Effect of Ce addition on Fe2O3 catalyst towards CO catalytic oxidation

doi:10.16085/j.issn.1000-6613.2017-0090

Abstract

Abstract: A series of iron-ceria oxide catalysts were prepared by co-precipitation method and the effects of Ce adding into Fe₂O₃ on CO catalytic oxidation activity were investigated. Activity result shows that the addition of Ce increases the CO catalytic activity significantly,which can attain more than 90% CO conversion at ambient temperature and atomospheric pressure. Higher surface area and better redox ability than those of pure Fe₂O₃,and the formation of iron-ceria solid solution in the catalyst may be responsible for the increased catalytic activity. Additionally,different iron precursor has great influence on the CO catalytic oxidation. Sample that was prepared by using FeCl₃as iron precursor shows the best catalytic performance.

Key words: catalysis, reduction, oxidation, carbon monoxide

摘要： 采用共沉淀法制备铁铈氧化物催化剂，考察Ce添加对Fe₂O₃催化氧化CO性能的影响。活性测试表明，负载Ce后，催化剂活性显著提升，CO的转化率在常温常压下能够达到90%以上，主要得益于添加Ce后的催化剂有着较大的比表面积，更好的氧化还原性能以及在催化剂中形成铁铈固溶体。此外，不同的铁前体对催化剂的活性有较大影响。实验结果表明，以FeCl₃作为前体制备出的CeO₂/Fe_（c）具有最大的比表面积和较好的氧化还原性能，从而显示出最佳的CO氧化活性。

关键词: 催化, 还原, 氧化, 一氧化碳

CLC Number:

X511

CHEN Ran, GAO Xiaoya, WANG Jing, CHEN Kezhen, ZHONG Liping, LEI Yanqiu, MEI Zhanqiang, LUO Yongming. Effect of Ce addition on Fe₂O₃ catalyst towards CO catalytic oxidation[J]. Chemical Industry and Engineering Progress, 2017, 36(10): 3737-3742.

陈然, 高晓亚, 王晶, 陈柯臻, 钟丽萍, 雷艳秋, 梅占强, 罗永明. Ce改性Fe₂O₃催化剂对CO催化氧化的影响[J]. 化工进展, 2017, 36(10): 3737-3742.

