Preparation of cellulose nanocrystals by solid catalyst zirconium phosphate assisted hydrolysis from spent mushroom substrate

doi:10.16085/j.issn.1000-6613.2016.03.033

Chemical Industry and Engineering Progree ›› 2016, Vol. 35 ›› Issue (03): 866-871.DOI: 10.16085/j.issn.1000-6613.2016.03.033

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Preparation of cellulose nanocrystals by solid catalyst zirconium phosphate assisted hydrolysis from spent mushroom substrate

ZHUANG Senyang¹, TANG Lirong^1,2, LU Qilin¹, LIN Fengcai¹, NI Peizhong¹, HUANG Biao¹

1 College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, Fujian, China;
2 Jinshan College of Fujian Agriculture and Forestry University, Fuzhou 350002, Fujian, China

Received:2015-07-23 Revised:2015-08-13 Online:2016-03-05 Published:2016-03-05

磷酸锆辅助催化水解菌糠制备纳米纤维素晶体的性能

庄森炀¹, 唐丽荣^1,2, 卢麒麟¹, 林凤采¹, 倪沛钟¹, 黄彪¹

1 福建农林大学材料工程学院, 福建福州 350002;
2 福建农林大学金山学院, 福建福州 350002

通讯作者: 黄彪,教授,博士生导师,主要从事植物纤维化学与炭材料研究。E-mail:fjhuangbiao@hotmail.com
作者简介:庄森炀(1991-),男,硕士研究生。唐丽荣(1984-),女,讲师,博士,主要从事植物纤维化学与炭材料研究。E-mail:tanglr0201@126.com.
基金资助:
“948”国家林业局引进先进林业科学技术项目(2014-4-30)、福建省教育厅A类科研项目(JA13371)及福建农林大学“校杰出青年科研人才”培养专项基金(xjq201422)项目。

Abstract

Abstract: In this research,cellulose nanocrystals (CNCs) were prepared by solid catalyst zirconium phosphate assisted hydrolysis method from spent mushroom substrate. Compared with traditional acid hydrolysis method,this method is simpler to operate and more eco-friendly. The effect of ultrasonication time,ultrasonication temperature and the concentration of diluted sulfuric acid on the yield of CNCs were investigated. The results showed that the yield of CNCs reached 42.80%,when ultrasonication time was 5h,ultrasonication temperature was 75℃ and the concentration of diluted sulfuric acid was 12.3%. The microstructure,morphology,spectrum properties and the crystal structure of CNCs were characterized by transmission electron microscopy(TEM),scanning electron microscope (SEM),fourier transformation infrared spectroscopy (FTIR) and X-ray diffraction (XRD),respectively. The SEM and TEM showed that CNCs were rod-like with diameters of 10-30nm,and the FTIR analysis showed that the CNCs still kept the basic chemical structure of cellulose. The XRD pattern showed that the CNCs presented the crystal form of cellulose I. Compared with the spent mushroom substrate,the crystallinity of CNCs increased from 63.79% to 81.04%. This research proposed a new approach to efficient utilization of the spent mushroom substrate.

Key words: spent mushroom substrate, zirconium phosphate, diluted sulfuricacid, catalytic hydrolysis, cellulose nanocrystals

摘要： 以食用菌产业的副产品菌糠为原料,采用磷酸锆催化剂辅助稀硫酸水解制备纳米纤维素晶体(cellulose nanocrystals,CNCs).与传统酸水解方法相比,该方法简化了工艺流程,制备过程环境友好。考察了超声时间、超声温度以及稀硫酸浓度等因素对CNCs得率的影响。结果表明当超声时间为5h、超声温度为75℃及稀硫酸浓度为12.3%时,CNCs得率为42.80%.采用透射电子显微镜(TEM)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)以及X射线衍射仪(XRD)对样品的微观形貌、谱学性能和晶体结构进行了研究分析,结果表明所制得的CNCs呈棒状,直径介于10～30nm之间;CNCs属于纤维素I型,与原料菌糠相比,结晶度由63.79%增大到81.04%;且CNCs仍具有天然纤维素的基本化学结构。论文研究为菌糠的资源化高效利用开辟了新途径。

关键词: 菌糠, 磷酸锆, 稀硫酸, 催化水解, 纳米纤维素晶体

CLC Number:

ZHUANG Senyang, TANG Lirong, LU Qilin, LIN Fengcai, NI Peizhong, HUANG Biao. Preparation of cellulose nanocrystals by solid catalyst zirconium phosphate assisted hydrolysis from spent mushroom substrate[J]. Chemical Industry and Engineering Progree, 2016, 35(03): 866-871.

