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Advances in production of 5-hydroxymethylfurfural from biomass by acid catalysis

OUYANG Siyu,XU Qiong,FU Zaihui,ZHANG Chao,LIU Xianxiang,YIN Dulin   

  1. National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources,Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research(Ministry of Education),School of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,Hunan,China
  • Online:2014-05-05 Published:2014-05-05

生物质转化制5-羟甲基糠醛的酸催化研究新进展

欧阳四余,徐琼,伏再辉,张超,刘贤响,尹笃林   

  1. 湖南师范大学化学化工学院石化新材料与资源精细利用国家地方联合工程实验室,化学生物学及中药分析 教育部重点实验室,湖南 长沙 410081

Abstract: 5-Hydroxymethylfurfural(5-HMF)is a kind of important platform chemical compound and can be transformed into a series of important organic compounds,pharmaceutical intermediates,pesticide products,and possesses wide application value and market prospect. In this paper,the research achievements in converting biomass to 5-HMF in the latest five years are summarized in terms of different catalytic system using cellulose,starch,inulin,sucrose,fructose,glucose,agricultural and forestry waste as raw materials. The advantages and disadvantages of different catalytic systems are analyzed. Strengthening the green design of catalytic materials,engineering research of catalyst recycling,exploration of catalytic liquefaction process of agriculture and forestry by-products are proposed to promote the development of industrial technology for preparing 5-HMF from biomass.

Key words: biomass, preparation, 5-HMF, catalysis

摘要: 5-羟甲基糠醛(5-HMF)是一种重要的平台化合物,可转化为一系列重要有机化工原料、医药中间体、农药产品等。本文综述了近5年来国内外以纤维素、淀粉、菊糖、蔗糖、果糖、葡萄糖和农林废物等生物质为原料,在不同酸催化下制备5-羟甲基糠醛的一些特色工作,分析比较了不同酸催化反应体系的优缺点,并建议在制备5-HMF的过程中应加强催化材料的绿色设计、催化剂循环利用的工程研究和农林副产物的复合催化液化工艺的探索,以促进生物质制备5-HMF工业技术的发展。

关键词: 生物质, 制备, 5-羟甲基糠醛, 催化

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