Recent progresses in CO2 to syngas and high value-added products

doi:10.16085/j.issn.1000-6613.2021-1909

Abstract

Abstract:

The global warming caused by excess carbon dioxide (CO₂) emission has been a worldwide focus. The development of carbon neutralization technologies is a strategic choice for the sustainability of human society. CO₂ capture and conversion to high value-added chemicals is an ultimate technology for the goal of carbon neutralization, which can optimize the fossil fuel-dominated energy structure, effectively alleviate environmental problems, and achieve carbon recycling. This paper focuses on the efficient CO₂ utilization by the route of CO₂-syngas-high value-added chemicals. As an important intermedia product, syngas is the most feasible for CO₂ conversion and can be further transformed into value-added chemicals. Recent progresses in three CO₂ to syngas technologies of thermo-catalysis, electrocatalysis and photocatalysis are reviewed, including the mechanism, catalysts design strategies, and the current industrial application prospects. Moreover, the conversion of syngas to light olefins and aromatics through the Fischer-Tropsch synthesis and relay catalytic routes are also reviewed. By analyzing and comparing the key technologies, we summarize the challenges of catalyst design and reactor optimization for the large-scale industrial applications of CO₂ to syngas and further to high value-added products, and proposed the prospects of CO₂ capture and utilization. At the same time, the problems of unclear reaction mechanism, high cost of catalysts and lack of large-scale producing are explained. The effort to promote application of the technologies in the future is to develop low-cost and long-life catalyst with high activity and efficiency.

Key words: carbon dioxide, syngas, catalytic mechanism, catalyst, industrial application

摘要：

由于二氧化碳（CO₂）过度排放导致全球变暖日益严峻，发展零碳技术已成为人类社会面向可持续发展的战略选择。将CO₂捕集并转化为高附加值化学和能源产品，可以优化化石能源为主体的能源结构、有效缓解环境问题，并实现碳资源的充分利用，是一项可以大规模实现低碳减排的技术。本文重点介绍了CO₂高效利用新途径，通过二氧化碳-合成气-高附加值化学品的产品工艺路线，实现CO₂的资源化利用。对比综述了热催化法、电催化法和光催化法高效转化合成气的最新进展，总结了热、电、光催化制备合成气过程中催化剂的设计原理和方法以及目前工业化应用前景；简单概述了合成气作为重要平台分子，进一步通过费托合成路线或接力催化路线转化为低碳烯烃和液态燃料或芳烃等化学品过程中催化剂设计研究进展。最后，总结了大规模工业化CO₂转化为合成气及高附加值产品过程催化剂设计和反应器优化的技术难题，并对未来CO₂高效转化利用方向进行了展望。同时指出目前各技术还普遍存在反应机理不清晰、催化剂成本高以及缺乏大规模合成等问题，未来开发出高效、高活性、低成本且稳定的催化剂是各技术推广应用的关键。

关键词: 二氧化碳, 合成气, 催化机理, 催化剂, 工业应用

CLC Number:

TQ211

SHAO Bin, SUN Zheyi, ZHANG Yun, PAN Fenghongkang, ZHAO Kaiqing, HU Jun, LIU Honglai. Recent progresses in CO₂ to syngas and high value-added products[J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1136-1151.

邵斌, 孙哲毅, 章云, 潘冯弘康, 赵开庆, 胡军, 刘洪来. 二氧化碳转化为合成气及高附加值产品的研究进展[J]. 化工进展, 2022, 41(3): 1136-1151.

