — | 0.63 | 6.24 | 9000 | 300 | COS:2000mg·m-3 | 97 | — | [ |
3D-A(P14.3)-K | 114.7 | 0.264 | 9.2 | 16000 | 70 | COS:800mg·m-3 | 100 | — | [ |
15% Fe2O3 /TiO2 | 61.7 | 0.095 | 6.18 | 6700 | 180 | H2S:2000mg·kg-1 | 96.57 | — | [ |
Fe/TiO2-x -S | 74.6 | 0.31 | 15.9 | 9000 | 210 | H2S:5000mg·kg-1 | 100 | — | [ |
CuO/Al2O3 | 215 | 0.45 | 6.6 | 6100 | 50 | H2S:1521±76mg·m-3 | — | 220.92 | [ |
V2O5/anatase-21 | 63 | 0.24 | 10.4 | 530000 | 200 | H2S:300mg·kg-1 | 100 | — | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能 (转化率)/% | 穿透容量 /mg·g-1 | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
Pd/γ-Al2O3 | — | — | — | 3000 | 200 | COS:60mg·kg-1 CS2:55mg·kg-1 | 100 | — | [ |
K2CO3-TiO2-γ-Al2O3 | — | 0.63 | 6.24 | 9000 | 300 | COS:2000mg·m-3 | 97 | — | [ |
3D-A(P14.3)-K | 114.7 | 0.264 | 9.2 | 16000 | 70 | COS:800mg·m-3 | 100 | — | [ |
15% Fe2O3 /TiO2 | 61.7 | 0.095 | 6.18 | 6700 | 180 | H2S:2000mg·kg-1 | 96.57 | — | [ |
Fe/TiO2-x -S | 74.6 | 0.31 | 15.9 | 9000 | 210 | H2S:5000mg·kg-1 | 100 | — | [ |
CuO/Al2O3 | 215 | 0.45 | 6.6 | 6100 | 50 | H2S:1521±76mg·m-3 | — | 220.92 | [ |
V2O5/anatase-21 | 63 | 0.24 | 10.4 | 530000 | 200 | H2S:300mg·kg-1 | 100 | — | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能 | 穿透容量/mg·g-1 | 参考文献 |
---|---|---|---|---|---|---|---|---|---|
NiO-MoS2/AC | — | — | — | 7000 | 280 | COS:500mg/kg-1 | 97.7① | — | [ |
ML-MoS2/RGO | — | — | — | 32000 | 220 | COS:500mg/kg-1 | 100① | — | [ |
Cu-Co-K/AC | 540.1 | 0.2969 | 1.099 | 5000 | 60 | COS:2800mg·m-3 | — | 43.34 | [ |
MnO/AC | — | — | — | 1000 | 70 | COS:900mg·m-3 | 90② | — | [ |
Fe-Cu-Ce/AC | 323.1 | 0.035 | 1.14 | 1000 | 50 | COS:1582mg·m-3 | 100① | — | [ |
Mn/AC | 905 | 0.464 | — | 3000 | 180 | H2S:3000mg·kg-1 | — | 142 | [ |
MCS-MgO-15 | 660 | 1.74 | 12 | 9000 | 30 | H2S:1000mg·kg-1 | — | 2320 | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能 | 穿透容量/mg·g-1 | 参考文献 |
---|---|---|---|---|---|---|---|---|---|
NiO-MoS2/AC | — | — | — | 7000 | 280 | COS:500mg/kg-1 | 97.7① | — | [ |
ML-MoS2/RGO | — | — | — | 32000 | 220 | COS:500mg/kg-1 | 100① | — | [ |
Cu-Co-K/AC | 540.1 | 0.2969 | 1.099 | 5000 | 60 | COS:2800mg·m-3 | — | 43.34 | [ |
MnO/AC | — | — | — | 1000 | 70 | COS:900mg·m-3 | 90② | — | [ |
Fe-Cu-Ce/AC | 323.1 | 0.035 | 1.14 | 1000 | 50 | COS:1582mg·m-3 | 100① | — | [ |
Mn/AC | 905 | 0.464 | — | 3000 | 180 | H2S:3000mg·kg-1 | — | 142 | [ |
MCS-MgO-15 | 660 | 1.74 | 12 | 9000 | 30 | H2S:1000mg·kg-1 | — | 2320 | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能(转化率)/% | 穿透容量/mg·g-1 | 参考文献 |
---|---|---|---|---|---|---|---|---|---|
10Cu-Co3O4 | 37.4 | 0.21 | 17.7 | 6000 | 70 | COS:110mg·m-3 | 100 | — | [ |
Fe-Cu-Al-O | 96.7 | — | — | 25000 | 40 | H2S:1000mg·kg-1 | — | 113.9 | [ |
