Catalytic hydrogenation of furfuryl alcohol into pentanediol over Pt/CaO materials

doi:10.16085/j.issn.1000-6613.2023-0448

Abstract

Abstract:

A series of Pt/CaO catalysts were synthesized via impregnation method and applied for the selective hydrogenation of bio-based furfuryl alcohol into pentanediol. The physicochemical characteristics of the as-prepared catalysts were comprehensively characterized through X-ray diffractometer, scanning electron microscopy, CO₂-temperature programmed desorption, N₂ isothermal adsorption-desorption, X-ray photoelectron spectroscopy, and thermogravimetric-differential thermal analysis. The experimental results showed that the Pt/CaO-600 catalyst exhibited excellent catalytic activity towards furfuryl alcohol hydrogenation. Gratifyingly, the furfuryl alcohol conversion achieved 99.8%, and the yields of 1,2-pentanediol and 1,5-pentanediol were 48.6% and 21.5% respectively at 210℃ under 4MPa H₂. The good activity of Pt/CaO could be attributed to the fact that the carrier CaO provided appropriate amounts of basic sites, which facilitated the ring-opening reaction of furfuryl alcohol, thus improving the conversion and pentanediol selectivity. Moreover, the as-prepared Pt/CaO also exhibited excellent performance in recycling experiments, wherein the yields of 1,2-pentanediol and 1,5-pentanediol reached 40.3% and 17.0% respectively with 96.5% furfuryl alcohol conversion after being repeated four times.

Key words: furfuryl alcohol, catalysis, hydrogenation, pentanediol

摘要：

通过浸渍法制备出一系列氧化钙负载铂金属催化材料，用于生物质基糠醇选择性加氢制备戊二醇研究。研究采用X射线衍射仪、扫描电子显微镜、CO₂-程序升温脱附、N₂等温吸附-脱附、X射线光电子能谱、热重-差热分析法等一系列表征手段，对合成的催化剂样品物理化学性质进行了系统表征。实验结果表明，Pt/CaO-600催化剂表现出优异的催化活性，在4MPa氢压、210℃反应温度条件下，糠醇转化率为99.8%，1,2-戊二醇和1,5-戊二醇收率分别可达48.6%和21.5%。催化剂的优异性能可归因于作为载体的CaO提供了适宜的碱性位点，有利于糠醇开环反应的发生，进而提高了糠醇转化率与戊二醇选择性。同时，催化剂还表现出了优异的循环使用性能，经重复使用4次后，其催化糠醇转化率可达96.5%，1,2-戊二醇和1,5-戊二醇的收率分别为40.3%和17.0%。

关键词: 糠醇, 催化, 加氢, 戊二醇

CLC Number:

TQ251.1

XIAO Yaoxin, ZHANG Jun, SHAN Rui, YUAN Haoran, CHEN Yong. Catalytic hydrogenation of furfuryl alcohol into pentanediol over Pt/CaO materials[J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1318-1327.

萧垚鑫, 张军, 单锐, 袁浩然, 陈勇. Pt/CaO材料催化糠醇加氢制备戊二醇[J]. 化工进展, 2024, 43(3): 1318-1327.

Figures/Tables 17

References 35

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样品	比表面积/m²·g^-1	平均孔径/nm	孔容/cm³·g^-1	碱度/μmol·g^-1
Pt/CaO-400	48.47	23.70	0.29	37.59
Pt/CaO-500	93.62	19.75	0.46	50.14
Pt/CaO-600	76.72	17.46	0.33	55.45
Pt/CaO-700	5.70	19.48	0.002	63.45

样品	比表面积/m²·g^-1	平均孔径/nm	孔容/cm³·g^-1	碱度/μmol·g^-1
Pt/CaO-400	48.47	23.70	0.29	37.59
Pt/CaO-500	93.62	19.75	0.46	50.14
Pt/CaO-600	76.72	17.46	0.33	55.45
Pt/CaO-700	5.70	19.48	0.002	63.45

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