Figures/Tables 2

References 95

1	FIGUERES C, LE QUÉRÉ C, MAHINDRA A, et al. Emissions are still rising: ramp up the cuts[J]. Nature, 2018, 564(7734): 27-30.
2	李函珂, 党成雄, 杨光星, 等. 面向二氧化碳捕集的过程强化技术进展[J]. 化工进展, 2020, 39(12): 4919-4939.
	LI Hanke, DANG Chengxiong, YANG Guangxing, et al. Process intensification techniques towards carbon dioxide capture: a review[J]. Chemical Industry and Engineering Progress, 2020, 39(12): 4919-4939.
3	GAO P, LI S G, BU X N, et al. Direct conversion of CO₂ into liquid fuels with high selectivity over a bifunctional catalyst[J]. Nature Chemistry, 2017, 9(10): 1019-1024.
4	ZHANG Z E, PAN S Y, LI H, et al. Recent advances in carbon dioxide utilization[J]. Renewable and Sustainable Energy Reviews, 2020, 125: 109799.
5	MA J, SUN N N, ZHANG X L, et al. A short review of catalysis for CO₂ conversion[J]. Catalysis Today, 2009, 148(3-4): 221-231.
6	周伟, 成康, 张庆红, 等. 合成气转化中的接力催化[J]. 科学通报, 2021, 66(10): 1157-1169.
	ZHOU Wei, CHENG Kang, ZHANG Qinghong, et al. Relay catalysis in the conversion of syngas[J]. Chinese Science Bulletin, 2021, 66(10): 1157-1169.
7	KAWI S, KATHIRASER Y, NI J, et al. Progress in synthesis of highly active and stable nickel-based catalysts for carbon dioxide reforming of methane[J]. ChemSusChem, 2015, 8(21): 3556-3575.
8	PAKHARE D, SPIVEY J. A review of dry (CO₂) reforming of methane over noble metal catalysts[J]. Chemical Society Reviews, 2014, 43(22): 7813-7837.
9	YABE T, SEKINE Y. Methane conversion using carbon dioxide as an oxidizing agent: a review[J]. Fuel Processing Technology, 2018, 181: 187-198.
10	ZUO Z J, LIU S Z, WANG Z C, et al. Dry reforming of methane on single-site Ni/MgO catalysts: importance of site confinement[J]. ACS Catalysis, 2018, 8(10): 9821-9835.
11	ASHCROFT A T, CHEETHAM A K, GREEN M L H, et al. Partial oxidation of methane to synthesis gas using carbon dioxide[J]. Nature, 1991, 352(6332): 225-226.
12	THEOFANIDIS S A, GALVITA V V, POELMAN H, et al. Enhanced carbon-resistant dry reforming Fe-Ni catalyst: role of Fe[J]. ACS Catalysis, 2015, 5(5): 3028-3039.
13	阮勇哲, 卢遥, 王胜平. 甲烷干重整Ni基催化剂失活及抑制失活研究进展[J]. 化工进展, 2018, 37(10): 3850-3857.
	RUAN Yongzhe, LU Yao, WANG Shengping. Progress in deactivation and anti-deactivation of nickel-based catalysts for methanedry reforming[J]. Chemical Industry and Engineering Progress, 2018, 37(10): 3850-3857.
14	张涛, 刘志成, 杨为民. 低碳烷烃与二氧化碳催化转化研究进展[J]. 中国科学: 化学, 2021, 51(2): 154-164.
	ZHANG Tao, LIU Zhicheng, YANG Weimin. Progress in the catalytic conversion of light alkanes with carbon dioxide[J]. Scientia Sinica (Chimica), 2021, 51(2): 154-164.
15	KATHIRASER Y, OEMAR U, SAW E T, et al. Kinetic and mechanistic aspects for CO₂ reforming of methane over Ni based catalysts[J]. Chemical Engineering Journal, 2015, 278: 62-78.
16	ZHU Y A, CHEN D, ZHOU X G, et al. DFT studies of dry reforming of methane on Ni catalyst[J]. Catalysis Today, 2009, 148(3/4): 260-267.
17	FAN C, ZHU Y A, YANG M L, et al. Density functional theory-assisted microkinetic analysis of methane dry reforming on Ni catalyst[J]. Industrial & Engineering Chemistry Research, 2015, 54(22): 5901-5913.
18	FOPPA L, SILAGHI M C, LARMIER K, et al. Intrinsic reactivity of Ni, Pd and Pt surfaces in dry reforming and competitive reactions: insights from first principles calculations and microkinetic modeling simulations[J]. Journal of Catalysis, 2016, 343: 196-207.
19	ZHANG X, DENG J, PUPUCEVSKI M, et al. High-performance binary Mo-Ni catalysts for efficient carbon removal during carbon dioxide reforming of methane[J]. ACS Catalysis, 2021, 11(19): 12087-12095.
20	KIM J H, SUH D J, PARK T J, et al. Effect of metal particle size on coking during CO₂ reforming of CH₄ over Ni-alumina aerogel catalysts[J]. Applied Catalysis A: General, 2000, 197(2): 191-200.
