Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (7): 3957-3965.DOI: 10.16085/j.issn.1000-6613.2022-0099
• Resources and environmental engineering • Previous Articles Next Articles
WANG Xiao1(), JIN Biao1, ZHANG Xiaoting1, ZHANG Jianwu1, WANG Yubin2, YUAN Dongdong1, YANG Liushuan1
Received:
2022-01-13
Revised:
2022-03-10
Online:
2022-07-23
Published:
2022-07-25
Contact:
WANG Xiao
汪潇1(), 金彪1, 张小婷1, 张建武1, 王宇斌2, 苑冬冬1, 杨留栓1
通讯作者:
汪潇
作者简介:
汪潇(1975—),男,博士,副教授,研究方向为固体废物资源化利用。E-mail:基金资助:
CLC Number:
WANG Xiao, JIN Biao, ZHANG Xiaoting, ZHANG Jianwu, WANG Yubin, YUAN Dongdong, YANG Liushuan. Effect of cation on hydrothermal crystallization of desulfurized gypsum whiskers in chloride system and its mechanism[J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3957-3965.
汪潇, 金彪, 张小婷, 张建武, 王宇斌, 苑冬冬, 杨留栓. 氯盐体系下阳离子对脱硫石膏晶须水热结晶的影响及其机理[J]. 化工进展, 2022, 41(7): 3957-3965.
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-0099
处理方式 | CaO | SO3 | Al2O3 | SiO2 | Fe2O3 | MgO | TiO2 | K2O | Na2O |
---|---|---|---|---|---|---|---|---|---|
预处理前 | 33.23 | 37.23 | 2.86 | 5.18 | 0.64 | 1.24 | 0.10 | 0.21 | 0.01 |
预处理后 | 31.02 | 43.98 | 1.06 | 2.48 | 0.32 | 0.15 | 0.05 | 0 | 0 |
处理方式 | CaO | SO3 | Al2O3 | SiO2 | Fe2O3 | MgO | TiO2 | K2O | Na2O |
---|---|---|---|---|---|---|---|---|---|
预处理前 | 33.23 | 37.23 | 2.86 | 5.18 | 0.64 | 1.24 | 0.10 | 0.21 | 0.01 |
预处理后 | 31.02 | 43.98 | 1.06 | 2.48 | 0.32 | 0.15 | 0.05 | 0 | 0 |
添加剂 | 面积 | 面积百分比/% | |||||
---|---|---|---|---|---|---|---|
Ca―O―S | H―O | R―O | 合计 | Ca―O―S | H―O | R―O | |
无 | 435646.30 | 193732.74 | — | 629379.04 | 69.22 | 40.78 | — |
NaCl | 296950.41 | 94892.78 | — | 378005.79 | 75.78 | 24.22 | — |
CuCl2 | 240580.59 | 55997.44 | 35539.94 | 332117.97 | 72.44 | 16.86 | 10.71 |
AlCl3 | 150731.44 | 39263.23 | 38190.37 | 228185.04 | 66.06 | 17.21 | 16.74 |
添加剂 | 面积 | 面积百分比/% | |||||
---|---|---|---|---|---|---|---|
Ca―O―S | H―O | R―O | 合计 | Ca―O―S | H―O | R―O | |
无 | 435646.30 | 193732.74 | — | 629379.04 | 69.22 | 40.78 | — |
NaCl | 296950.41 | 94892.78 | — | 378005.79 | 75.78 | 24.22 | — |
CuCl2 | 240580.59 | 55997.44 | 35539.94 | 332117.97 | 72.44 | 16.86 | 10.71 |
AlCl3 | 150731.44 | 39263.23 | 38190.37 | 228185.04 | 66.06 | 17.21 | 16.74 |
18 | 汪潇, 杨留栓, 朱新峰, 等. K2SO4/KCl添加剂对脱硫石膏晶须结晶的影响[J]. 人工晶体学报, 2013, 42(12): 2661-2668. |
WANG Xiao, YANG Liushuan, ZHU Xinfeng, et al. Effect of K2SO4/KCl additive on the crystallization of desulfurization gypsum whisker[J]. Journal of Synthetic Crystals, 2013, 42(12): 2661-2668. | |
19 | 汪潇, 金彪, 张小婷, 等. MgSO4/MgCl2对脱硫石膏溶解度及其晶须结晶的影响[J]. 河南科技大学学报(自然科学版), 2018, 39(2): 6-10, 24. |
WANG Xiao, JIN Biao, ZHANG Xiaoting, et al. Effects of MgSO4/MgCl2 on FGD gypsum solubility and whisker crystallization[J]. Journal of Henan University of Science and Technology (Natural Science), 2018, 39(2): 6-10, 24. | |
20 | WANG Xiao, YANG Liushuan, ZHU Xinfeng, et al. Preparation of calcium sulfate whiskers from FGD gypsum via hydrothermal crystallization in the H2SO4-NaCl-H2O system[J]. Particuology, 2014, 17: 42-48. |
21 | YANG Liushuan, WANG Xiao, ZHU Xinfeng, et al. Preparation of calcium sulfate whisker by hydrothermal method from flue gas desulfurization (FGD) gypsum[J]. Applied Mechanics and Materials, 2012, 268/269/270: 823-826. |
22 | WANG Xiao, JIN Biao, YANG Liushuan, et al. Effect of CuCl2 on hydrothermal crystallization of calcium sulfate whiskers prepared from FGD gypsum[J]. Crystal Research and Technology, 2015, 50(8): 633-640. |