References

[1] 王东辉,程代云,郝正平,等.纳米金催化剂上CO低(常)温氧化的研究[J].化学进展,2002,14(5):360-367.WANG D H,CHEN D Y,HAO Z P,et al.Carbon monoxide low-temperature oxidation over nanosize gold catalyst[J].Progress in Chemistry,2002,14(5):360-367.
[2] FUNAZAKI N,HEMMI A,ITO S,et al.Development of carbon monoxide detector using Au fine particles doped α-Fe₂O₃[J].Sensors and Actuators B,1993,13/14:536-538.
[3] 张俊,陈婧,黄新松,等.CO催化氧化用纳米材料及其最新研究成果[J].化学进展,2012,24:1245-1251.ZHANG J,CHEN J,HUANG X S,et al.Recent research progress and applications of nano catalytic materials for CO oxidation[J].Progress in Chemistry,2012,24:1245-1251.
[4] YUAN Y,KOZLVOA A P,ASAKURA K,et al.Supported Au catalysts prepared from Au phosphine complexes and As-precipitated metal hydroxides:characterization and low-temperature CO oxidation[J].Journal of Catalysis,1997,170:191-199.
[5] CHEN G X,LI Q L,WEI Y C,et al.Low temperature CO oxidation on Ni-promoted CuO-CeO₂ catalysts[J].Chinese Journal of Catalysis,2013,34:322-329.
[6] XIE X,LI Y,LIU Z Q,et al.Low-temperature oxidation of CO catalysed by Co₃O₄ nanorods[J].Nature,2009,458:746-749.
[7] ZHONG L S,HU J S,CAO A M,et al.3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal[J].Chemistry of Material,2007,19:1648-1655.
[8] LIU X,LIU M H,LUO Y C,et al.Strong metal-support interactions between gold nanoparticles and ZnO nanorods in CO oxidation[J].Journal of the American Chemical Society,2012,134:10251-10258.
[9] LIN H K,CHIU H C,TSAI H C,et al.Characterization and catalytic oxidation of carbon monoxide over cobalt oxide[J].Catalysis Letters,2003,88:169-174.
[10] 刘东亮,刘道胜,张晓彤,等.CO低温氧化负载金催化剂研究进展[J].化工进展,2007,26(8):1110-1115.LIU D L,LIU D S,ZHANG X T,et al.Studies on low-temperature oxidation of CO by Au cataIyst[J].Chemical Industry and Engineering Progress,2007,26(8):1110-1115.
[11] 鲁继青,罗孟飞,辛勤.纳米金催化剂在 CO 低温氧化和选择性氧化中的研究进展[J].化工进展,2007,26(3):306-309.LU J Q,LUO M F,XIN Q.Nano-sized gold catalysts for CO low-temperature oxidation and selective oxidation[J].Chemical Industry and Engineering Progress,2007,26(3):306-309.
[12] KIM Y,SHI S K,WHITE J M.Oxygen inhibition of CO oxidation on polycrystalline Rh[J].Journal of Catalysis,1980,61:374-377.
[13] YAO Y F Y.The oxidation of CO and hydrocarbons over noble metal catalysts[J].Journal of Catalysis,1984,87:152-162.
[14] SCHWANKNER R J,EISWIRTH M,MÖLLER P,et al.Kinetic oscillations in the catalytic CO oxidation on Pt(100):periodic perturbations[J].Journal of Chemical Physics,1985,83(4):1578-1587.
[15] HU L,SUN K,PENG Q,et al.Surface active sites on Co₃O₄ nanobelt and nanocube model catalysts for CO oxidation[J].Nano Research,2010,3:363-368.
[16] 陈霞,张俊丰,黄妍,等.CuCoO_x/TiO₂催化氧化CO性能[J].化工进展,2009,28(8):1355-1359.CHEN X,ZHANG J F,HUANG Y,et al.Catalytic performance of CuCoO_x/TiO₂ for oxidation of carbon monoxide[J].Chemical Industry and Engineering Progress,2009,28(8):1355-1359.
[17] JIA C J,SCHWICKARDI M,WEIDENTHALER C,et al.Co₃O₄-SiO₂ nanocomposite:a very active catalyst for CO oxidation with unusual catalytic behavior[J].Journal of the American Chemical Society,2011,133:11279-11288.
[18] ROYER S,DUPREZ D.Catalytic oxidation of carbon monoxide over transition metal oxides[J].ChemCatChem,2011,3:24-65.
[19] DENG S,XIAO X,XING X,et al.Structure and catalytic activity of 3D macro/mesoporous Co₃O₄ for CO oxidation prepared by a facile self-sustained decomposition of metal-organic complexes[J].Journal of Molecular Catalysis A:Chemical,2015,398:79-85.
[20] WANG G Y,ZHANG W X,LIAN H L,et al.Effect of calcination temperatures and precipitant on the catalytic performance of Au/ZnO catalysts for CO oxidation at ambient temperature and in humid circumstances[J].Applied Catalysis A:General,2003,239:1-10.
[21] YAKIMOVA M S,IVANOV V K,POLEZHAEVA O S,et al.Oxidation of CO on nanocrystalline ceria promoted by transition metal oxides[J].Doklady Chemistry,2009,427:186-189.
[22] ZOU Q Z,MENG M,LI Q,et al.Surfactants-assisted synthesis and characterizations of multicomponent mesoporous materials Co-Ce-Zr-O and Pd/Co-Ce-Zr-O used for low-temperature CO oxidation[J].Materials Chemistry and Physics,2008,109:373-380.