21	AKRI M, ZHAO S, LI X Y, et al. Atomically dispersed nickel as coke-resistant active sites for methane dry reforming[J]. Nature Communications, 2019, 10: 5181.
22	SONG Y, OZDEMIR E, RAMESH S, et al. Dry reforming of methane by stable Ni-Mo nanocatalysts on single-crystalline MgO[J]. Science, 2020, 367(6479): 777-781.
23	KIM S M, ABDALA P M, MARGOSSIAN T, et al. Cooperativity and dynamics increase the performance of NiFe dry reforming catalysts[J]. Journal of the American Chemical Society, 2017, 139(5): 1937-1949.
24	KAISER P, UNDE R, KERN C, et al. Production of liquid hydrocarbons with CO₂ as carbon source based on reverse water-gas shift and Fischer-Tropsch synthesis[J]. Chemie Ingenieur Technik, 2013, 85(4): 489-499.
25	SU X, YANG X L, ZHAO B, et al. Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: recent advances and the future directions[J]. Journal of Energy Chemistry, 2017, 26(5): 854-867.
26	BAHMANPOUR A M, SIGNORILE M, KRÖCHER O. Recent progress in syngas production via catalytic CO₂ hydrogenation reaction[J]. Applied Catalysis B: Environmental, 2021, 295: 120319.
27	WANG X, SHI H, KWAK J H, et al. Mechanism of CO₂ hydrogenation on Pd/Al₂O₃ catalysts: kinetics and transient DRIFTS-MS studies[J]. ACS Catalysis, 2015, 5(11): 6337-6349.
28	BAHMANPOUR A M, HÉROGUEL F, KILIÇ M, et al. Essential role of oxygen vacancies of Cu-Al and Co-Al spinel oxides in their catalytic activity for the reverse water gas shift reaction[J]. Applied Catalysis B: Environmental, 2020, 266: 118669.
29	JUNEAU M, VONGLIS M, HARTVIGSEN J, et al. Assessing the viability of K-Mo₂C for reverse water-gas shift scale-up: molecular to laboratory to pilot scale[J]. Energy & Environmental Science, 2020, 13(8): 2524-2539.
30	SHAO B, HU G H, ALKEBSI K A M, et al. Heterojunction-redox catalysts of Fe _x Co _y Mg₁₀CaO for high-temperature CO₂ capture and in situ conversion in the context of green manufacturing[J]. Energy & Environmental Science, 2021, 14(4): 2291-2301.
31	陈倩倩, 顾宇, 唐志永, 等. 以二氧化碳规模化利用技术为核心的碳减排方案[J]. 中国科学院院刊, 2019, 34(4): 478-487.
	CHEN Qianqian, GU Yu, TANG Zhiyong, et al. Carbon dioxide sizable utilization technology based carbon reduction solutions[J]. Bulletin of Chinese Academy of Sciences, 2019, 34(4): 478-487.
32	Green Car Congress. Carbon sciences licenses catalyst technology for carbon dioxide reforming of methane from University of Saskatchewan[EB/OL]. .
33	CHEN Q J, ZHANG J, PAN B R, et al. Temperature-dependent anti-coking behaviors of highly stable Ni-CaO-ZrO₂ nanocomposite catalysts for CO₂ reforming of methane[J]. Chemical Engineering Journal, 2017, 320: 63-73.
34	Shanghai Advanced Research Institute of Chinese Academy of Science. Methane and carbon dioxide autothermal reforming to produce tens of thousands of Nm³ syngas pilot-scale plant achieves stable operation [EB/OL]. 2017. .
35	WU H, LIU J X, LIU H M, et al. CO₂ reforming of methane to syngas at high pressure over bi-component Ni-Co catalyst: the anti-carbon deposition and stability of catalyst[J]. Fuel, 2019, 235: 868-877.
36	REZAEI E, DZURYK S. Techno-economic comparison of reverse water gas shift reaction to steam and dry methane reforming reactions for syngas production[J]. Chemical Engineering Research and Design, 2019, 144: 354-369.
37	葛欣. 逆水煤气变换耦合乙烷脱氢高选择性制备乙烯反应的研究进展[J]. 化工进展, 2010, 29(10): 1811-1816.
	GE Xin. Coupling of ethane dehydrogenation with reversed water-gas shift reaction for ethylene synthesis[J]. Chemical Industry and Engineering Progress, 2010, 29(10): 1811-1816.