23 | CAO Bolun, WANG Xiao, ZHANG Xiaoting, et al. A readily monitored and controllable hydrothermal system for the facile, cost-effective transformation of FGD gypsum to calcium sulfate hemihydrate whiskers[J]. Particuology, 2021, 54: 173-180. |
24 | JIA Caiyun, CHEN Qiaoshan, ZHOU Xu, et al. Trace NaCl and Na2EDTA mediated synthesis of α-calcium sulfate hemihydrate in glycerol-water solution[J]. Industrial & Engineering Chemistry Research, 2016, 55(34): 9189-9194. |
25 | ZHAO Wenpeng, GAO Chuanhui, ZHANG Guangyu, et al. Controlling the morphology of calcium sulfate hemihydrate using aluminum chloride as a habit modifier[J]. New Journal of Chemistry, 2016, 40(4): 3104-3108. |
26 | 王宇斌, 文堪, 王森, 等. 同离子效应对半水硫酸钙形貌的调控机理[J]. 高校化学工程学报, 2018, 32(6): 1444-1449. |
WANG Yubin, WEN Kan, WANG Sen, et al. Regulation mechanism of common ion effect on the morphology of calcium sulphate hemihydrate[J]. Journal of Chemical Engineering of Chinese Universities, 2018, 32(6): 1444-1449. | |
27 | 汪潇, 金彪, 王宇斌, 等. 阴离子在脱硫石膏晶须水热结晶中的作用机理[J]. 高等学校化学学报, 2020, 41(3): 473-480. |
WANG Xiao, JIN Biao, WANG Yubin, et al. Interaction mechanism of anions in hydrothermal crystallization of desulfurization gypsum whiskers[J]. Chemical Journal of Chinese Universities, 2020, 41(3): 473-480. | |
28 | LI Zhibao, DEMOPOULOS George P. Effect of NaCl, MgCl2, FeCl2, FeCl3, and AlCl3 on solubility of CaSO4 phases in aqueous HCl or HCl+CaCl2 solutions at 298 to 353K[J]. Journal of Chemical & Engineering Data, 2006, 51(2): 569-576. |
29 | 汪潇, 杨留栓, 朱新峰, 等. 湿法脱硫石膏颗粒特性与杂质赋存状况分析[J]. 环境科学与技术, 2013, 36(9): 135-138. |
WANG Xiao, YANG Liushuan, ZHU Xinfeng, et al. Analysis of particle characteristics and existing formation of the impurities in wet FGD gypsum[J]. Environmental Science & Technology, 2013, 36(9): 135-138. | |
30 | 汪潇, 杨留栓, 王宇斌, 等. 脱硫石膏的提纯工艺及其提纯出的石膏原料: CN102616825A[P]. 2012-08-01. |
WANG Xiao, YANG Liushuan, WANG Yubin, et al. Purification process of desulfurization gypsum and gypsum raw materials purified through process: CN102616825A[P]. 2012-08-01. | |
31 | MAHAN G D. Ionic polarization[C]//Williamsburg Conference on Ferroelectrics. Presented at the 2nd Williamsburg Conference on Ferroelectrics, Williamsburg, 1992. |
32 | 汪潇, 曹博伦, 金彪, 等. 添加剂调控半水石膏晶体生长研究进展[J]. 硅酸盐学报, 2020, 48(1): 94-103. |
WANG Xiao, CAO Bolun, JIN Biao, et al. Using additives to control crystal growth of hemihydrate gypsum-A short review[J]. Journal of the Chinese Ceramic Society, 2020, 48(1): 94-103. | |
33 | 罗康碧. 硫酸钙晶须的水热制备工艺及定向生长机理研究[D]. 昆明: 昆明理工大学, 2011. |
1 | GAO Danying, ZHANG Zhenqing, MENG Yang, et al. Effect of flue gas desulfurization gypsum on the properties of calcium sulfoaluminate cement blended with ground granulated blast furnace slag[J]. Materials, 2021, 14(2): 382. |
2 | 孟令佳, 吉忠海, 陈津. 工业副产石膏热分解脱硫的研究进展[J]. 化工进展, 2017, 36(2): 626-633. |
MENG Lingjia, JI Zhonghai, CHEN Jin. Advance of the thermal decomposition of industrial by-product gypsum[J]. Chemical Industry and Engineering Progress, 2017, 36(2): 626-633. | |
3 | 马文静, 陈学青, 郜丽丽, 等. 脱硫石膏制备γ-CaSO4晶须及Ⅱ-CaSO4晶须[J]. 高校化学工程学报, 2021, 35(3): 520-528. |
MA Wenjing, CHEN Xueqing, GAO Lili, et al. Preparation of γ-CaSO4 and Ⅱ-CaSO4 whiskers using FGD gypsum[J]. Journal of Chemical Engineering of Chinese Universities, 2021, 35(3): 520-528. | |
33 | LUO Kangbi. Study on hydrothermal preparation and directional growth mechanism of calcium sulfate whisker[D]. Kunming: Kunming University of Science and Technology, 2011. |