[23] SASIKALA R,GUPTA N M,KULSHRESHTHA S K.Temperature-programmed reduction and CO oxidation studies over Ce-Sn mixed oxides[J].Catalysis Letters,2001,71:69-73.
[24] 士丽勄,郑德山,王素勄.富氢气氛中CO优先氧化CuO-CeO₂基催化剂的研究进展[J].化工进展,2011,30(9):1956-1960.SHI L M,ZHENG D S,WANG S M.Research progress of CuO-CeO₂-based catalysts for preferential oxidation of CO in hydrogen-rich gas[J].Chemical Industry and Engineering Progress,2011,30(9):1956-1960.
[25] 张文丽,刘娜,丁素萍,等.逆CeO₂-CuO催化剂用于优先氧化CO的性能[J].化工进展,2011,30(8):1744-1748.ZHANG W L,LIU N,DING S P,et al.Study on catalytic performance of CeO₂/CuO catalyst for preferential CO oxidation[J].Chemical Industry and Engineering Progress,2011,30(8):1744-1748.
[26] LIANG S,TENG F,BULGAN G,et al.Effect of phase structure of MnO₂ nanorod catalyst on the activity for CO oxidation[J].Journal of Physical Chemistry C,2008,112:5307-5315.
[27] XU R,WANG D,WANG X,et al.Surface structure effects in nanocrystal MnO₂ and Ag/MnO₂ catalytic oxidation of CO[J].Journal of Catalysis,2006,237:426-430.
[28] YAN W F,CHEN B,MAHURIN S M,et al.Preparation and comparison of supported gold nanocatalysts on anatase,brookite,rutile,and P25 polymorphs of TiO₂ for catalytic oxidation of CO[J].Journal of Physical Chemistry B,2005,109:10676-85.
[29] GREEN I X Y,TANG W J,NEUROCK M,et al.Spectroscopic observation of dual catalytic sites during oxidation of CO on a Au/TiO₂ catalyst[J].Science,2011,333:736-739.
[30] LI K,ZHOU W,WANG X,et al.CeO₂ based oxygen storage compounds Ⅱ.Adding precious metal to improve oxygen storage capacity[J].Journal of the Chinese Rare Earth Society,2004,22:32-34.
[31] TROVARELLI A,LEITENBURG C D,DOLCETTI G,et al.Design better cerium-based oxidation catalysts[J].Chemtech,1997,27:32-37.
[32] DESHPANDE P A,ARUNA S T,MADRAS G.CO oxidation by CeO₂-Al₂O₃-CeAlO₃ hybrid oxides[J].Catalysis Science and Technology,2011,1:1683-1691.
[33] KUBSH J E,RIECK J S,SPENCER N D.Cerium oxide stabilization:physical property and three-way activity considerations[J].Studies in Surface Science and Catalysis,1991,71:125-138.
[34] TROVARELLI A.Catalytic properties of ceria and CeO₂-containing materials[J].Catalysis Reviews,1996,38(4):439-520.
[35] 赵志利,李建伟,陈标华.三氧化二铁晶型对铁铬系高温变换催化剂性能的影响[J].现代化工,2006,26(2):143-146.ZHAO Z L,LI J W,CHEN B H.Effect of Fe₂O₃ crystal structure on the performance of Fe₂O₃/Cr₂O₃ high temperature water gas shift catalyst[J].Modern Chemical Industry,2006,26(2):143-146.
[36] KAPTEIJN F,LOPEZ G M,MELIANCABRERA I,et al.Synergy of Fe_xCe_1-xO₂ mixed oxides for N₂O decomposition[J].Journal of Catalysis,2006,239:340-346.
[37] LIU X,LIU J,CHANG Z,et al.Crystal plane effect of Fe₂O₃ with various morphologies on CO catalytic oxidation[J].Catalysis Communication,2011,12:530-534.
[38] ZHONG Z Y,HO J,TEO J,et al.Synthesis of porous α-Fe₂O₃ nanorods and deposition of very small gold particles in the pores for catalytic oxidation of CO[J].Chemistry of Materials,2007,19:69-73.
[39] 孙令玥.铈铁氧载体化学链储氢-制氢性能研究[D].昆明:昆明理工大学,2015.SUN L Y.Hydrogen storage of cerium iron oxide carrier chain of chemical-research on hydrogen production performance[D].Kunming:Kunming University of Science and Technology,2015.
[40] LI X M,HAN D Z,WANG H,et al.Propene oligomerization to high-quality liquid fuels over Ni/HZSM-5[J].Fuel,2015,144:9-14.
[41] TANG L, YAMAGUCHI D, BURKE N, et al.Methanedecomposition over ceria modified iron catalysts[J].CatalysisCommunications,2010,11:1215-1219.
[42] ZIELINSKI J,ZGLINICKA I,ZNAK L,et al.Reduction of Fe₂O₃ with hydrogen[J].Applied Catalysis A:General,2010,381:191-196.
[43] ZHU X,WEI Y,WANG H,et al.Ce-Fe oxygen carriers forchemical-looping stream methane reforming[J].International Journalof Hydrogen Energy,2013,38:4492-4501.
[44] QIAO D S,LU G Z,LIU X H,et al.Preparation of Ce_12xFe_xO₂ solidsolution and its catalytic performance for oxidation of CH₄ and CO[J].Journal of Material Science,2011,46:3500-3506.
[45] 刘雄姗.Fe-CeO₂(111)表面催化活性及CO 吸附与氧化第一性原理研究[D].大连:大连理工大学,2015.LIONG X S.First-principles study of the catalytic activities ofFe-CeO₂ (111) surface and CO adsorption and oxidation at the dopedsurface[D].Dalian:Dalian University of Technology,2015.