38	CHENG Y, ZHAO S Y, JOHANNESSEN B, et al. Atomically dispersed transition metals on carbon nanotubes with ultrahigh loading for selective electrochemical carbon dioxide reduction[J]. Advanced Materials, 2018, 30(13): 1706287.
39	LIU S G, HUANG S P. Size effects and active sites of Cu nanoparticle catalysts for CO₂ electroreduction[J]. Applied Surface Science, 2019, 475: 20-27.
40	ZHU W, MICHALSKY R, METIN Ö, et al. Monodisperse Au nanoparticles for selective electrocatalytic reduction of CO₂ to CO[J]. Journal of the American Chemical Society, 2013, 135(45): 16833-16836.
41	ZHANG H N, LI J, XI S B, et al. A graphene-supported single-atom FeN₅ catalytic site for efficient electrochemical CO₂ reduction[J]. Angewandte Chemie International Edition, 2019, 58(42): 14871-14876.
42	GONG Y N, JIAO L, QIAN Y Y, et al. Regulating the coordination environment of MOF-templated single-atom nickel electrocatalysts for boosting CO₂ reduction[J]. Angewandte Chemie International Edition, 2020, 59(7): 2705-2709.
43	WANG X Q, CHEN Z, ZHAO X Y, et al. Regulation of coordination number over single Co sites: triggering the efficient electroreduction of CO₂ [J]. Angewandte Chemie International Edition, 2018, 57(7): 1944-1948.
44	QIN X P, ZHU S Q, XIAO F, et al. Active sites on heterogeneous single-iron-atom electrocatalysts in CO₂ reduction reaction[J]. ACS Energy Letters, 2019, 4(7): 1778-1783.
45	GUO W W, BI J H, ZHU Q G, et al. Highly selective CO₂ electroreduction to CO on Cu-Co bimetallic catalysts[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(33): 12561-12567.
46	HE Q, LIU D B, LEE J H, et al. Electrochemical conversion of CO₂ to syngas with controllable CO/H₂ ratios over Co and Ni single-atom catalysts[J]. Angewandte Chemie International Edition, 2020, 59(8): 3033-3037.
47	REN W H, TAN X, YANG W F, et al. Isolated diatomic Ni-Fe metal-nitrogen sites for synergistic electroreduction of CO₂ [J]. Angewandte Chemie International Edition, 2019, 58(21): 6972-6976.
48	LU Z Y, WANG B, HU Y F, et al. An isolated zinc-cobalt atomic pair for highly active and durable oxygen reduction[J]. Angewandte Chemie International Edition, 2019, 58(9): 2622-2626.
49	XIANG H, RASUL S, HOU B, et al. Copper-indium binary catalyst on a gas diffusion electrode for high-performance CO₂ electrochemical reduction with record CO production efficiency[J]. ACS Applied Materials & Interfaces, 2020, 12(1): 601-608.
50	JIANG K, SIAHROSTAMI S, ZHENG T T, et al. Isolated Ni single atoms in graphene nanosheets for high-performance CO₂ reduction[J]. Energy & Environmental Science, 2018, 11(4): 893-903.
51	LU S S, SHI Y M, MENG N N, et al. Electrosynthesis of syngas via the co-reduction of CO₂ and H₂O[J]. Cell Reports Physical Science, 2020, 1(11): 100237.
52	JIN S, HAO Z M, ZHANG K, et al. Advances and challenges for the electrochemical reduction of CO₂ to CO: from fundamentals to industrialization[J]. Angewandte Chemie International Edition, 2021, 60(38): 20627-20648.
53	JOUNY M, LUC W W, JIAO F. General techno-economic analysis of CO₂ electrolysis systems[J]. Industrial & Engineering Chemistry Research, 2018, 57(6): 2165-2177.
54	NAVARRO R M, PEÑA M A, FIERRO J L. Hydrogen production reactions from carbon feedstocks: fossil fuels and biomass[J]. Chemical Reviews, 2007, 107(10): 3952-3991.
55	LEE S, CHOI M, LEE J. Looking back and looking ahead in electrochemical reduction of CO₂ [J]. The Chemical Record, 2020, 20(2): 89-101.
56	VERMA S, LU S, KENIS P J A. Co-electrolysis of CO₂ and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption[J]. Nature Energy, 2019, 4(6): 466-474.
57	BAI S, JIANG J, ZHANG Q, et al. Steering charge kinetics in photocatalysis: intersection of materials syntheses, characterization techniques and theoretical simulations[J]. Chemical Society Reviews, 2015, 44(10): 2893-2939.