4 | ZHANG Xiaoting, RAN Lingwei, WANG Xiao, et al. Structural characteristic and formation mechanism of hemihydrate calcium sulfate whiskers prepared using FGD gypsum[J]. Particuology, 2022, 62: 98-103. |
5 | LIU Tianjie, FAN Hao, XU Yanxia, et al. Effects of metal ions on the morphology of calcium sulfate hemihydrate whiskers by hydrothermal method[J]. Frontiers of Chemical Science and Engineering, 2017, 11(4): 545-553. |
6 | FAN Hao, SONG Xingfu, LIU Tianjie, et al. Effect of Al3+ on crystal morphology and size of calcium sulfate hemihydrate: experimental and molecular dynamics simulation study[J]. Journal of Crystal Growth, 2018, 495: 29-36. |
7 | 方羊, 窦焰, 孙祥斌, 等. Al3+对水热法制备α-CaSO4·0.5H2O晶须的影响[J]. 高校化学工程学报, 2017, 31(2): 413-419. |
FANG Yang, DOU Yan, SUN Xiangbin, et al. Effects of Al3+ on α-CaSO4·0.5H2O whisker formation in hydrothermal conditions[J]. Journal of Chemical Engineering of Chinese Universities, 2017, 31(2): 413-419. | |
8 | MAO Xiulong, SONG Xingfu, LU Guimin, et al. Effects of metal ions on crystal morphology and size of calcium sulfate whiskers in aqueous HCl solutions[J]. Industrial & Engineering Chemistry Research, 2014, 53(45): 17625-17635. |
9 | RABIZADEH Taher, STAWSKI Tomasz M, MORGAN David J, et al. The effects of inorganic additives on the nucleation and growth kinetics of calcium sulfate dihydrate crystals[J]. Crystal Growth & Design, 2017, 17(2): 582-589. |
10 | LUO Kangbi, LI Huping, TAN Yanxia. Study on the preparation of calcium sulfate whisker by hydrothermal method[J]. Advanced Materials Research, 2012, 602/603/604: 1369-1372. |
11 | GUAN Baohong, YANG Liuchun, WU Zhongbiao. Effect of Mg2+ ions on the nucleation kinetics of calcium sulfate in concentrated calcium chloride solutions[J]. Industrial & Engineering Chemistry Research, 2010, 49(12): 5569-5574. |
12 | AHMED Samia BEN, TLILI Mohamed Mouldi, AMAMI Mongi, et al. Gypsum precipitation kinetics and solubility in the NaCl-MgCl2-CaSO4-H2O system[J]. Industrial & Engineering Chemistry Research, 2014, 53(23): 9554-9560. |
13 | PRISCIANDARO Marina, LANCIA Amedeo, MUSMARRA Dino. Calcium sulfate dihydrate nucleation in the presence of calcium and sodium chloride salts[J]. Industrial & Engineering Chemistry Research, 2001, 40(10): 2335-2339. |
14 | HOU Sichao, WANG Jing, WANG Xiaoxue, et al. Effect of Mg2+ on hydrothermal formation of α-CaSO4·0.5H2O whiskers with high aspect ratios[J]. Langmuir, 2014, 30(32): 9804-9810. |
15 | GUAN Qingjun, SUN Wei, LIU Runqing, et al. Preparation of α-calcium sulfate hemihydrate whiskers with high aspect ratios in presence of a minor amount of CuCl2·2H2O[J]. Journal of Central South University, 2018, 25(3): 526-533. |
16 | FU Hailu, HUANG Jianshi, SHEN Luming, et al. Sodium cation-mediated crystallization of α-hemihydrate whiskers from gypsum in ethylene glycol-water solutions[J]. Crystal Growth & Design, 2018, 18(11): 6694-6701. |
17 | 杨娜, 肖汉宁, 郭文明. 添加剂辅助水热法制备硫酸钙晶须及生长机理研究[J]. 硅酸盐学报, 2014, 42(4): 539-544. |
YANG Na, XIAO Hanning, GUO Wenming. Additives-assisted hydrothermal synthesis of calcium sulfate whisker and its growth mechanism[J]. Journal of the Chinese Ceramic Society, 2014, 42(4): 539-544. |
[1] | SHENG Weiwu, CHENG Yongpan, CHEN Qiang, LI Xiaoting, WEI Jia, LI Linge, CHEN Xianfeng. Operating condition analysis of the microbubble and microdroplet dual-enhanced desulfurization reactor [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 142-147. |
