Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (10): 5200-5213.DOI: 10.16085/j.issn.1000-6613.2021-2512
• Chemical processes and equipment • Previous Articles Next Articles
HUANG Yang1(), ZHANG Jiajun1, LI Jiateng1, XIA Ming2(), XU Chunjian1()
Received:
2021-12-09
Revised:
2021-12-21
Online:
2022-10-21
Published:
2022-10-20
Contact:
XIA Ming, XU Chunjian
黄洋1(), 张稼骏1, 李家腾1, 夏铭2(), 许春建1()
通讯作者:
夏铭,许春建
作者简介:
黄洋(1997—),男,硕士研究生,研究方向为精馏分离。E-mail:yh_1@tju.edu.cn。
CLC Number:
HUANG Yang, ZHANG Jiajun, LI Jiateng, XIA Ming, XU Chunjian. Separation of mixed alcohols from Fischer-Tropsch aqueous by-product: design, optimization and control of fraction cutting[J]. Chemical Industry and Engineering Progress, 2022, 41(10): 5200-5213.
黄洋, 张稼骏, 李家腾, 夏铭, 许春建. 费托合成水相副产物混合醇分离: 馏分切割工艺设计及控制[J]. 化工进展, 2022, 41(10): 5200-5213.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2021-2512
组分 | 分子式 | 组成(质量分数)/% | 沸点/℃ | 共沸物中的醇质量分数/% | 共沸物沸点/℃ | 溶解度(水) |
---|---|---|---|---|---|---|
甲醇 | CH4O | 0.96 | 65.40 | — | — | 混溶 |
乙醇 | C2H6O | 2.00 | 78.01 | 95.6 | 78.16 | 混溶 |
正丙醇 | C3H8O | 1.00 | 97.20 | 69.0 | 87.63 | 混溶 |
正丁醇 | C4H10O | 0.83 | 118.66 | 56.5 | 91.78 | 微溶 |
正戊醇 | C5H12O | 0.53 | 137.80 | 45.5 | 94.30 | 微溶 |
正己醇 | C6H14O | 0.25 | 157.40 | 25.0 | 97.80 | 微溶 |
正庚醇 | C7H16O | 0.04 | 176.30 | 17.0 | 98.70 | 微溶 |
正辛醇 | C8H18O | 0.01 | 195.20 | 10.0 | 99.40 | 不溶 |
水 | H2O | 94.38 | 100.00 | — | — | — |
组分 | 分子式 | 组成(质量分数)/% | 沸点/℃ | 共沸物中的醇质量分数/% | 共沸物沸点/℃ | 溶解度(水) |
---|---|---|---|---|---|---|
甲醇 | CH4O | 0.96 | 65.40 | — | — | 混溶 |
乙醇 | C2H6O | 2.00 | 78.01 | 95.6 | 78.16 | 混溶 |
正丙醇 | C3H8O | 1.00 | 97.20 | 69.0 | 87.63 | 混溶 |
正丁醇 | C4H10O | 0.83 | 118.66 | 56.5 | 91.78 | 微溶 |
正戊醇 | C5H12O | 0.53 | 137.80 | 45.5 | 94.30 | 微溶 |
正己醇 | C6H14O | 0.25 | 157.40 | 25.0 | 97.80 | 微溶 |
正庚醇 | C7H16O | 0.04 | 176.30 | 17.0 | 98.70 | 微溶 |
正辛醇 | C8H18O | 0.01 | 195.20 | 10.0 | 99.40 | 不溶 |
水 | H2O | 94.38 | 100.00 | — | — | — |