Effect of Ce addition on Fe₂O₃ catalyst towards CO catalytic oxidation

Ce改性Fe₂O₃催化剂对CO催化氧化的影响

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Fu'an. Consumption and emission reduction of the reactor of 300kt/a propylene oxide process [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 213-218.
[2]	ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286.
[3]	YANG Xiazhen, PENG Yifan, LIU Huazhang, HUO Chao. Regulation of active phase of fused iron catalyst and its catalytic performance of Fischer-Tropsch synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 310-318.
[4]	ZHENG Qian, GUAN Xiushuai, JIN Shanbiao, ZHANG Changming, ZHANG Xiaochao. Photothermal catalysis synthesis of DMC from CO₂ and methanol over Ce_0.25Zr_0.75O₂ solid solution [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 319-327.
[5]	ZHAO Wei, ZHAO Deyin, LI Shihan, LIU Hongda, SUN Jin, GUO Yanqiu. Synthesis and application of triazine drag reducing agent for nature gas pipeline [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 391-399.
[6]	WANG Zhengkun, LI Sifang. Green synthesis of gemini surfactant decyne diol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 400-410.
[7]	GAO Yufei, LU Jinfeng. Mechanism of heterogeneous catalytic ozone oxidation:A review [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 430-438.
[8]	ZHANG Jie, WANG Fangfang, XIA Zhonglin, ZHAO Guangjin, MA Shuangchen. Current SF₆ emission, emission reduction and future prospects under “carbon peaking and carbon neutrality” [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 447-460.
[9]	WANG Lele, YANG Wanrong, YAO Yan, LIU Tao, HE Chuan, LIU Xiao, SU Sheng, KONG Fanhai, ZHU Canghai, XIANG Jun. Influence of spent SCR catalyst blending on the characteristics and deNO _x performance for new SCR catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 489-497.
[10]	GU Yongzheng, ZHANG Yongsheng. Dynamic behavior and kinetic model of Hg⁰ adsorption by HBr-modified fly ash [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 498-509.
[11]	ZHAO Jingchao, TAN Ming. Effect of surfactants on the reduction of industrial saline wastewater by electrodialysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 529-535.
[12]	DENG Liping, SHI Haoyu, LIU Xiaolong, CHEN Yaoji, YAN Jingying. Non-noble metal modified vanadium titanium-based catalyst for NH₃-SCR denitrification simultaneous control VOCs [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 542-548.
[13]	SHU Bin, CHEN Jianhong, XIONG Jian, WU Qirong, YU Jiangtao, YANG Ping. Necessity analysis of promoting the development of green methanol under the goal of carbon neutrality [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4471-4478.
[14]	GENG Yuanze, ZHOU Junhu, ZHANG Tianyou, ZHU Xiaoyu, YANG Weijuan. Homogeneous/heterogeneous coupled combustion of heptane in a partially packed bed burner [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4514-4521.
[15]	WANG Peng, SHI Huibing, ZHAO Deming, FENG Baolin, CHEN Qian, YANG Da. Recent advances on transition metal catalyzed carbonylation of chlorinated compounds [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4649-4666.