58	HABISREUTINGER S N, SCHMIDT-MENDE L, STOLARCZYK J K. Photocatalytic reduction of CO₂ on TiO₂ and other semiconductors[J]. Angewandte Chemie International Edition, 2013, 52(29): 7372-7408.
59	LUO S H, ZENG Z T, ZENG G M, et al. Recent advances in conjugated microporous polymers for photocatalysis: designs, applications, and prospects[J]. Journal of Materials Chemistry A, 2020, 8(14): 6434-6470.
60	YU X X, YANG Z Z, QIU B, et al. Eosin Y-functionalized conjugated organic polymers for visible-light-driven CO₂ reduction with H₂O to CO with high efficiency[J]. Angewandte Chemie International Edition, 2019, 58(2): 632-636.
61	LI D D, KASSYMOVA M, CAI X C, et al. Photocatalytic CO₂ reduction over metal-organic framework-based materials[J]. Coordination Chemistry Reviews, 2020, 412: 213262.
62	DONG H, ZHANG X, LU Y, et al. Regulation of metal ions in smart metal-cluster nodes of metal-organic frameworks with open metal sites for improved photocatalytic CO₂ reduction reaction[J]. Applied Catalysis B: Environmental, 2020, 276: 119173.
63	LU M, LIU J, LI Q, et al. Rational design of crystalline covalent organic frameworks for efficient CO₂ photoreduction with H₂O[J]. Angewandte Chemie International Edition, 2019, 58(36): 12392-12397.
64	ZHONG W F, SA R J, LI L Y, et al. A covalent organic framework bearing single Ni sites as a synergistic photocatalyst for selective photoreduction of CO₂ to CO[J]. Journal of the American Chemical Society, 2019, 141(18): 7615-7621.
65	HE Y J, CHEN X, HUANG C, et al. Encapsulation of Co single sites in covalent triazine frameworks for photocatalytic production of syngas[J]. Chinese Journal of Catalysis, 2021, 42(1): 123-130.
66	QIU C H, BAI S, CAO W J, et al. Tunable syngas synthesis from photocatalytic CO₂ reduction under visible-light irradiation by interfacial engineering[J]. Transactions of Tianjin University, 2020, 26(5): 352-361.
67	CHEN C, HU J D, YANG X G, et al. Ambient-stable black phosphorus-based 2D/2D S-scheme heterojunction for efficient photocatalytic CO₂ reduction to syngas[J]. ACS Applied Materials & Interfaces, 2021, 13(17): 20162-20173.
68	WANG X, WANG Z L, BAI Y, et al. Tuning the selectivity of photoreduction of CO₂ to syngas over Pd/layered double hydroxide nanosheets under visible light up to 600nm[J]. Journal of Energy Chemistry, 2020, 46: 1-7.
69	YANG J, WANG Z Y, JIANG J C, et al. In-situ polymerization induced atomically dispersed manganese sites as cocatalyst for CO₂ photoreduction into synthesis gas[J]. Nano Energy, 2020, 76: 105059.
70	WANG X W, CHEN J F, LI Q Y, et al. Light-driven syngas production over defective ZnIn₂S₄ nanosheets[J]. Chemistry: A European Journal, 2021, 27(11): 3786-3792.
71	YANG P J, SHANG L, ZHAO J H, et al. Selectively constructing nitrogen vacancy in carbon nitrides for efficient syngas production with visible light[J]. Applied Catalysis B: Environmental, 2021, 297: 120496.
72	ZHOU W, CHENG K, KANG J C, et al. New horizon in C₁ chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO₂ into hydrocarbon chemicals and fuels[J]. Chemical Society Reviews, 2019, 48(12): 3193-3228.
73	PAN X L, JIAO F, MIAO D Y, et al. Oxide-zeolite-based composite catalyst concept that enables syngas chemistry beyond Fischer-Tropsch synthesis[J]. Chemical Reviews, 2021, 121(11): 6588-6609.
74	BILOEN P, SACHTLER W M H. Mechanism of hydrocarbon synthesis over Fischer-Tropsch catalysts[J]. Advances in Catalysis, 1981, 30: 165-216.
75	SANTEN R A VAN, GHOURI M M, SHETTY S, et al. Structure sensitivity of the Fischer-Tropsch reaction; molecular kinetics simulations[J]. Catalysis Science & Technology, 2011, 1(6): 891.