共沸物 | 模拟值/(kg/kg,℃) | 实验值/(kg/kg,℃) |
---|---|---|
乙醇/水 | 0.9581/0.0419,78.17 | 0.956/0.044,78.16 |
丙醇/水 | 0.6914/0.3086,87.73 | 0.690/0.310,87.63 |
丁醇/水 | 0.5742/0.4258,92.64 | 0.565/0.435,91.78 |
戊醇/水 | 0.4492/0.5508,95.87 | 0.455/0.545,94.30 |
己醇/水 | 0.2793/0.7207,98.21 | 0.250/0.750,97.80 |
庚醇/水 | 0.1614/0.8386,99.21 | 0.170/0.830,98.70 |
辛醇/水 | 0.1159/0.8841,99.52 | 0.100/0.900,99.40 |
共沸物 | 模拟值/(kg/kg,℃) | 实验值/(kg/kg,℃) |
---|---|---|
乙醇/水 | 0.9581/0.0419,78.17 | 0.956/0.044,78.16 |
丙醇/水 | 0.6914/0.3086,87.73 | 0.690/0.310,87.63 |
丁醇/水 | 0.5742/0.4258,92.64 | 0.565/0.435,91.78 |
戊醇/水 | 0.4492/0.5508,95.87 | 0.455/0.545,94.30 |
己醇/水 | 0.2793/0.7207,98.21 | 0.250/0.750,97.80 |
庚醇/水 | 0.1614/0.8386,99.21 | 0.170/0.830,98.70 |
辛醇/水 | 0.1159/0.8841,99.52 | 0.100/0.900,99.40 |
参数 | 公式 |
---|---|
塔壳费用/USD | (M&S/280)×596.115d1.066H0.802 |
塔板费用/USD | (M&S/280)×12.69d1.55H |
换热器费用①/USD | (M&S/280)×101.3A0.65(2.29+3.75Fd) |
塔高(H)/m | 1.2h (NT-2) |
换热面积(A)②/m2 | Q/(UΔT) |
低压蒸汽(500kPa,160℃) /USD·GJ-1 | 13.28 |
冷却水(30~35℃)/USD·GJ-1 | 0.354 |
M&S | 1638.2(2018)[ |
参数 | 公式 |
---|---|
塔壳费用/USD | (M&S/280)×596.115d1.066H0.802 |
塔板费用/USD | (M&S/280)×12.69d1.55H |
换热器费用①/USD | (M&S/280)×101.3A0.65(2.29+3.75Fd) |
塔高(H)/m | 1.2h (NT-2) |
换热面积(A)②/m2 | Q/(UΔT) |
低压蒸汽(500kPa,160℃) /USD·GJ-1 | 13.28 |
冷却水(30~35℃)/USD·GJ-1 | 0.354 |
M&S | 1638.2(2018)[ |
参数 | S1 | S2 |
---|---|---|
进料板 | 19 | 19 |
侧线出料位置 | 18 | 49 |
NT1 | 60 | 60 |
NT2 | 15 | 15 |
塔径/m | ||
d1 | 1.1 | 1.4 |
d2 | 0.5 | 0.25 |
塔板间距/m | ||
h1 | 0.6 | 0.8 |
h2 | 0.4 | 0.2 |
再沸器热负荷/kW | ||
QR1 | 2882.54(差异31.48%①) | 4206.67 |
QR2 | 278.65 | 99.27 |
总再沸器热负荷QR/kW | 3161.19(差异26.59%②) | 4305.94 |
冷凝器热负荷QC/kW | -2502.16 | -3828.01 |
FCI/kUSD·a-1 | 1032.86 | 1275.04 |
OC/kUSD·a-1 | 1237.21 | 1686.71 |
TAC/kUSD·a-1 | 1547.07(差异25.23%③) | 2069.22 |
参数 | S1 | S2 |
---|---|---|
进料板 | 19 | 19 |
侧线出料位置 | 18 | 49 |
NT1 | 60 | 60 |
NT2 | 15 | 15 |
塔径/m | ||
d1 | 1.1 | 1.4 |
d2 | 0.5 | 0.25 |
塔板间距/m | ||
