Chemical Industry and Engineering Progree ›› 2012, Vol. 31 ›› Issue (04): 893-895.

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Synthesis and properties of di-hydrophilic betaine with amide group

DU GuangjinLIU XueminLI DanpingYANG Qianqian   

  1. School of Chemical & Material Engineering,Jiangnan University,Wuxi 214122,Jiangsu,China
  • Received:2011-10-24 Revised:2011-11-09 Online:2012-04-05 Published:2012-04-05

酰胺型双亲水基甜菜碱的合成与性能

杜光劲,刘学民,李丹萍,杨欠欠   

  1. 江南大学化学与材料工程学院,江苏 无锡 214122
  • 通讯作者: 杜光劲

Abstract: A novel di-hydrophilic beatine,N,N-bis[3-(dimethylcarboxymethylammonio)-propyl] lauramide was synthesized using lauroyl chloride,
tetramethyldipropylenetriamine and sodium chloroacetate as starting materials.The structure of this betaine surfactant was confirmed by FT-IR and ESI-MS spectrum,and surface chemical properties of the product were measured.The lowest surface tension is 36.04 mN/m,critical micelle concentration is 1.07×10-3 mol/L at 25 ℃.The foaming and emulsification properties and lime soap dispersing power of the surfactant were also studied.

Key words: amide group, di-hydrophilic betaine, synthesis, properties, amide group, di-hydrophilic betaine, synthesis, properties

摘要: 以十二酰氯、四甲基二丙烯三胺和氯乙酸钠为原料,合成了一种新型双亲水基甜菜碱表面活性剂——N,N-双[3-(二甲基羧甲基铵基)-丙基]十二酰胺。经FT-IR、ESI-MS分析确证,合成的表面活性剂为目标产物,并对产品的表面化学性能进行了测定。25 ℃时所合成的双亲水基甜菜碱水溶液的最低表面张力为36.04 mN/m,临界胶束浓度为1.07×10-3 mol/L,并考察其泡沫性能、乳化力、钙皂分散力。

关键词: 酰胺基, 双亲水基甜菜碱, 合成, 性能,  ,

CLC Number: 

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