Abstract: New methods of catalytic synthesis of novel plasticizer，catalytic reaction process，catalyst type and preparation were summarized. Properties of major domestic and overseas new environmental protection plasticizers，applications and the research status were especially focused on，including the synthesis and properties of biological-base vegetable oil plasticizer，polyester plasticizer，citric acid ester plasticizer，trioctyl trimellitate plasticizer and dioctyl terephthalate plasticizer. At the meantime，compared with the traditional synthesis method and catalyst，the trend of catalytic synthesis of plasticizer and the application direction of plasticizers in national high-tech fields were pointed out. Put forward the plasticizer industry and new materials additive field in our country development should focus on the adjustment of product structure, accelerate the exploitation of non adjacent benzene structure, plant oil base plasticizer.

Key words: environmental protection plasticizer, esterification, PVC additives, biological-base plasticizer, catalyst

摘要： 综述了国内外催化合成新型增塑剂的新方法和催化反应工艺、催化剂的种类和制备，重点介绍了国内外主要新型环保增塑剂的性能、应用及研究现状，包括生物基植物油、聚酯、柠檬酸酯、偏苯三酸三酯及对苯二甲酸二辛酯类增塑剂的合成与性能，并与传统合成方法及催化剂比较，指出了我国催化合成增塑剂的趋势和增塑剂在国家高新技术领域中应用方向，提出我国增塑剂行业及新材料助剂领域的发展应着重于调整产品结构，加快非邻苯结构类、植物油基增塑剂的开发。

关键词: 环保增塑剂, 酯化反应, PVC助剂, 生物基增塑剂, 催化剂