h1 | 0.6 | 0.8 |
h2 | 0.4 | 0.2 |
再沸器热负荷/kW | ||
QR1 | 2882.54(差异31.48%①) | 4206.67 |
QR2 | 278.65 | 99.27 |
总再沸器热负荷QR/kW | 3161.19(差异26.59%②) | 4305.94 |
冷凝器热负荷QC/kW | -2502.16 | -3828.01 |
FCI/kUSD·a-1 | 1032.86 | 1275.04 |
OC/kUSD·a-1 | 1237.21 | 1686.71 |
TAC/kUSD·a-1 | 1547.07(差异25.23%③) | 2069.22 |
参数 | 两塔-侧线分相器流程 | 常规三塔粗分流程 | ||||
---|---|---|---|---|---|---|
侧线精馏塔 | 重醇塔 | 脱水塔 | 醇分塔 | 重醇塔 | ||
p/kPa | 101.3 | 121.3 | 101.3 | 121.3 | ||
NT | 62 | 14 | 47 | 51 | 8 | |
NF | 25 | 1 | 10 | 29 | 1 | |
RR | 6.13 | — | 1.61 | 1.69 | — | |
d/m | 1.1 | 0.5 | 1.0 | 0.7 | 0.25 | |
h/m | 0.6 | 0.4 | 0.6 | 0.4 | 0.2 | |
QC/kW | -2224.74 | -272.31 | -2111.65 | -840.84 | -80.20 | |
QR/kW | 2571.21 | 291.39 | 2446.14 | 858.11 | 101.95 | |
合计QR/kW | 2862.60(差异15.96%①) | 3406.20 | ||||
FCI/kUSD·a-1 | 1016.67 | 1136.08 | ||||
OC/kUSD·a-1 | 1120.30 | 1333.67 | ||||
TAC/kUSD·a-1 | 1456.40(差异14.79%②) | 1709.25 |
参数 | 两塔-侧线分相器流程 | 常规三塔粗分流程 | ||||
---|---|---|---|---|---|---|
侧线精馏塔 | 重醇塔 | 脱水塔 | 醇分塔 | 重醇塔 | ||
p/kPa | 101.3 | 121.3 | 101.3 | 121.3 | ||
NT | 62 | 14 | 47 | 51 | 8 | |
NF | 25 | 1 | 10 | 29 | 1 | |
RR | 6.13 | — | 1.61 | 1.69 | — | |
d/m | 1.1 | 0.5 | 1.0 | 0.7 | 0.25 | |
h/m | 0.6 | 0.4 | 0.6 | 0.4 | 0.2 | |
QC/kW | -2224.74 | -272.31 | -2111.65 | -840.84 | -80.20 | |
QR/kW | 2571.21 | 291.39 | 2446.14 | 858.11 | 101.95 | |
合计QR/kW | 2862.60(差异15.96%①) | 3406.20 | ||||
FCI/kUSD·a-1 | 1016.67 | 1136.08 | ||||
OC/kUSD·a-1 | 1120.30 | 1333.67 | ||||
TAC/kUSD·a-1 | 1456.40(差异14.79%②) | 1709.25 |
项目 | 控制变量 | 操纵变量 | 增益/Kc | 积分时间τI/min |
---|---|---|---|---|
CC1 | xD1(丁醇) | 回流比(侧线精馏塔) | 0.10 | 40.92 |
CC2 | xB1(水) | 再沸器热负荷(侧线精馏塔) | 0.20 | 77.88 |
T4 | xB1(丙醇) | 再沸器热负荷(重醇塔) | 0.35 | 10.56 |
项目 | 控制变量 | 操纵变量 | 增益/Kc | 积分时间τI/min |
---|---|---|---|---|
CC1 | xD1(丁醇) | 回流比(侧线精馏塔) | 0.10 | 40.92 |
CC2 | xB1(水) | 再沸器热负荷(侧线精馏塔) | 0.20 | 77.88 |
T4 | xB1(丙醇) | 再沸器热负荷(重醇塔) | 0.35 | 10.56 |
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