76	SANTEN R A VAN, MARKVOORT A J, FILOT I A W, et al. Mechanism and microkinetics of the Fischer-Tropsch reaction[J]. Physical Chemistry Chemical Physics, 2013, 15(40): 17038.
77	FRIEDEL R A, ANDERSON R B. Composition of synthetic liquid fuels (I): product distribution and analysis of C₅—C₈ paraffin isomers from cobalt catalyst[J]. Journal of the American Chemical Society, 1950, 72(3): 1212-1215.
78	PUSKAS I, HURLBUT R S. Comments about the causes of deviations from the Anderson-Schulz-Flory distribution of the Fischer-Tropsch reaction products[J]. Catalysis Today, 2003, 84(1/2): 99-109.
79	ZHONG L S, YU F, AN Y L, et al. Cobalt carbide nanoprisms for direct production of lower olefins from syngas[J]. Nature, 2016, 538(7623): 84-87.
80	XU Y F, LI X Y, GAO J H, et al. A hydrophobic FeMn@Si catalyst increases olefins from syngas by suppressing C₁ by-products[J]. Science, 2021, 371(6529): 610-613.
81	ZHAI P, XU C, GAO R, et al. Highly tunable selectivity for syngas-derived alkenes over zinc and sodium-modulated Fe₅C₂ catalyst[J]. Angewandte Chemie, 2016, 128(34): 10056-10061.
82	JIAO F, LI J J, PAN X L, et al. Selective conversion of syngas to light olefins[J]. Science, 2016, 351(6277): 1065-1068.
83	新华社. 大连化物所煤制烯烃新技术成功完成工业试验[EB/OL]. 2019-09-20.
	Xinhua News Agency. Dalian Institute of Chemical Physicshas successfully completed the industrial test of the new coal to olefin technology[EB/OL]. 2019-09-20. .
84	DING Y, JIAO F, PAN X L, et al. Effects of proximity-dependent metal migration on bifunctional composites catalyzed syngas to olefins[J]. ACS Catalysis, 2021, 11(15): 9729-9737.
85	CHENG K, GU B, LIU X L, et al. Direct and highly selective conversion of synthesis gas into lower olefins: design of a bifunctional catalyst combining methanol synthesis and carbon-carbon coupling[J]. Angewandte Chemie, 2016, 128(15): 4803-4806.
86	LIU X L, ZHOU W, YANG Y D, et al. Design of efficient bifunctional catalysts for direct conversion of syngas into lower olefins via methanol/dimethyl ether intermediates[J]. Chemical Science, 2018, 9(20): 4708-4718.
87	JAVED M, CHENG S L, ZHANG G H, et al. A facile solvent-free synthesis strategy for Co-imbedded zeolite-based Fischer-Tropsch catalysts for direct gasoline production[J]. Chinese Journal of Catalysis, 2020, 41(4): 604-612.
88	LI N, JIAO F, PAN X L, et al. High-quality gasoline directly from syngas by dual metal oxide-zeolite (OX-ZEO) catalysis[J]. Angewandte Chemie International Edition, 2019, 58(22): 7400-7404.
89	NI Y M, WANG K Y, ZHU W L, et al. Realizing high conversion of syngas to gasoline-range liquid hydrocarbons on a dual-bed-mode catalyst[J]. Chem Catalysis, 2021, 1(2): 383-392.
90	KANG J C, HE S, ZHOU W, et al. Single-pass transformation of syngas into ethanol with high selectivity by triple tandem catalysis[J]. Nature Communications, 2020, 11: 827.
91	ZHOU W, SHI S L, WANG Y, et al. Selective conversion of syngas to aromatics over a Mo-ZrO₂/H-ZSM-5 bifunctional catalyst[J]. ChemCatChem, 2019, 11(6): 1681-1688.
92	MIAO D Y, DING Y, YU T, et al. Selective synthesis of benzene, toluene, and xylenes from syngas[J]. ACS Catalysis, 2020, 10(13): 7389-7397.
93	ZHAO B, ZHAI P, WANG P F, et al. Direct transformation of syngas to aromatics over Na-Zn-Fe₅C₂ and hierarchical HZSM-5 tandem catalysts[J]. Chem, 2017, 3(2): 323-333.
94	CHENG K, ZHOU W, KANG J C, et al. Bifunctional catalysts for one-step conversion of syngas into aromatics with excellent selectivity and stability[J]. Chem, 2017, 3(2): 334-347.
95	LIU C, SU J J, XIAO Y, et al. Constructing directional component distribution in a bifunctional catalyst to boost the tandem reaction of syngas conversion[J]. Chem Catalysis, 2021, 1(4): 896-907.

