Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (06): 2768-2775.DOI: 10.16085/j.issn.1000-6613.2018-1684
• Industrial catalysis • Previous Articles Next Articles
Lihong JIANG1(),Shuangshuang SONG1,Deng PAN1,2,Yaming WANG1,Kun LIU1,Yan’e ZHENG1
Received:
2018-08-20
Online:
2019-06-05
Published:
2019-06-05
蒋丽红1(),宋爽爽1,潘登1,2,王亚明1,刘坤1,郑燕娥1
作者简介:
蒋丽红(1968—),博士,教授,研究方向为新型催化剂在天然产物深加工中的应用。E-mail:<email>jlh65@163.com</email>。
基金资助:
CLC Number:
Lihong JIANG, Shuangshuang SONG, Deng PAN, Yaming WANG, Kun LIU, Yan’e ZHENG. Study on the properties of amorphous catalyst Ni-P/TiO2 for hydrogenation of α-pinene[J]. Chemical Industry and Engineering Progress, 2019, 38(06): 2768-2775.
蒋丽红, 宋爽爽, 潘登, 王亚明, 刘坤, 郑燕娥. Ni-P/TiO2非晶态催化剂对α-蒎烯加氢的性能[J]. 化工进展, 2019, 38(06): 2768-2775.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2018-1684
催化剂 | S BET/m2·g-1 | 转化率/% | 选择性/% |
---|---|---|---|
TiO2 | 34 | — | — |
Ni-P | 21 | 81% | 94% |
Ni-P/TiO2 | 29 | 99% | 98% |
催化剂 | S BET/m2·g-1 | 转化率/% | 选择性/% |
---|---|---|---|
TiO2 | 34 | — | — |
Ni-P | 21 | 81% | 94% |
Ni-P/TiO2 | 29 | 99% | 98% |
样品 | 原子量/% | ||
---|---|---|---|
Ni | P | 其他 | |
新鲜催化剂 | 18.80 | 5.79 | 75.41 |
失活催化剂 | 4.25 | 5.53 | 90.22 |
样品 | 原子量/% | ||
---|---|---|---|
Ni | P | 其他 | |
新鲜催化剂 | 18.80 | 5.79 | 75.41 |
失活催化剂 | 4.25 | 5.53 | 90.22 |
序号 | 催化剂 | 反应条件 | 活性 | 参考文献 | ||
---|---|---|---|---|---|---|
转化率/% | 选择性/% | |||||
1 | Ni-P/TiO2 | 130℃, 4MPa, 4h | 99.0 | 98.0 | 本研究 | |
2 | Ni/γ-A12O3 | 170℃, 0.1MPa, 6.5h | 97.7 | 83.1 | [ | |
3 | Raney Ni | 160℃, 6MPa,4h | 98.2 | 92.7 | [ | |
4 | 纳米镍 | 90℃,4MPa, 1.5h | 100.0 | 94.3 | [ | |
5 | 氧化铝、丝光沸石、金属镍沸石分子筛催化剂 | 180~230℃, 2.0MPa, 连续140h | 95.0 | 75.0 | [ | |
6 | Ni/FCC催化剂 | 120℃, 3MPa,2h | 99.4 | 94.41 | [ |
序号 | 催化剂 | 反应条件 | 活性 | 参考文献 | ||
---|---|---|---|---|---|---|
转化率/% | 选择性/% | |||||
1 | Ni-P/TiO2 | 130℃, 4MPa, 4h | 99.0 | 98.0 | 本研究 | |
2 | Ni/γ-A12O3 | 170℃, 0.1MPa, 6.5h | 97.7 | 83.1 | [ | |
3 | Raney Ni | 160℃, 6MPa,4h | 98.2 | 92.7 | [ | |
4 | 纳米镍 | 90℃,4MPa, 1.5h | 100.0 | 94.3 | [ | |
5 | 氧化铝、丝光沸石、金属镍沸石分子筛催化剂 | 180~230℃, 2.0MPa, 连续140h | 95.0 | 75.0 | [ | |
6 | Ni/FCC催化剂 | 120℃, 3MPa,2h | 99.4 | 94.41 | [ |
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