3DOM-50ZFS | 229.38 | 0.41 | 7.33 | — | 500 | H2S:1000mg·kg-1 | — | 70 | [ |
3DOM-70ZFS | 213.10 | 0.39 | 7.4 | — | 500 | H2S:1000mg·kg-1 | — | 50 | [ |
ZnAl-3 | — | — | — | 10000 | 500 | H2S:2000mg·kg-1 | — | 268.3 | [ |
MA-LDH-3∶1 | 34 | 0.04 | 5.26 | 12000 | 130 | COS:110 mg·m-3 | 100 | — | [ |
MA-LDH-3∶1 | 34 | 0.04 | 5.26 | 12000 | 150 | H2S:5000mg·kg-1 | 100 | — | [ |
HTLCs-200 | 159.33 | 0.49 | 11.14 | 5000 | 50 | COS:360mg·kg-1 | 95 | — | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能(转化率)/% | 穿透容量/mg·g-1 | 参考文献 |
---|---|---|---|---|---|---|---|---|---|
10Cu-Co3O4 | 37.4 | 0.21 | 17.7 | 6000 | 70 | COS:110mg·m-3 | 100 | — | [ |
Fe-Cu-Al-O | 96.7 | — | — | 25000 | 40 | H2S:1000mg·kg-1 | — | 113.9 | [ |
3DOM-50ZFS | 229.38 | 0.41 | 7.33 | — | 500 | H2S:1000mg·kg-1 | — | 70 | [ |
3DOM-70ZFS | 213.10 | 0.39 | 7.4 | — | 500 | H2S:1000mg·kg-1 | — | 50 | [ |
ZnAl-3 | — | — | — | 10000 | 500 | H2S:2000mg·kg-1 | — | 268.3 | [ |
MA-LDH-3∶1 | 34 | 0.04 | 5.26 | 12000 | 130 | COS:110 mg·m-3 | 100 | — | [ |
MA-LDH-3∶1 | 34 | 0.04 | 5.26 | 12000 | 150 | H2S:5000mg·kg-1 | 100 | — | [ |
HTLCs-200 | 159.33 | 0.49 | 11.14 | 5000 | 50 | COS:360mg·kg-1 | 95 | — | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能 | 穿透容量/mg·g-1 | 参考文献 |
---|---|---|---|---|---|---|---|---|---|
Cu-K-Co/AC | 641.48 | 0.31 | 2.29 | 30000 | 60 | H2S:75mg·m-3 COS:125mg·m-3 | 100② | 218.21 | [ |
Na(0.45)-SAC | 455.05 | 0.22 | 1.89 | 7200 | 60 | H2S:200mg·kg-1 COS:300 mg·kg-1 | 100② | 116.60 | [ |
Cu-Fe/TSAC | 554 | 0.29 | 0.3~1.6 | 10000 | 60 | H2S:500mg·kg-1 COS:400mg·kg-1 CS2:60mg·kg-1 | 100② | 231.28 | [ |
2DNHPC-10 | 567 | 0.50 | 12.1 | 12000 | 180 | H2S:5000mg·kg-1 | 100① | — | [ |
2DNHPC-10 | 567 | 0.50 | 12.1 | 12000 | 150 | COS:110mg·m-3 | 100① | — | [ |
N-HPP-HMTA | 1397 | 0.83 | 0~140 | 6000 | 50 | H2S:5000mg·kg-1 | 100① | — | [ |
N-HPP-HMTA | 1397 | 0.83 | 0~140 | 6000 | 180 | COS:100mg·m-3 | 100① | — | [ |
催化剂 | 比表面积/m2·g-1 | 孔体积/cm·g-1 | 平均孔径/nm | 空速/h-1 | 反应温度/℃ | COS/H2S浓度 | 脱除性能 | 穿透容量/mg·g-1 | 参考文献 |
---|---|---|---|---|---|---|---|---|---|
Cu-K-Co/AC | 641.48 | 0.31 | 2.29 | 30000 | 60 | H2S:75mg·m-3 COS:125mg·m-3 | 100② | 218.21 | [ |
Na(0.45)-SAC | 455.05 | 0.22 | 1.89 | 7200 | 60 | H2S:200mg·kg-1 COS:300 mg·kg-1 | 100② | 116.60 | [ |
Cu-Fe/TSAC | 554 | 0.29 | 0.3~1.6 | 10000 | 60 | H2S:500mg·kg-1 COS:400mg·kg-1 CS2:60mg·kg-1 | 100② | 231.28 | [ |
2DNHPC-10 | 567 | 0.50 | 12.1 | 12000 | 180 | H2S:5000mg·kg-1 | 100① | — | [ |
2DNHPC-10 | 567 | 0.50 | 12.1 | 12000 | 150 | COS:110mg·m-3 | 100① | — | [ |
N-HPP-HMTA | 1397 | 0.83 | 0~140 | 6000 | 50 | H2S:5000mg·kg-1 | 100① | — | [ |
N-HPP-HMTA | 1397 | 0.83 | 0~140 | 6000 | 180 | COS:100mg·m-3 | 100① | — | [ |
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