[2] | WANG Jiaqing, SONG Guangwei, LI Qiang, GUO Shuaicheng, DAI Qingli. Rubber-concrete interface modification method and performance enhancement path [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 328-343. |
[3] | CHEN Chongming, CHEN Qiu, GONG Yunqian, CHE Kai, YU Jinxing, SUN Nannan. Research progresses on zeolite-based CO2 adsorbents [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 411-419. |
[4] | ZHANG Jie, WANG Fangfang, XIA Zhonglin, ZHAO Guangjin, MA Shuangchen. Current SF6 emission, emission reduction and future prospects under “carbon peaking and carbon neutrality” [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 447-460. |
[5] | WANG Lele, YANG Wanrong, YAO Yan, LIU Tao, HE Chuan, LIU Xiao, SU Sheng, KONG Fanhai, ZHU Canghai, XIANG Jun. Influence of spent SCR catalyst blending on the characteristics and deNO x performance for new SCR catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 489-497. |
[6] | SUN Yuyu, CAI Xinlei, TANG Jihai, HUANG Jingjing, HUANG Yiping, LIU Jie. Optimization and energy-saving of a reactive distillation process for the synthesis of methyl methacrylate [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 56-63. |
[7] | ZHAO Xi, MA Haoran, LI Ping, HUANG Ailing. Simulation analysis and optimization design of mixing performance of staggered impact micromixer [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4559-4572. |
[8] | WANG Jinhang, HE Yong, SHI Lingli, LONG Zhen, LIANG Deqing. Progress of gas hydrate anti-agglomerants [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4587-4602. |
[9] | ZHU Jie, JIN Jing, DING Zhenghao, YANG Huipan, HOU Fengxiao. Modification of CaSO4 oxygen carrier by Zhundong coal ash in chemical looping gasification and its mechanism [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4628-4635. |
[10] | WANG Jingang, ZHANG Jianbo, TANG Xuejiao, LIU Jinpeng, JU Meiting. Research progress on modification of Cu-SSZ-13 catalyst for denitration of automobile exhaust gas [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4636-4648. |
[11] | XIANG Shuo, LU Peng, SHI Weinian, YANG Xin, HE Yan, ZHU Liye, KONG Xiangwei. Controllable and large-scale preparation of two-dimensional WS2 nanosheet and its tribological properties as lubricant additives in lithium grease [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4783-4790. |
[12] | XU Zhongshuo, ZHOU Panpan, WANG Yuhui, HUANG Wei, SONG Xinshan. Advances in sulfur iron ore mediated autotrophic denitrification [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4863-4871. |
[13] | SONG Weitao, SONG Huiping, FAN Zhenlian, FAN Biao, XUE Fangbin. Research progress of fly ash in anti-corrosion coatings [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4894-4904. |
[14] | LI Xin, YANG Zao, ZHONG Xinru, HAN Haoxuan, ZHUANG Xuning, BAI Jianfeng, DONG Bin, XU Zuxin. Binding mechanism of Pb2+ onto humic acids from sludge hyper-thermophilic composting [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4957-4966. |
[15] | ZHANG Lihong, JIN Yaoru, CHENG Fangqin. Resource utilization of coal gasification slag [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4447-4457. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 Copyright © Chemical Industry and Engineering Progress, All Rights Reserved. E-mail: hgjz@cip.com.cn Powered by Beijing Magtech Co. Ltd |