[1]	YANG Hanyue, KONG Lingzhen, CHEN Jiaqing, SUN Huan, SONG Jiakai, WANG Sicheng, KONG Biao. Decarbonization performance of downflow tubular gas-liquid contactor of microbubble-type [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 197-204.
[2]	ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286.
[3]	SHI Yongxing, LIN Gang, SUN Xiaohang, JIANG Weigeng, QIAO Dawei, YAN Binhang. Research progress on active sites in Cu-based catalysts for CO₂ hydrogenation to methanol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 287-298.
[4]	XIE Luyao, CHEN Songzhe, WANG Laijun, ZHANG Ping. Platinum-based catalysts for SO₂ depolarized electrolysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 299-309.
[5]	YANG Xiazhen, PENG Yifan, LIU Huazhang, HUO Chao. Regulation of active phase of fused iron catalyst and its catalytic performance of Fischer-Tropsch synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 310-318.
[6]	ZHENG Qian, GUAN Xiushuai, JIN Shanbiao, ZHANG Changming, ZHANG Xiaochao. Photothermal catalysis synthesis of DMC from CO₂ and methanol over Ce_0.25Zr_0.75O₂ solid solution [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 319-327.
[7]	WANG Lele, YANG Wanrong, YAO Yan, LIU Tao, HE Chuan, LIU Xiao, SU Sheng, KONG Fanhai, ZHU Canghai, XIANG Jun. Influence of spent SCR catalyst blending on the characteristics and deNO _x performance for new SCR catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 489-497.
[8]	DENG Liping, SHI Haoyu, LIU Xiaolong, CHEN Yaoji, YAN Jingying. Non-noble metal modified vanadium titanium-based catalyst for NH₃-SCR denitrification simultaneous control VOCs [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 542-548.
[9]	SUN Yuyu, CAI Xinlei, TANG Jihai, HUANG Jingjing, HUANG Yiping, LIU Jie. Optimization and energy-saving of a reactive distillation process for the synthesis of methyl methacrylate [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 56-63.
[10]	CHENG Tao, CUI Ruili, SONG Junnan, ZHANG Tianqi, ZHANG Yunhe, LIANG Shijie, PU Shi. Analysis of impurity deposition and pressure drop increase mechanisms in residue hydrotreating unit [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4616-4627.
[11]	WANG Peng, SHI Huibing, ZHAO Deming, FENG Baolin, CHEN Qian, YANG Da. Recent advances on transition metal catalyzed carbonylation of chlorinated compounds [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4649-4666.
[12]	ZHANG Qi, ZHAO Hong, RONG Junfeng. Research progress of anti-toxicity electrocatalysts for oxygen reduction reaction in PEMFC [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4677-4691.
[13]	GE Quanqian, XU Mai, LIANG Xian, WANG Fengwu. Research progress on the application of MOFs in photoelectrocatalysis [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4692-4705.
[14]	WANG Weitao, BAO Tingyu, JIANG Xulu, HE Zhenhong, WANG Kuan, YANG Yang, LIU Zhaotie. Oxidation of benzene to phenol over aldehyde-ketone resin based metal-free catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4706-4715.
[15]	GE Yafen, SUN Yu, XIAO Peng, LIU Qi, LIU Bo, SUN Chengying, GONG Yanjun. Research progress of zeolite for VOCs removal [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4716-4730.

Recent progresses in CO₂ to syngas and high value-added products

二氧化碳转化为合成气及高附加值产品的研究进展

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 2

References 95

Related Articles 15

Recommended Articles

Metrics

Comments