庄森炀, 唐丽荣, 卢麒麟, 林凤采, 倪沛钟, 黄彪. 磷酸锆辅助催化水解菌糠制备纳米纤维素晶体的性能[J]. 化工进展, 2016, 35(03): 866-871.

References

[1] TANG L,HUANG B,LU Q,et al. Ultrasonication-assisted manufacture of cellulose nanocrystals esterified with acetic acid[J]. Bioresource Technology,2013,127:100-105.

[2] LU Q,TANG L,LIN F,et al. Preparation and characterization of cellulose nanocrystals via ultrasonication-assisted FeCl₃-catalyzed hydrolysis[J]. Cellulose,2014,21(5):3497-3506.

[3] TORVINEN K,SIEVÄNEN J,HJELT T,et al. Smooth and flexible filler-nanocellulose composite structure for printed electronics applications[J]. Cellulose,2012,19(3):821-829.

[4] OKAHISA Y,ABE K,NOGI M,et al. Effects of delignification in the production of plant-based cellulose nanofibers for optically transparent nanocomposites[J]. Composites Science and Technology,2011,71(10):1342-1347.

[5] ZAMAN M,LIU H,XIAO H,et al. Hydrophilic modification of polyester fabric by applying nanocrystalline cellulose containing surface finish[J]. Carbohydrate Polymers,2013,91(2):560-567.

[6] GAO W,LIANG J,PIZZUL L,et al. Evaluation of spent mushroom substrate as substitute of peat in Chinese biobeds[J]. International Biodeterioration & Biodegradation,2015,98:107-112.

[7] 汪水平,王文娟. 菌糠饲料的开发和利用[J]. 粮食与饲料工业,2003(6):37-39.

[8] 李加友,苗淑杏,姚祥坦. 蘑菇菌糠二次增效发酵及其作物栽培应用[J]. 食用菌学报,2008,15(3):75-79.

[9] BAHETI V,ABBASI R,MILITKY J. Ball milling of jute fibre wastes to prepare nanocellulose[J]. World Journal of Engineering,2012,9(1):45-50.

[10] 刘鹤,王丹,商士斌,等. 纤维素纳米晶须与水性聚氨酯复合材料的性能[J]. 化工进展,2010,29(s1):236-239.

[11] NIDETZKY B,STEINER W. A new approach for modeling cellulase-cellulose adsorption and the kinetics of the enzymatic hydrolysis of microcrystalline cellulose[J]. Biotechnology and Bioengineering,1993,42(4):469-479.

[12] 饶小平. 晶态混合磷酸锆的超分子插层组装[D]. 重庆:西南师范大学,2004.

[13] 李颖,刘可,华伟明,等. 苯磺酸修饰的层柱磷酸锆的制备及催化应用[J]. 高等学校化学学报,2011,32(3):731-737.

[14] 卢麒麟. 巨菌草制备纳米纤维素的研究[D]. 福州:福建农林大学,2013.

[15] ALEMDAR A,SAIN M. Isolation and characterization of nanofibers from agricultural residues-wheat straw and soy hulls[J]. Bioresource Technology,2008,99(6):1664-1671.

[16] OH S Y,YOO D I,SHIN Y,et al. Crystalline structure analysis of cellulose treated with sodium hydroxide and carbon dioxide by means of X-ray diffraction and FTIR spectroscopy[J]. Carbohydrate Research,2005,340(15):2376-2391.

[17] QUA E H,HORNSBY P R,SHARMA H S S,et al. Preparation and characterisation of cellulose nanofibres[J]. Journal of Materials Science,2011,46(18):6029-6045.

Preparation of cellulose nanocrystals by solid catalyst zirconium phosphate assisted hydrolysis from spent mushroom substrate

磷酸锆辅助催化水解菌糠制备纳米纤维素晶体的性能

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